The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined. Concept Introduction : Mass spectroscopy : It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule. Molecular formula: It represents the types of atoms with their total number present in a given molecule. Molecular ion peak (M) + · : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value. Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

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Answer 1

Question

Chapter 14.9, Problem 19CC

(a)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

(b)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

(c)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

(d)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

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20.17 Predict the structure of the major product formed by 1,2-addition of HBr to 3-methylenecyclohexene. 3-Methylenecyclohexene 20.18 Predict the major product formed by 1,4-addition of HBr to 3-methylenecyclohexene.

+ Draw a vicinal alkyl bromide that would produce the following alkene in an E2 elimination. Use a dash or wedge bond to indicate stereochemistry on asymmetric centers, where applicable. Ignore any inorganic byproducts. Br Drawing Strong Base H Q Atoms, Bonds Charges and Rings Draw or tap a new bond to see suggestions. Remove Done 語 Reset Undo + Drag To Pan

Draw a vicinal alkyl bromide that would produce the following alkene in an E2 elimination. Use a dash or wedge bond to indicate stereochemistry on asymmetric centers, where applicable. Ignore any inorganic byproducts. + Drawing Į Strong Base H Br Q Atoms, Bonds and Rings Charges Draw or tap a new bond to see suggestions. Undo Reset 謂 Remove Done Drag To Pan +

Answer 2

Question

Chapter 14.9, Problem 19CC

(a)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

(b)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

(c)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

(d)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

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Answer 3

Question

Chapter 14.9, Problem 19CC

(a)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

(b)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

(c)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

(d)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

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Answer 4

Question

Chapter 14.9, Problem 19CC

(a)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

(b)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

(c)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

(d)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

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Answer 5

Chapter 14.9, Problem 19CC

(a)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

(b)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

(c)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

(d)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

Answer 6

Chapter 14.9, Problem 19CC

(a)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

Answer 7

Chapter 14.9, Problem 19CC

(a)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The molecular weight and the expected value for the molecular ion peak in mass spectrum for the given set of compounds should be determined.

Concept Introduction:

Mass spectroscopy: It is a form of spectroscopic technique which is used for the elucidation of the molecular formula and molecular weight of the compound, depending upon the mass of the molecule.

Molecular formula: It represents the types of atoms with their total number present in a given molecule.

Molecular ion peak $(M)+·$ : It is defined as the heaviest peak in the IR spectrum of the molecule which represents the largest molecular ion in the given molecule with greater m/z value.

Nitrogen Rule: It says that the molecule with odd molecular weight denotes the presence of odd number of nitrogen atoms in the molecule and the molecule with even molecular weight determines the absence or the presence of even number of nitrogen atoms present in the molecule.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 14.3 - Prob. 1CC Ch. 14.3 - Prob. 2CC Ch. 14.3 - Prob. 3CC Ch. 14.3 - Prob. 4CC Ch. 14.4 - Prob. 5CC Ch. 14.4 - Prob. 6CC Ch. 14.4 - Prob. 7CC Ch. 14.5 - Prob. 8CC Ch. 14.5 - Prob. 9CC Ch. 14.5 - Prob. 10CC

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Chapter 14 Solutions