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Which of the following gas samples would have the largest volume, if all samples are at the same temperature and pressure? (a)
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Chapter 14 Solutions
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- Pyruvic acid, HC3H3O3, is involved in cell metabolism. It can be assayed for (that is, the amount of it determined) by using a yeast enzyme. The enzyme makes the following reaction go to completion: HC3H3O3(aq)C2H4O(aq)+CO2(g) If a sample containing pyruvic acid gives 21.2 mL of carbon dioxide gas, CO2, at 349 mmHg and 30C, how many grams of pyruvic acid are there in the sample?arrow_forwardHow does hydraulic fracturing differ from previously used techniques for the recovery of natural gas from the earth?arrow_forwardGiven that a sample of air is made up of nitrogen, oxygen, and argon in the mole fractions 0.78 N2, 0.21 O2, and 0.010 Ar, what is the density of air at standard temperature and pressure?arrow_forward
- When calcium carbonate is heated strongly, it evolves carbon dioxide gas. CaCO3(s)CaO(s)+CO2(g) 25 g of CaCO3 is heated, what mass of CO2would be produced? What volume would this quantity of CO2 (CU at STP?arrow_forwardA mixture contained zinc sulfide, ZnS, and lead sulfide, PbS. A sample of the mixture weighing 6.12 g was reacted with an excess of hydrochloric acid. The reactions are ZnS(s)+2HCL(aq)ZnCl2(aq)+H2S(g)PbS(s)+2HCL(aq)PbCl2(aq)+H2S(g) If the sample reacted completely and produced 1.049 L of hydrogen sulfide, H2S, at 23C and 762 mmHg, what were the percentages of ZnS and PbS in the mixture?arrow_forwardYou have a gas, one of the three known phosphorus-fluorine compounds (PF3, PF3, and P2F4). To find out which, you have decided to measure its molar mass. (a) First, yon determine that the density of the gas is 5.60 g/L at a pressure of 0.971 atm and a temperature of 18.2 C. Calculate the molar mass and identify the compound. (b) To check the results from part (a), you decide to measure the molar mass based on the relative rales of effusion of the unknown gas and CO2. You find that CO2 effuses at a rate of 0.050 mol/min, whereas the unknown phosphorus fluoride effuses at a rate of 0.028 mol/min. Calculate the molar mass of the unknown gas based on these results.arrow_forward
- A student prepares phosphorous acid, H3PO3, by reacting solid phosphorus triiodide with water. PI3(s)+3H2O(l)H3PO3(s)+3HI(g) The student needs to obtain 0.250 L of H3PO3(d=1.651g/cm3). The procedure calls for a 45.0% excess of water and a yield of 75.0%. How much phosphorus triiodide should be weighed out? What volume of water (d=1.651g/cm3) should be used?arrow_forwardA mixture contained calcium carbonate, CaCO3, and magnesium carbonate, MgCO3. A sample of this mixture weighing 7.85 g was reacted with excess hydrochloric acid. The reactions are CaCO3(g)+2HCL(aq)CaCl2(aq)+H2O(I)+CO2(g)MgCO3(s)+2HCL(aq)MgCl2(aq)+H2O(I)+CO2(g) If the sample reacted completely and produced 1.94 L of carbon dioxide, CO2, at 25C and 785 mmHg, what were the percentages of CaCO3 and MgCO3 in the mixture?arrow_forward5. An experiment is performed to measure the mass percent of CaCO3(s) in eggshells. Five different samples of CaCO3(s) of known mass react with an excess of 2.0M HCl(aq) in identical sealed, rigid reaction vessels. The pressure of the gas produced is measured with a pressure gauge attached to the reaction vessel. Since the reaction is exothermic, the reaction system is cooled to its original temperature before Cooling the HCl(aq) to a lower temperature than it was in the original experiment the pressure is recorded. The experimental data are used to create the calibration line below. Using eggshells that are more finely powdered than those used in the original experiment 0.10- 0.09 0.08- Using 2.0M CH3COOH(aq) instead of 2.0M HCl(aq) 0.07 * 0.06- Reducing the volume of the reaction vessel 0.05 0.04 CLEAR ALL 0.03- 0.02- 0.05 0.10 0.15 0.20 Mass of CaCO3(s) (grams) The experiment is repeated with an eggshell sample, and the experimental data are recorded in the table below. Mass of…arrow_forward
- Q1.A glass vessel was filled with an unknown quantity of nitrogen gas and the pressure at 28°C was 4.2 x 10⁴Pa. Oxygen gas was introduced at the same temperature until the pressure was to 1.013 ×10⁵Pa. (I) calculate the partial pressures of nitrogen gas and oxygen gas (II) calculate the mass ratio of the two gases. ( N=14, O=16) Q2. When temperature is increased by 10K, what happens to the rate of reaction? Why is it so?arrow_forwardAt 1450. mmHg and 286 K, a skin diver exhales a 208-mL bubble of air that is 77% N2, 17% O2, and 6.0% CO2 by volume. (a) How many milliliters would the volume of the bubble be if it were exhaled at the surface at 1 atm and 298 K? (b) How many moles of N2 are in the bubble?arrow_forward(a) Find the density in SI units of air at a pressure of 1.00 atm and a temperature of 20 °C , assuming that air is 78% N2, 21% O2, and 1% Ar , (b) Find the density of the atmosphere on Venus, assuming that it’s 96% CO2 and 4% N2 , with a temperature of 737 K and a pressure of 92.0 atm.arrow_forward
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