Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Question
Chapter 14.4, Problem 7P
Interpretation Introduction
Interpretation:
Among the chlorination or bromination product for 2,3-dimethylbutane, the reaction which gives a greater yield of 1-halo-2,3-dimethylbutane should be determined.
Concept Introduction:
- In a halogenation reaction, one or more halogen atoms are introduced into an organic compound. Generally, these reactions are initiated in the presence of light or heat.
- Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.
- Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.
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Correctly name this compound using the IUPAC naming system by sorting the
components into the correct order.
Br
IN
Ν
H
How is the radical intermediate for this structure formed? Can you please draw arrows from the first radical to the resonance form that would result in this product? I'm lost.
Part VI.
(a) calculate the λ max of the compound using woodward - Fieser rules.
(b) what types of electronic transitions are present in the compound?
(c) what are the prominent peaks in the IR spectrum of the compound?
Chapter 14 Solutions
Essential Organic Chemistry (3rd Edition)
Ch. 14.2 - Write the mechanism for the monobromination of...Ch. 14.2 - Prob. 2PCh. 14.4 - Prob. 3PCh. 14.4 - Which of the hydrogens in the structure in the...Ch. 14.4 - How many alkyl chlorides can be obtained from...Ch. 14.4 - Prob. 7PCh. 14.5 - Prob. 9PCh. 14.6 - a. Which ether is most apt to form a peroxide? b....Ch. 14.7 - Prob. 11PCh. 14 - Prob. 12P
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