Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Textbook Question
Chapter 14.2, Problem 1P
Write the mechanism for the monobromination of ethane.
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Give the major organic product(s) of each of the following reactions or sequences of reactions. Show all
relevant stereochemistry. [two only]
CH3O
(11
HC-C-C-CH3
A.
CH3
12. NaOH
Diethyl malonate can be prepared by the following reaction sequence. Draw the structures of each of the
missing intermediates in the boxes provided.
17
1. Br PBr
H&C
OH 2 H₂O
CH3CH₂OH
На
NaCN
H₂SO4
NC.
CH CH₂OH
на
H₂O, heat
CH₂
OCHCH3
ཝསི། ཡིཀྑཱམུདྡྷནྟ
CH₂
OEt
The reaction of a carboxylic acid with an alcohol in the presence of acid is termed Fischer esterification.
OH + CH₂OH
На
B C
A. The nucleophile in this reaction is
B. Compound C functions as
a.
a base scavenger
b.
a solvent
C.
a catalyst
d.
a neutralizer
C. Fischer esterification is an example of: .
a. nucleophilic acyl addition
b. nucleophilic acyl substitution
c. nucleophilic acyl elimination
d. nucleophilic acyl rearrangement
in this reaction.
Chapter 14 Solutions
Essential Organic Chemistry (3rd Edition)
Ch. 14.2 - Write the mechanism for the monobromination of...Ch. 14.2 - Prob. 2PCh. 14.4 - Prob. 3PCh. 14.4 - Which of the hydrogens in the structure in the...Ch. 14.4 - How many alkyl chlorides can be obtained from...Ch. 14.4 - Prob. 7PCh. 14.5 - Prob. 9PCh. 14.6 - a. Which ether is most apt to form a peroxide? b....Ch. 14.7 - Prob. 11PCh. 14 - Prob. 12P
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