Chemistry In Focus
Chemistry In Focus
7th Edition
ISBN: 9781337670425
Author: Tro
Publisher: Cengage
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Chapter 14, Problem 40E
Interpretation Introduction

Interpretation:

The given statement “a health-related website recommended taking small amounts of iodine as antioxidant to prevent aging” is to be explained.

Concept Introduction:

Oxidation is the addition of an electronegative element or the removal of an electropositive element in a chemical reaction.

Reduction is the addition of an electropositive element or the removal of an electronegative element in a chemical reaction.

A chemical reaction in which oxidation process and reduction process take place simultaneously is called a redox reaction.

An oxidizing agent is a substance that has the capacity to oxidize the other substances and get reduced in a chemical reaction.

A reducing agent is a substance that has the capacity to reduce the other substances and get oxidized in a chemical reaction.

An antioxidant is a reducing agent. The reducing agent loses electrons easily in the chemical reaction. It reduces the other substances and gets oxidized in the oxidation-reduction reaction.

Iodine is an oxidizing agent. So, iodine will not work as an antioxidant.

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The SN 1 mechanism starts with the rate-determining step which is the dissociation of the alkyl halide into a carbocation and a halide ion. The next step is the rapid reaction of the carbocation intermediate with the nucleophile; this step completes the nucleophilic substitution stage. The step that follows the nucleophilic substitution is a fast acid-base reaction. The nucleophile now acts as a base to remove the proton from the oxonium ion from the previous step, to give the observed product. Draw a curved arrow mechanism for the reaction, adding steps as necessary. Be sure to include all nonzero formal charges. Cl: Add/Remove step G Click and drag to start drawing a structure.

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