The following data are given at 1000K: CO ( g ) +H 2 O ( g ) ⇌ CO 2 ( g ) +H 2 ( g ) ; Δ t H°=-42kJ mol -1 ;K z =0 .66 . After an initial equilibrium is established in a 1.00L container, the equilibrium amount of H 2 can be increased by (a) adding a catalyst; (b) increasing the temperature; (c) transferring the mixture to a 10.0 L container; (d) in some way other than (a), (b), or (c).
The following data are given at 1000K: CO ( g ) +H 2 O ( g ) ⇌ CO 2 ( g ) +H 2 ( g ) ; Δ t H°=-42kJ mol -1 ;K z =0 .66 . After an initial equilibrium is established in a 1.00L container, the equilibrium amount of H 2 can be increased by (a) adding a catalyst; (b) increasing the temperature; (c) transferring the mixture to a 10.0 L container; (d) in some way other than (a), (b), or (c).
Solution Summary: The author explains Le Chatelier's principle that if a change in the temperature, pressure or concentration of the system takes place, the equilibrium shifts to the direction to counteract the changes.
The following data are given at
1000K:
CO
(
g
)
+H
2
O
(
g
)
⇌
CO
2
(
g
)
+H
2
(
g
)
;
Δ
t
H°=-42kJ
mol
-1
;K
z
=0
.66
. After an initial equilibrium is established in a 1.00L container, the equilibrium amount of
H
2
can be increased by (a) adding a catalyst; (b) increasing the temperature; (c) transferring the mixture to a 10.0 L container; (d) in some way other than (a), (b), or (c).
Shown below are five NMR spectra for five different C6H10O2 compounds. For each spectrum, draw the structure of the compound, and assign the spectrum by labeling H's in your structure (or in a second drawing of the structure) with the chemical shifts of the corresponding signals (which can be estimated to nearest 0.1 ppm). IR information is also provided. As a reminder, a peak near 1700 cm-1 is consistent with the presence of a carbonyl (C=O), and a peak near 3300 cm-1 is consistent with the presence of an O–H.
Extra information: For C6H10O2 , there must be either 2 double bonds, or 1 triple bond, or two rings to account for the unsaturation. There is no two rings for this problem.
A strong band was observed in the IR at 1717 cm-1
Predict the major products of the organic reaction below.
: ☐
+
Х
ك
OH
1. NaH
2. CH₂Br
Click and drag to start
drawing a structure.
NG
NC
15Show all the steps you would use to synthesize the following products shown below using
benzene and any organic reagent 4 carbons or less as your starting material in addition to
any inorganic reagents that you have learned.
NO 2
NC
SO3H
NO2
OH
Chapter 15 Solutions
General Chemistry: Principles And Modern Applications Plus Mastering Chemistry With Pearson Etext -- Access Card Package (11th Edition)
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