Balance the following half-reactions, adding H + a q , H 2 O l , and electrons as appropriate. a Br 2 a q → Br − a q b H 2 O l → O 2 g c IO 3 − a q → I 2 a q d MnO 2 s → Mn 2 + a q
Balance the following half-reactions, adding H + a q , H 2 O l , and electrons as appropriate. a Br 2 a q → Br − a q b H 2 O l → O 2 g c IO 3 − a q → I 2 a q d MnO 2 s → Mn 2 + a q
Solution Summary: The author explains the skeleton equation for the half-reaction: H+(aq)stackrel
16. The proton NMR spectral information shown in this problem is for a compound with formula
CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec-
tral results, including DEPT-135 and DEPT-90 results, are tabulated:
7
J
Normal Carbon
DEPT-135
DEPT-90
19 ppm
Positive
No peak
122
Positive
Positive
cus
и
124
Positive
Positive
126
Positive
Positive
128
No peak
No peak
4°
129
Positive
Positive
130
Positive
Positive
(144
No peak
No peak
148
No peak
No peak
150
Positive
Positive
してし
3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing
mechanism below, but make sure to draw the product of each proposed step (3 points).
+ En
CN
CN
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Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell