The structure with stereochemistry of the product formed when dimethylbutynedioate undergoes Diels-Alder reaction with (2E,4E) 2.4-hexadiene is to be given. Concept introduction: In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond and if the diene adapts a s-cis conformation during the reaction. To give: The structure and stereochemistry of the product formed when dimethylbutynedioate undergoes Diels-Alder reaction with (2E,4E) 2,4-hexadiene.

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Chapter 14.SE, Problem 62AP

Interpretation Introduction

Interpretation:

The structure with stereochemistry of the product formed when dimethylbutynedioate undergoes Diels-Alder reaction with (2E,4E) 2.4-hexadiene is to be given.

Concept introduction:

In Diels-Alder reaction, a dienophile reacts with a diene to yield a cyclic adduct. The reaction takes place through 1,4 addition of the dienophile into the diene through a cyclic transition state. These reactions occur rapidly with dienophiles having electron withdrawing substituent groups in conjugation with the double bond and if the diene adapts a s-cis conformation during the reaction.

To give:

The structure and stereochemistry of the product formed when dimethylbutynedioate undergoes Diels-Alder reaction with (2E,4E) 2,4-hexadiene.

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