The enzyme urease catalyzez the reaction of urea,( NH2CONH2), with water to produce carbon dioxide and ammonia. In water,without the enzyme, the reaction proceeds with a first-order rate constant of 4.15*10-5S-1 at 100 °C. in the presence of the enzyme in water, the reaction proceeds with a rate constant of 3.4*104 s-1 at 21 °C. (a) write out the balanced equation for the reaction catalyzed by urease. (b) if the rate of the catalyzed and uncatalyzed reactions? (c) in actuality,what would you expect for the rate of the catalyzed reaction at 100 C as compared to that at 21 °C? (d) on the basis of parts (c) and (d), what can you conclude about the difference in activation energies for the catalyzed and uncatalyzed reactions?
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Chapter 14 Solutions
CHEMISTRY THE CENTRAL SCIENCE 14TH EDI
- This thermodynamic cycle describes the formation of an ionic compound MX2 from a metal element M and nonmetal element X in their standard states. What is the lattice enthalpy of MX2 ? What is the enthalpy formation of MX2 ? Suppose both the heat of sublimation of M and the ionization enthalpy of M were smaller. Would MX2 be more stable? Or less? or impossible to tell without more information?arrow_forward7. Draw the mechanism to describe the following transformation: Note: This is a base catalyzed reaction. So, the last steps must make [OH]- OH [OH]¯ OH Heat Oarrow_forwardShow work with explanation...don't give Ai generated solutionarrow_forward
- Br. , H+ .OH Mg ether solvent H+, H₂O 17. Which one of the compounds below is the final product of the reaction sequence shown above? HO A HO HO OH D B OH HO OH C OH HO OH Earrow_forward8:57 PM Sun Jan 26 Content ← Explanation Page X Content X ALEKS Jade Nicol - Le A https://www-av C www-awa.aleks.com O States of Matter Understanding consequences of important physical properties of liquids ? QUESTION Liquid A is known to have a lower viscosity and lower surface tension than Liquid B. Use these facts to predict the result of each experiment in the table below, if you can. experiment Liquid A and Liquid B are each pumped through tubes with an inside diameter of 27.0 mm, and the pressures PA and PB needed to produce a steady flow of 2.4 mL/s are measured. 25.0 mL of Liquid A are poured into a beaker, and 25.0 mL of Liquid B are poured into an identical beaker. Stirrers in each beaker are connected to motors, and the forces FA and FB needed to stir each liquid at a constant rate are measured. predicted outcome OPA will be greater than PB OPA will be less than PB OPA will be equal to PB It's impossible to predict whether PA or PB will be greater without more information.…arrow_forwardShow work. Don't give Ai generated solutionarrow_forward
- 5. Please draw in the blanks the missing transition states and the correlated products. Explicitly display relevant absolute stereochemical configuration. MeOH I OMe H Endo transition state, dienophile approaching from the bottom of diene + H ཎྞཾ ཌཱརཱ༔,_o OMe H H OMe Endo transition state, dienophile approaching from the top of diene or from the bottom but horizontally flipped (draw one) + Exo transition state, dienophile approaching from the top of diene or from the bottom but horizontally flipped (draw one) Exo transition state, dienophile approaching from the top of diene or from the bottom but horizontally flipped (draw one) MeO H H MeO H MeO H MeO H Harrow_forwardH H (1) H C. C C .H (2) (3) Cl H The ideal value for bond angle (1) is (Choose one) and the ideal value for bond angle (3) is (Choose one) degrees, the value for bond angle (2) is (Choose one) degrees, degrees.arrow_forwardShow work.....don't give Ai generated solutionarrow_forward
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