
Organic Chemistry, 3e WileyPLUS Registration Card + Loose-leaf Print Companion
3rd Edition
ISBN: 9781119340577
Author: Klein
Publisher: Wiley (WileyPLUS Products)
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Chapter 14, Problem 77CP
Interpretation Introduction
Interpretation: The reasonable structure and mechanism of formation for the ion consistent with a peak at
Concept Introduction:
Mass spectrometry:
- It is a technique used to find out the molecular weight of the compounds and thus providing the structure and chemical properties of different molecules.
- The sample ion is converted into gaseous ions with or without fragmentation and are characterized by their charge to mass ratios and relative abundances.
- Mass spectrum is a plot of the relative abundance of the generated ions as a function of the charge to mass ratio.
Nitrogen rule:
- If the molecular weight is odd, then it indicates the odd number of nitrogen atoms in the compound.
- If the molecular weight is even, then it indicates the absence of nitrogen or an even number of nitrogen atoms.
McLafferty rearrangement:
- It is the fragmentation involves in
ketones andaldehydes . - A hydrogen atom has to be present at the gamma position in aldehydes and ketones in-order to undergo the fragmentation known as McLafferty rearrangement.
- The rearrangement results in the loss of a neutral
alkene fragment.
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2. Draw the missing structure(s) in each of the following reactions. The missing
structure(s) can be a starting material or the major reaction product(s).
C5H10
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CH2Cl2
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Draw the products of the stronger acid protonating the other reactant.
དའི་སྐད”“
H3C
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H3C
CH
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Draw the products of the stronger acid protonating the other reactant.
H3C
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NH2
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Product base
Chapter 14 Solutions
Organic Chemistry, 3e WileyPLUS Registration Card + Loose-leaf Print Companion
Ch. 14.3 - Prob. 1CCCh. 14.3 - Prob. 2CCCh. 14.3 - Prob. 3CCCh. 14.3 - Prob. 4CCCh. 14.4 - Prob. 5CCCh. 14.4 - Prob. 6CCCh. 14.4 - Prob. 7CCCh. 14.5 - Prob. 8CCCh. 14.5 - Prob. 9CCCh. 14.5 - Prob. 10CC
Ch. 14.5 - Prob. 11CCCh. 14.6 - Prob. 1LTSCh. 14.6 - Prob. 12PTSCh. 14.6 - Prob. 13ATSCh. 14.7 - Prob. 2LTSCh. 14.7 - Prob. 14PTSCh. 14.7 - Prob. 15ATSCh. 14.7 - Prob. 16ATSCh. 14.7 - Prob. 17ATSCh. 14.9 - Prob. 18CCCh. 14.9 - Prob. 19CCCh. 14.10 - Prob. 3LTSCh. 14.10 - Prob. 20PTSCh. 14.10 - Prob. 21ATSCh. 14.11 - Prob. 22CCCh. 14.11 - Prob. 23CCCh. 14.12 - Prob. 24CCCh. 14.12 - Prob. 25CCCh. 14.12 - Prob. 26CCCh. 14.12 - Prob. 27CCCh. 14.13 - Prob. 28CCCh. 14.13 - Prob. 29CCCh. 14.16 - Prob. 4LTSCh. 14.16 - Prob. 30PTSCh. 14.16 - Prob. 31PTSCh. 14.16 - Strigol is an important plant hormone that is...Ch. 14 - Prob. 33PPCh. 14 - Prob. 34PPCh. 14 - Prob. 35PPCh. 14 - Prob. 36PPCh. 14 - Prob. 37PPCh. 14 - Prob. 38PPCh. 14 - Prob. 39PPCh. 14 - Prob. 40PPCh. 14 - Prob. 41PPCh. 14 - Prob. 42PPCh. 14 - Prob. 43PPCh. 14 - The mass spectrum of 2-bromopentane shows many...Ch. 14 - Prob. 45PPCh. 14 - Prob. 46PPCh. 14 - Prob. 47PPCh. 14 - Prob. 48PPCh. 14 - Prob. 49PPCh. 14 - Prob. 50PPCh. 14 - Prob. 51PPCh. 14 - Prob. 52PPCh. 14 - Prob. 53PPCh. 14 - Prob. 54PPCh. 14 - Prob. 55PPCh. 14 - Prob. 56PPCh. 14 - Prob. 57IPCh. 14 - Prob. 58IPCh. 14 - Prob. 59IPCh. 14 - Prob. 60IPCh. 14 - Prob. 61IPCh. 14 - Prob. 62IPCh. 14 - Prob. 63IPCh. 14 - Prob. 64IPCh. 14 - Prob. 65IPCh. 14 - Prob. 66IPCh. 14 - Prob. 67IPCh. 14 - Prob. 68IPCh. 14 - Compound A exists in equilibrium with its...Ch. 14 - The following two isomers were each subjected to...Ch. 14 - Myosmine can be isolated from tobacco, along with...Ch. 14 - Prob. 72IPCh. 14 - Prob. 73IPCh. 14 - Prob. 74IPCh. 14 - Prob. 75IPCh. 14 - Prob. 76CPCh. 14 - Prob. 77CPCh. 14 - Prob. 78CPCh. 14 - Prob. 79CP
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