Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337670418
Author: Kotz
Publisher: Cengage
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Chapter 14.7, Problem 2.3ACP
Interpretation Introduction
Interpretation: Explanation has to be given for the given why termolecular reactions are likely to be slowest.
Concept Introduction:
Molecularity of the reaction is the number of molecules that is seen on the reactant side of an elementary reaction.
The reaction that involves in one reactant molecule is unimolecular reaction.
The reaction that involves in two reactant molecules is bimolecular reaction.
The reaction that involves in three reactant molecules is termolecular reaction.
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1,
How many signals do you expect in the H NMR spectrum for this molecule?
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red.
Note for advanced students: In this question, any multiplet is counted as one signal.
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional Hs to color in top
molecule
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute.
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional Hs to color in bottom
molecule
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Incorrect
Row 2: Your answer is incorrect.
Consider this molecule:
How many H atoms are in this molecule?
22
How many different signals could be found in its 'H NMR spectrum?
12
Note: A multiplet is considered one signal.
13
How many signals would you expect to see in the
Check
O
signal(s)
X
§
'C NMR spectrum for the following compound?
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Chapter 14 Solutions
Chemistry & Chemical Reactivity
Ch. 14.1 - Sucrose decomposes to fructose and glucose in acid...Ch. 14.1 - What are the relative rates of appearance or...Ch. 14.3 - The initial rate ( [NO]/ t] of the reaction of...Ch. 14.3 - The rate constant, k, at 25 C is 0.27/h for the...Ch. 14.4 - Sucrose, a sugar, decomposes in acid solution to...Ch. 14.4 - Gaseous azomethane (CH3N2CH3) decomposes to ethane...Ch. 14.4 - Prob. 14.7CYUCh. 14.4 - The catalyzed decomposition of hydrogen peroxide...Ch. 14.4 - Americium is used in smoke detectors and in...Ch. 14.5 - Prob. 14.10CYU
Ch. 14.5 - The colorless gas N2O4, decomposes to the brown...Ch. 14.7 - Nitrogen monoxide is reduced by hydrogen to give...Ch. 14.7 - Prob. 14.13CYUCh. 14.7 - One possible mechanism for the decomposition of...Ch. 14.7 - Prob. 1.1ACPCh. 14.7 - Prob. 1.2ACPCh. 14.7 - Prob. 2.1ACPCh. 14.7 - Prob. 2.2ACPCh. 14.7 - Prob. 2.3ACPCh. 14.7 - Determine the activation energy for the reaction...Ch. 14 - Give the relative rates of disappearance of...Ch. 14 - Give the relative rates of disappearance of...Ch. 14 - In the reaction 2 O3(g) 3 O2(g), the rate of...Ch. 14 - In the synthesis of ammonia, if [H2]/t = 4.5 104...Ch. 14 - Experimental data are listed here for the reaction...Ch. 14 - Phenyl acetate, an ester, reacts with water...Ch. 14 - Using the rate equation Rate = k[A]2[B], define...Ch. 14 - A reaction has the experimental rate equation Rate...Ch. 14 - The reaction between ozone and nitrogen dioxide at...Ch. 14 - Nitrosyl bromide, NOBr, is formed from NO and Br2:...Ch. 14 - The data in the table are for the reaction of NO...Ch. 14 - The reaction 2 NO(g) + 2 H2(g) N2(g) + 2 H2O(g)...Ch. 14 - Data for the reaction NO(g) + O2(g) NO2(g) are...Ch. 14 - Data for the following reaction are given in the...Ch. 14 - The rate equation for the hydrolysis of sucrose to...Ch. 14 - The decomposition of N2O5 in CCl4 is a first-order...Ch. 14 - The decomposition of SO2Cl2 is a first-order...Ch. 14 - The conversion of cyclopropane to propene (Example...Ch. 14 - Hydrogen peroxide, H2O2(aq), decomposes to H2O()...Ch. 14 - The decomposition of nitrogen dioxide at a high...Ch. 14 - At 573 K, gaseous NO2(g) decomposes, forming NO(g)...Ch. 14 - The dimerization of butadiene, C4H6, to form...Ch. 14 - The decomposition of ammonia on a metal surface to...Ch. 14 - Hydrogen iodide decomposes when heated, forming...Ch. 14 - The rate equation for the decomposition of N2O5...Ch. 14 - Gaseous azomethane, CH3N=NCH3, decomposes in a...Ch. 14 - The decomposition of SO2Cl2 SO2Cl2(g) SO2(g) +...Ch. 14 - The compound Xe(CF3)2 decomposes in a first-order...Ch. 14 - The radioactive isotope 64Cu is used in the form...Ch. 14 - Radioactive gold-198 is used in the diagnosis of...Ch. 14 - Prob. 31PSCh. 14 - Ammonia decomposes when heated according to the...Ch. 14 - Gaseous NO2 decomposes at 573 K. NO2(g) NO(g) + ...Ch. 14 - The decomposition of HOF occurs at 25 C. HOF(g) ...Ch. 14 - Prob. 35PSCh. 14 - Prob. 36PSCh. 14 - Calculate the activation energy, Ea, for the...Ch. 14 - If the rate constant for a reaction triples when...Ch. 14 - When healed lo a high temperature, cyclobutane,...Ch. 14 - When heated, cyclopropane is converted to propene...Ch. 14 - The reaction of H2 molecules with F atoms H2(g) +...Ch. 14 - Prob. 42PSCh. 14 - Compare the lock-and-key and induced-fit models...Ch. 14 - Prob. 44PSCh. 14 - Prob. 45PSCh. 14 - The enzyme carbonic anhydrase catalyzes the...Ch. 14 - What is the rate law for each of the following...Ch. 14 - What is the rate law for each of the following...Ch. 14 - Ozone, O3, in the Earths upper atmosphere...Ch. 14 - The reaction of NO2(g) and CO(g) is thought to...Ch. 14 - A proposed mechanism for the reaction of NO2 and...Ch. 14 - The mechanism for the reaction of CH3OH and HBr is...Ch. 14 - A reaction has the following experimental rate...Ch. 14 - For a first-order reaction, what fraction of...Ch. 14 - Prob. 55GQCh. 14 - Data for the following reaction are given in the...Ch. 14 - Formic acid decomposes at 550 C according to the...Ch. 14 - Isomerization of CH3NC occurs slowly when CH3NC is...Ch. 14 - When heated, tetrafluoroethylene dimerizes to form...Ch. 14 - Data in the table were collected at 540 K for the...Ch. 14 - Ammonium cyanate, NH4NCO, rearranges in water to...Ch. 14 - Prob. 62GQCh. 14 - At temperatures below 500 K, the reaction between...Ch. 14 - Nitryl fluoride can be made by treating nitrogen...Ch. 14 - The decomposition of dinitrogen pentaoxide N2O5(g)...Ch. 14 - The data in the table give the temperature...Ch. 14 - The decomposition of gaseous dimethyl ether at...Ch. 14 - The decomposition of phosphine, PH3, proceeds...Ch. 14 - The thermal decomposition of diacetylene, C4H2,...Ch. 14 - Prob. 70GQCh. 14 - The ozone in the Earths ozone layer decomposes...Ch. 14 - Hundreds of different reactions occur in the...Ch. 14 - Data for the reaction [Mn(CO)5(CH3CN)]+ + NC5H5 ...Ch. 14 - The gas-phase reaction 2 N2O5(g) 4 NO2(g) + O2(g)...Ch. 14 - Prob. 75GQCh. 14 - The decomposition of SO2Cl2 to SO2 and Cl2 is...Ch. 14 - The decomposition of nitrogen dioxide at a high...Ch. 14 - Prob. 78GQCh. 14 - Egg protein albumin is precipitated when an egg is...Ch. 14 - A The compound 1,3-butadiene (C4H6) forms...Ch. 14 - Hypofluorous acid, HOF, is very unstable,...Ch. 14 - We know that the decomposition of SO2Cl2 is...Ch. 14 - Nitramide, NO2NH2, decomposes slowly in aqueous...Ch. 14 - Prob. 84GQCh. 14 - The color change accompanying the reaction of...Ch. 14 - Prob. 87ILCh. 14 - Prob. 88ILCh. 14 - The oxidation of iodide ion by the hypochlorite...Ch. 14 - The acid-catalyzed iodination of acetone...Ch. 14 - Prob. 91SCQCh. 14 - The following statements relate to the reaction...Ch. 14 - Chlorine atoms contribute to the destruction of...Ch. 14 - Prob. 95SCQCh. 14 - Prob. 96SCQCh. 14 - The reaction cyclopropane propene occurs on a...Ch. 14 - Prob. 98SCQCh. 14 - Examine the reaction coordinate diagram given...Ch. 14 - Draw a reaction coordinate diagram for an...Ch. 14 - Consider the reaction of ozone and nitrogen...
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- 13 Consider the "C NMR spectrum below. 140 120 100 80 60 40 20 20 PPM 0 The spectrum belongs to which one of the following constitutional isomers of the compound C,H12? Select the single best answer. Check ✓ G Save For Later 2025 McGraw Hill LLC. All Rights Reserved. Terms of Usearrow_forwardThe structure of compound 1,3,5-trimethylbenzene (mesitylene) is given below. How many signals would you expect to find in the 'H NMR spectrum of 1,3,5-trimethylbenzene (mesitylene)? Check ×arrow_forward1 How many signals do you expect in the 'H NMR spectrum for this molecule? CI CI Cl Write the answer in the table below. Also, in each of the drawing areas below is a copy of the molecule, with H atoms shown. In each copy, one of the H atoms is highlighted red. Highlight in red all other H atoms that would contribute to the same signal as the H already highlighted red. Note for advanced students: Remember, a multiplet is considered one signal in the 'H NMR spectrum. 1 Number of signals in the 'H NMR spectrum. ☐ For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. No additional H atoms to highlight in top molecule For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at…arrow_forward
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