The synthesis of the given ether by Williamson synthesis methods using any alcohol or phenol. Interpretation: The synthesis of the given ethers by Williamson synthesis using any alcohol and phenol is to be stated. Concept introduction: The reaction of an alkoxide ion with 1 ° alkyl halide through S N 2 mechanism to form ether is known as Williamson synthesis.

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Answer 1

Question

Chapter 14.5, Problem 14.9P

(a)

Interpretation Introduction

To determine: The synthesis of the given ether by Williamson synthesis methods using any alcohol or phenol.

Interpretation: The synthesis of the given ethers by Williamson synthesis using any alcohol and phenol is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(b)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(c)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(d)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(e)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

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3. Consider the compounds below and determine if they are aromatic, antiaromatic, or non-aromatic. In case of aromatic or anti-aromatic, please indicate number of I electrons in the respective systems. (Hint: 1. Not all lone pair electrons were explicitly drawn and you should be able to tell that the bonding electrons and lone pair electrons should reside in which hybridized atomic orbital 2. You should consider ring strain- flexibility and steric repulsion that facilitates adoption of aromaticity or avoidance of anti- aromaticity) H H N N: NH2 N Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic TT electrons Me H Me Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic πT electrons H HH…

A chemistry graduate student is studying the rate of this reaction: 2 HI (g) →H2(g) +12(g) She fills a reaction vessel with HI and measures its concentration as the reaction proceeds: time (minutes) [IH] 0 0.800M 1.0 0.301 M 2.0 0.185 M 3.0 0.134M 4.0 0.105 M Use this data to answer the following questions. Write the rate law for this reaction. rate = 0 Calculate the value of the rate constant k. k = Round your answer to 2 significant digits. Also be sure your answer has the correct unit symbol.

Answer 2

Question

Chapter 14.5, Problem 14.9P

(a)

Interpretation Introduction

To determine: The synthesis of the given ether by Williamson synthesis methods using any alcohol or phenol.

Interpretation: The synthesis of the given ethers by Williamson synthesis using any alcohol and phenol is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(b)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(c)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(d)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(e)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

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Answer 3

Question

Chapter 14.5, Problem 14.9P

(a)

Interpretation Introduction

To determine: The synthesis of the given ether by Williamson synthesis methods using any alcohol or phenol.

Interpretation: The synthesis of the given ethers by Williamson synthesis using any alcohol and phenol is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(b)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(c)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(d)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(e)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

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Answer 4

Question

Chapter 14.5, Problem 14.9P

(a)

Interpretation Introduction

To determine: The synthesis of the given ether by Williamson synthesis methods using any alcohol or phenol.

Interpretation: The synthesis of the given ethers by Williamson synthesis using any alcohol and phenol is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(b)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(c)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(d)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(e)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

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Answer 5

Chapter 14.5, Problem 14.9P

(a)

Interpretation Introduction

To determine: The synthesis of the given ether by Williamson synthesis methods using any alcohol or phenol.

Interpretation: The synthesis of the given ethers by Williamson synthesis using any alcohol and phenol is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(b)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(c)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(d)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(e)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

Answer 6

Chapter 14.5, Problem 14.9P

(a)

Interpretation Introduction

To determine: The synthesis of the given ether by Williamson synthesis methods using any alcohol or phenol.

Interpretation: The synthesis of the given ethers by Williamson synthesis using any alcohol and phenol is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

Answer 7

Chapter 14.5, Problem 14.9P

(a)

Interpretation Introduction

To determine: The synthesis of the given ether by Williamson synthesis methods using any alcohol or phenol.

Interpretation: The synthesis of the given ethers by Williamson synthesis using any alcohol and phenol is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

Answer 8

(b)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

Answer 9

(b)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

Answer 10

(c)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

Answer 11

(c)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

Answer 12

(d)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

Answer 13

(d)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

Answer 14

(e)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

Answer 15

(e)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 14.2C - Rank the given solvents in decreasing order of...Ch. 14.2D - Prob. 14.2P Ch. 14.2D - In the presence of 18-crown-6, potassium...Ch. 14.3B - Give a common name (when possible) and a...Ch. 14.3C - Prob. 14.5P Ch. 14.3C - Name the following heterocyclic ethers.Ch. 14.4 - Propose a fragmentation to account for each...Ch. 14.5 - Prob. 14.8P Ch. 14.5 - Prob. 14.9P Ch. 14.6 - Prob. 14.10P

Solution Summary: The author explains that the synthesis of the given ethers by Williamson is to be stated.

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Chapter 14 Solutions