ALEKS 360 AC INTRD CHEM >I<
5th Edition
ISBN: 9781260977585
Author: BAUER
Publisher: MCG
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Question
Chapter 14, Problem 95QP
(a)
Interpretation Introduction
Interpretation:
The oxidized element in the given
(b)
Interpretation Introduction
Interpretation:
The reduced element in the given chemical reaction between methane and oxygen gas is to be determined.
(c)
Interpretation Introduction
Interpretation:
The number of moles of electron is to be determined for the combustion of each mole of methane.
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
4. For the following complexes, draw the structures and give a d-electron count of the
metal:
a) Tris(acetylacetonato)iron(III)
b) Hexabromoplatinate(2-)
c) Potassium diamminetetrabromocobaltate(III)
(6 points)
2. Calculate the overall formation constant for [Fe(CN)6]³, given that the overall formation
constant for [Fe(CN)6] 4 is ~1032, and that:
Fe3+ (aq) + e
= Fe²+ (aq)
E° = +0.77 V
[Fe(CN)6]³ (aq) + e¯ = [Fe(CN)6] (aq) E° = +0.36 V
(4 points)
Chapter 14 Solutions
ALEKS 360 AC INTRD CHEM >I<
Ch. 14 - Prob. 1QCCh. 14 - Prob. 2QCCh. 14 - How do chemical reactions provide electricity in...Ch. 14 - Prob. 4QCCh. 14 - Prob. 5QCCh. 14 - How do oxidation-reduction reactions generate...Ch. 14 - Prob. 7QCCh. 14 - Prob. 1PPCh. 14 - Assign oxidation numbers to each element in the...Ch. 14 - Prob. 3PP
Ch. 14 - Cadmium reacts with nickel(II) nitrate according...Ch. 14 - The reaction that occurs in most camera batteries...Ch. 14 - Prob. 6PPCh. 14 - Balance the following equation that occurs in...Ch. 14 - Prob. 8PPCh. 14 - Prob. 9PPCh. 14 - Prob. 1QPCh. 14 - Prob. 2QPCh. 14 - Prob. 3QPCh. 14 - Why is oxidation always coupled with reduction?Ch. 14 - Prob. 5QPCh. 14 - How do you know when something is reduced?Ch. 14 - When a strip of magnesium metal is placed in an...Ch. 14 - When a strip of nickel metal is placed in an...Ch. 14 - Consider the following reaction:...Ch. 14 - Consider the following reaction:...Ch. 14 - Prob. 11QPCh. 14 - Prob. 12QPCh. 14 - Indicate the oxidation number of each element in...Ch. 14 - Indicate the oxidation number of each element in...Ch. 14 - Prob. 15QPCh. 14 - Prob. 16QPCh. 14 - What is the oxidation number of phosphorus in each...Ch. 14 - Determine the oxidation number of chlorine in each...Ch. 14 - Indicate the oxidation number of phosphorus in...Ch. 14 - Determine the oxidation number of iodine in each...Ch. 14 - The ion shown has a charge of 2. What are the...Ch. 14 - The ion shown has a charge of 1. What are the...Ch. 14 - Prob. 23QPCh. 14 - Indicate the oxidation number of chromium in each...Ch. 14 - Determine the oxidation number of each element in...Ch. 14 - Determine the oxidation number of each element in...Ch. 14 - Determine the oxidation number of each element in...Ch. 14 - Prob. 28QPCh. 14 - Prob. 29QPCh. 14 - Prob. 30QPCh. 14 - Under certain conditions, nitrogen gas reacts with...Ch. 14 - Under certain conditions, solid carbon reacts with...Ch. 14 - Consider the following reaction:...Ch. 14 - In the following oxidation-reduction reactions,...Ch. 14 - In the following oxidation-reduction reactions,...Ch. 14 - Draw a diagram of a voltaic cell that corresponds...Ch. 14 - Draw a diagram of a voltaic cell that corresponds...Ch. 14 - The figure shows a molecular-level representation...Ch. 14 - The figure shows a molecular-level representation...Ch. 14 - The reaction that occurs in a lead-acid battery is...Ch. 14 - The reaction that occurs in a lead-acid battery is...Ch. 14 - The nickel-cadmium battery is used in portable...Ch. 14 - The zinc-silver oxide battery, although expensive,...Ch. 14 - Balance the following half-reactions....Ch. 14 - Balance the following half-reactions....Ch. 14 - For each of the following, write balanced...Ch. 14 - For each of the following, write balanced...Ch. 14 - Prob. 49QPCh. 14 - Prob. 50QPCh. 14 - Balance the following half-reactions, adding...Ch. 14 - Balance the following half-reactions, adding...Ch. 14 - Balance the following half-reactions, adding...Ch. 14 - Balance the following half-reactions, adding...Ch. 14 - Prob. 55QPCh. 14 - Complete and balance the following...Ch. 14 - Complete and balance the following...Ch. 14 - Complete and balance the following...Ch. 14 - Denitrification occurs when nitrogen in the soil...Ch. 14 - Prob. 60QPCh. 14 - Consider the partially labelled voltaic cell...Ch. 14 - Consider the partially labelled voltaic cell...Ch. 14 - Using the activity series in Figure 14.22, place...Ch. 14 - Using the activity series in Figure 14.22, place...Ch. 14 - What is electrolysis?Ch. 14 - Describe what happens at each electrode during the...Ch. 14 - Prob. 67QPCh. 14 - Prob. 68QPCh. 14 - Prob. 69QPCh. 14 - Prob. 70QPCh. 14 - Prob. 71QPCh. 14 - Prob. 72QPCh. 14 - Prob. 73QPCh. 14 - Prob. 74QPCh. 14 - If the chrome placing on an automobile bumper is...Ch. 14 - Prob. 76QPCh. 14 - Prob. 77QPCh. 14 - Prob. 78QPCh. 14 - Prob. 79QPCh. 14 - Prob. 80QPCh. 14 - Prob. 81QPCh. 14 - Prob. 82QPCh. 14 - Prob. 83QPCh. 14 - Prob. 84QPCh. 14 - Prob. 85QPCh. 14 - Prob. 86QPCh. 14 - Prob. 87QPCh. 14 - Prob. 88QPCh. 14 - Prob. 89QPCh. 14 - Prob. 90QPCh. 14 - Prob. 91QPCh. 14 - Prob. 92QPCh. 14 - Prob. 93QPCh. 14 - Prob. 94QPCh. 14 - Prob. 95QPCh. 14 - Prob. 96QPCh. 14 - Prob. 97QPCh. 14 - Prob. 98QPCh. 14 - Prob. 99QPCh. 14 - Prob. 100QPCh. 14 - Prob. 101QPCh. 14 - Prob. 102QPCh. 14 - Prob. 103QPCh. 14 - Prob. 104QPCh. 14 - Prob. 105QPCh. 14 - Prob. 106QPCh. 14 - Prob. 107QPCh. 14 - Prob. 108QPCh. 14 - Prob. 109QPCh. 14 - Prob. 110QP
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