Study Guide for Chemistry: The Central Science
Study Guide for Chemistry: The Central Science
14th Edition
ISBN: 9780134554075
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus, James C. Hill
Publisher: PEARSON
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Chapter 14, Problem 20E

A flask is charged with 0.100 mol of A and allowed to react to form B according to the hypothetical gas-phase reaction A (g) →B (g). The following data are collected:

    Time (s) 0 40 80 120 160
    Moles of A 0.100 0.067 0.045 0.030 0.020

(a) Calculate the number of moles of B at each time in the table, assuming that A is cleanly converted to B with no intermediates. (b) Calculate the average rate of disappearance of A for each 40 s interval in units of mol/s. (c) Which of the following would be needed to calculate the rate in units of concentration per time: (i) the pressure of the gas at each time, (ii) the volume of the reaction flask, (iii) the temperature, or (iv) the molecular weight of A?

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