To determine why 2-Pentanol is chiral and 3-Pentanol is not. Concept Introduction: A molecule is said to be chiral if it cannot be superimposed on its mirror image and if it does not possess an alternate axis of symmetry. A carbon atom bonded in a tetrahedral structure to four different substituents in a molecule, it is called as a chiral centre. If an organic molecule has more than one chiral carbon or chiral centre then the molecule may be achiral or chiral and it is depend upon whether the molecule has element of symmetry or not. The elements of symmetry are- A plane of symmetry A centre of symmetry n-fold alternating axis of symmetry

Question

Draw the major substitution products you would expect for the reaction shown below. If substitution would not occur at a significant rate under these conditions, check the box underneath the drawing area instead. Be sure you use wedge and dash bonds where necessary, for example to distinguish between major products. Note for advanced students: you can assume that the reaction mixture is heated mildly, somewhat above room temperature, but strong heat or reflux is not used. Cl Substitution will not occur at a significant rate. Explanation Check :☐ O-CH + Х Click and drag to start drawing a structure.

Answer 1

Question

Chapter 14, Problem 7P

Interpretation Introduction

Interpretation:

To determine why 2-Pentanol is chiral and 3-Pentanol is not.

Concept Introduction:

A molecule is said to be chiral if it cannot be superimposed on its mirror image and if it does not possess an alternate axis of symmetry.

A carbon atom bonded in a tetrahedral structure to four different substituents in a molecule, it is called as a chiral centre.

If an organic molecule has more than one chiral carbon or chiral centre then the molecule may be achiral or chiral and it is depend upon whether the molecule has element of symmetry or not.

The elements of symmetry are-

A plane of symmetry

A centre of symmetry

n-fold alternating axis of symmetry

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Draw the major substitution products you would expect for the reaction shown below. If substitution would not occur at a significant rate under these conditions, check the box underneath the drawing area instead. Be sure you use wedge and dash bonds where necessary, for example to distinguish between major products. Note for advanced students: you can assume that the reaction mixture is heated mildly, somewhat above room temperature, but strong heat or reflux is not used. Cl Substitution will not occur at a significant rate. Explanation Check :☐ O-CH + Х Click and drag to start drawing a structure.

Draw the major substitution products you would expect for the reaction shown below. If substitution would not occur at a significant rate under these conditions, check the box underneath the drawing area instead. Be sure you use wedge and dash bonds where necessary, for example to distinguish between major products. Note for advanced students: you can assume that the reaction mixture is heated mildly, somewhat above room temperature, but strong heat or reflux is not used. Cl C O Substitution will not occur at a significant rate. Explanation Check + O-CH3 Х Click and drag to start drawing a structure.

✓ aw the major substitution products you would expect for the reaction shown below. If substitution would not occur at a significant rate under these conditions, check the box underneath the drawing area instead. Be sure you use wedge and dash bonds where necessary, for example to distinguish between major products. Note for advanced students: you can assume that the reaction mixture is heated mildly, somewhat above room temperature, but strong heat or reflux is not used. C Cl HO–CH O Substitution will not occur at a significant rate. Explanation Check -3 ☐ : + D Click and drag to start drawing a structure. © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use Privacy Ce