LCPO CHEMISTRY W/MODIFIED MASTERING
8th Edition
ISBN: 9780135214756
Author: Robinson
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Question
Chapter 15, Problem 15.136SP
Interpretation Introduction
Interpretation:
This is to be shown that theequilibrium constant is equal to the ratio of the rate constant of the forward and reverse direction.
Concept introduction:
A
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionChapter 15 Solutions
LCPO CHEMISTRY W/MODIFIED MASTERING
Ch. 15 - The oxidation of sulfur dioxide to give...Ch. 15 - APPLY 14.2 Nitrogen dioxide, a pollutant that...Ch. 15 - The following equilibrium concentrations were...Ch. 15 - APPLY 14.4 Lactic acid, which builds up in muscle...Ch. 15 - Conceptual PRACTICE 14.5 The following pictures...Ch. 15 - Conceptual APPLY 14.6 The equilibrium constant...Ch. 15 - PRACTICE 14.7 In the industrial synthesis of...Ch. 15 - APPLY 14.8 At 25 °C, Kp = 25 for the reaction...Ch. 15 - Nitric oxide reacts with oxygen to give nitrogen...Ch. 15 - APPLY 14.10For the reaction...
Ch. 15 - Write the equilibrium constant expression (Kp)...Ch. 15 - APPLY 14.12 Magnesium hydroxide is the active...Ch. 15 - When wine spoils, ethanol is oxidized to acetic...Ch. 15 - The value of K for the dissociation reaction...Ch. 15 - The equilibrium constant K. for the reaction...Ch. 15 - Conceptual APPLY 14.16 The reaction A2 + B2 2...Ch. 15 - PRACTICE 14.17 The H2/CO ratio in mixtures of...Ch. 15 - APPLY 14.18 Calculate the equilibrium...Ch. 15 - PRACTICE 14.19 Calculate the equilibrium...Ch. 15 - APPLY 14.20 Calculate the equilibrium...Ch. 15 - Calculate the equilibrium concentrations of...Ch. 15 - Calculate the equilibrium concentrations of...Ch. 15 - The equilibrium constant Kp , for the reaction...Ch. 15 - The equilibrium constant Kp , for the reaction...Ch. 15 - Consider the equilibrium for the water—gas shift...Ch. 15 - Solid particles that form in the kidney are called...Ch. 15 - Does the number of moles of products...Ch. 15 - CONCEPTUAL APPLY 15.28 The following picture...Ch. 15 - When air is heated at very high temperatures in an...Ch. 15 - Ethyl acetate, a solvent used in many...Ch. 15 - The following pictures represent the composition...Ch. 15 - The following picture represents an equilibrium...Ch. 15 - Nitric oxide emitted from the engines of...Ch. 15 - The energy profile of the reaction krKf is shown....Ch. 15 - Refer to Figure 15.16 to answer the following...Ch. 15 - Prob. 15.36PCh. 15 - Prob. 15.37PCh. 15 - Prob. 15.38PCh. 15 - Prob. 15.39PCh. 15 - Prob. 15.40PCh. 15 - Prob. 15.41CPCh. 15 - The following pictures represent the equilibrium...Ch. 15 - The reaction A2+BA+AB has an equilibrium constant...Ch. 15 - Prob. 15.44CPCh. 15 - Prob. 15.45CPCh. 15 - Prob. 15.46CPCh. 15 - The following pictures represent equilibrium...Ch. 15 - Prob. 15.48CPCh. 15 - Prob. 15.49CPCh. 15 - Prob. 15.50CPCh. 15 - Prob. 15.51CPCh. 15 - Prob. 15.52SPCh. 15 - Identify the true statement about the...Ch. 15 - Prob. 15.54SPCh. 15 - Prob. 15.55SPCh. 15 - For each of the following equilibria, write the...Ch. 15 - Prob. 15.57SPCh. 15 - Prob. 15.58SPCh. 15 - Prob. 15.59SPCh. 15 - For each of the following equilibria, write the...Ch. 15 - Prob. 15.61SPCh. 15 - The reaction 2AsH3(g)As2(g)+3H2(g) has Kp = 7.2107...Ch. 15 - Prob. 15.63SPCh. 15 - Calculate the value of the equilibrium constant at...Ch. 15 - Prob. 15.65SPCh. 15 - An equilibrium mixture of PCI5, PCi3, and Cl2 at a...Ch. 15 - The partial pressures in an equilibrium mixture of...Ch. 15 - At 298 K, Kc is 2.2105 for the reaction F (g) + O2...Ch. 15 - At 298 K, Kp is 1.6106 for the reaction...Ch. 15 - Prob. 15.70SPCh. 15 - Prob. 15.71SPCh. 15 - Prob. 15.72SPCh. 15 - Prob. 15.73SPCh. 15 - For each of the following equilibria, write the...Ch. 15 - For each of the following equilibria, write the...Ch. 15 - When the following reactions come to equilibrium,...Ch. 15 - Prob. 15.77SPCh. 15 - A chemical engineer is studying reactions to...Ch. 15 - Prob. 15.79SPCh. 15 - At 1400 K, Kc = 103 for the reaction...Ch. 15 - The first step in the industrial synthesis of...Ch. 15 - Phosphine (PH3) decomposes at elevated...Ch. 15 - Prob. 15.83SPCh. 15 - Calculate the equilibrium concentrations of N2O4...Ch. 15 - Calculate the equilibrium concentrations at 25 °C...Ch. 15 - A sample of HI (9.30 103 mol) was placed in an...Ch. 15 - The industrial solvent ethyl acetate is produced...Ch. 15 - Prob. 15.88SPCh. 15 - Prob. 15.89SPCh. 15 - The following reaction, which has Kc = 0.145 at...Ch. 15 - An equilibrium mixture of N2, H2, and NH1 at 700 K...Ch. 15 - An equilibrium mixture of O2 , SO2 , and SO4...Ch. 15 - The air pollutant NO is produced in automobile...Ch. 15 - Prob. 15.94SPCh. 15 - Prob. 15.95SPCh. 15 - Prob. 15.96SPCh. 15 - Prob. 15.97SPCh. 15 - Prob. 15.98SPCh. 15 - The reaction of iron (III) oxide with carbon...Ch. 15 - The equilibrium concentrations in a gas mixture at...Ch. 15 - Prob. 15.101SPCh. 15 - Prob. 15.102SPCh. 15 - Prob. 15.103SPCh. 15 - Prob. 15.104SPCh. 15 - Prob. 15.105SPCh. 15 - At 100 °C, K = 4.72 for the reaction...Ch. 15 - At 25 °C, Kc = 216 for the reaction...Ch. 15 - At 500 °C, F2 , gas is stable and does not...Ch. 15 - Prob. 15.109SPCh. 15 - Phosgene ( COCl2 ) is a toxic gas that damages the...Ch. 15 - Prob. 15.111SPCh. 15 - At 45 °C, Kc = 0.6 19 for the reaction...Ch. 15 - Prob. 15.113SPCh. 15 - Prob. 15.114SPCh. 15 - Prob. 15.115SPCh. 15 - Prob. 15.116SPCh. 15 - Prob. 15.117SPCh. 15 - Consider the following equilibrium:...Ch. 15 - Will the concentration of NO2 increase, decrease,...Ch. 15 - When each of the following equilibria is disturbed...Ch. 15 - Prob. 15.121SPCh. 15 - For the water-gas shift reaction...Ch. 15 - Prob. 15.123SPCh. 15 - Consider the exothermic reaction...Ch. 15 - Prob. 15.125SPCh. 15 - Methanol ( CH3OH ) is manufactured by the reaction...Ch. 15 - In the gas phase at 400°C, isopropyl alcohol...Ch. 15 - The following reaction is important in gold...Ch. 15 - Prob. 15.129SPCh. 15 - The equilibrium constant Kp for the reaction...Ch. 15 - Prob. 15.131SPCh. 15 - Prob. 15.132SPCh. 15 - Consider the following gas-phase reaction:...Ch. 15 - Prob. 15.134SPCh. 15 - Prob. 15.135SPCh. 15 - Prob. 15.136SPCh. 15 - Prob. 15.137SPCh. 15 - Prob. 15.138SPCh. 15 - Prob. 15.139SPCh. 15 - Prob. 15.140SPCh. 15 - Prob. 15.141SPCh. 15 - Prob. 15.142SPCh. 15 - Prob. 15.143SPCh. 15 - Prob. 15.144MPCh. 15 - Prob. 15.145MPCh. 15 - Refining petroleum involves cracking large...Ch. 15 - At 1000 K, Kp = 2.1 106 and H ° = -107.7 kJ for...Ch. 15 - Consider the gas-phase decomposition of...Ch. 15 - Prob. 15.149MPCh. 15 - Prob. 15.150MPCh. 15 - Prob. 15.151MPCh. 15 - Prob. 15.152MPCh. 15 - Prob. 15.153MPCh. 15 - Prob. 15.154MPCh. 15 - A 125.4 g quantity of water and an equal molar...Ch. 15 - Prob. 15.156MPCh. 15 - Prob. 15.157MPCh. 15 - Prob. 15.158MPCh. 15 - Prob. 15.159MPCh. 15 - Ozone is unstable with respect to decomposition to...Ch. 15 - Prob. 15.161MPCh. 15 - For the decomposition reaction...Ch. 15 - Prob. 15.163MP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Write a chemical equation for an equilibrium system that would lead to the following expressions (ad) for K. (a) K=(PH2S)2 (PO2)3(PSO2)2 (PH2O)2 (b) K=(PF2)1/2 (PI2)1/2PIF (c) K=[ Cl ]2(Pcl2)[ Br ]2 (d) K=(PNO)2 (PH2O)4 [ Cu2+ ]3[ NO3 ]2 [ H+ ]8arrow_forwardWrite an equation for an equilibrium system that would lead to the following expressions (ac) for K. (a) K=(Pco)2 (PH2)5(PC2H6)(PH2O)2 (b) K=(PNH3)4 (PO2)5(PNO)4 (PH2O)6 (c) K=[ ClO3 ]2 [ Mn2+ ]2(Pcl2)[ MNO4 ]2 [ H+ ]4 ; liquid water is a productarrow_forwardBecause calcium carbonate is a sink for CO32- in a lake, the student in Exercise 12.39 decides to go a step further and examine the equilibrium between carbonate ion and CaCOj. The reaction is Ca2+(aq) + COj2_(aq) ** CaCO,(s) The equilibrium constant for this reaction is 2.1 X 10*. If the initial calcium ion concentration is 0.02 AI and the carbonate concentration is 0.03 AI, what are the equilibrium concentrations of the ions? A student is simulating the carbonic acid—hydrogen carbonate equilibrium in a lake: H2COj(aq) H+(aq) + HCO}‘(aq) K = 4.4 X 10"7 She starts with 0.1000 AI carbonic acid. What are the concentrations of all species at equilibrium?arrow_forward
- What is the law of mass action? Is it true that the value of K depends on the amounts of reactants and products mixed together initially? Explain. Is it true that reactions with large equilibrium constant values are very fast? Explain. There is only one value of the equilibrium constant for a particular system at a particular temperature, but there is an infinite number of equilibrium positions. Explain.arrow_forwardWrite equilibrium constant expressions for the following reactions. For gases, use either pressures or concentrations. (a) 2 H2O2(g) 2 H2O(g) + O2(g) (b) CO(g) + O2g CO2(g) (c) C(s) + CO2(g) 2 CO(g) (d) NiO(s) + CO(g) Ni(s) + CO2(g)arrow_forwardFor the reaction N2(g)+3H2(g)2NH3(g) show that Kc = Kp(RT)2 Do not use the formula Kp = Kc(RT)5n given in the text. Start from the fact that Pi = [i]RT, where Pi is the partial pressure of substance i and [i] is its molar concentration. Substitute into Kc.arrow_forward
- At room temperature, the equilibrium constant Kc for the reaction 2 NO(g) ⇌ N2(g) + O2(g) is 1.4 × 1030. Is this reaction product-favored or reactant-favored? Explain your answer. In the atmosphere at room temperature the concentration of N2 is 0.33 mol/L, and the concentration of O2 is about 25% of that value. Calculate the equilibrium concentration of NO in the atmosphere produced by the reaction of N2 and O2. How does this affect your answer to Question 11?arrow_forwardSuppose a reaction has the equilibrium constant K = 1.3 108. What does the magnitude of this constant tell you about the relative concentrations of products and reactants that will be present once equilibrium is reached? Is this reaction likely to be a good source of the products?arrow_forward1. Graphite and carbon dioxide are kept at constant volume at 1000 K until the reaction C(graphite) + CO2(g) ⇄ 2 CO(g) has come to equilibrium. At this temperature, kc = 0.021. The initial concentration of CO2 is 0.012 mol/L. Calculate the equilibrium concentration of CO. 0.012 M 0.011 M 0.0057 Marrow_forward
- 1. Which of the following is the correct form of the equilibrium constant expression for the decomposition of SO3 to SO2 and O2? Kc = [SO2][O2]/[SO3] Kc = [SO2]2[O2]/[SO3]2 Kc = [SO3]2/[SO2]2[O2] Kc = [SO2][O2]2arrow_forwardThe decomposition of PCl5(g) to form PCl3(g) and Cl2(g) has Kc = 33.3 at a high temperature. If the initial concentration of PCl5 is 0.1000 M, what are the equilibrium concentrations of the reactants and products?arrow_forwardConsider 0.200 mol phosphorus pentachloride sealed in a 2.0-L container at 620 K. The equilibrium constant, Kc, is 0.60 for PCl5(g) PCl3(g) + Cl2(g) Calculate the concentrations of all species after equilibrium has been reached.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningChemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStaxChemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
Chemical Equilibria and Reaction Quotients; Author: Professor Dave Explains;https://www.youtube.com/watch?v=1GiZzCzmO5Q;License: Standard YouTube License, CC-BY