CHEMISTRY:MOLECULAR..(LL)-PRINT..W/CODE
CHEMISTRY:MOLECULAR..(LL)-PRINT..W/CODE
7th Edition
ISBN: 9781119457282
Author: JESPERSEN
Publisher: WILEY
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Chapter 14, Problem 1PE

In what way dots the chapter-opening photo represent a dynamic equilibrium and in what ways does it differ from a dynamic equilibrium?

Expert Solution & Answer
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Interpretation Introduction

The way in which the chapter-opening photo represents dynamic equilibrium and the ways in which it differs from a dynamic equilibrium are to be provided.

Concept Introduction:

The chapter-opening photo represents an artist maintaining equilibrium in a high-wire act. Dynamic equilibrium can be defined as the state of chemical equilibrium in which the concentrations of products and substrates cease to change that is rate of forward reaction is equal to rate of backward reaction. Such kind of equilibrium is established when two different and opposing processes take place at a similar rate.

Answer to Problem 1PE

Solution:

The tight-rope walker represents a dynamic equilibrium in the chapter-opening photograph because the walker is consistently adjusting to keep himself upright. It differs from the dynamic equilibrium as the two processes are in equilibrium are not occurring at the same time.

Explanation of Solution

In the picture, the artist is maintaining the equilibrium in a high wire act. The maintenance of the equilibrium is necessary to prevent any disaster. The tightrope walker maintains the equilibrium by counteracting the motion that is by keeping himself upright. In case, if he or she gets pushed in one direction, then he or she tries to bend in other direction to maintain the equilibrium. This similar to the processes during dynamic equilibrium. In case, if changes in one condition takes place, then the processes try to maintain the equilibrium.

In case of dynamic equilibrium, the concentration of reactants and products remains constant. Such reactions are reversible, that is the concentration of substrate decreases until it reaches non-zero value and similarly, the concentration of products increases till it reaches final steady value. In dynamic equilibrium, the reaction can move either in forward or backward reaction, however in high wire act, in case, if the walker is not able to maintain the balance, then he or she will fall.

The way it differs from a dynamic equilibrium is that the two processes, which are in equilibrium, are not occurring simultaneously.

Conclusion

The tight rope walker tries to maintain equilibrium by counteracting the motion. The two processes are in equilibrium but are not occurring at the same time.

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Chapter 14 Solutions

CHEMISTRY:MOLECULAR..(LL)-PRINT..W/CODE

Ch. 14 - Write the equilibrium law for each of the...Ch. 14 - Suppose a mixture contained equal concentrations...Ch. 14 - Arrange the following reactions in order of their...Ch. 14 - Consider the equilibrium...Ch. 14 - Consider the equilibrium PCl3(g)+Cl2(g)PCl5(g) for...Ch. 14 - In a particular experiment, it was found that when...Ch. 14 - An equilibrium was established for the reaction...Ch. 14 - A student placed 0.200 mol of PCl3(g) and 0.100...Ch. 14 - The decomposition of , has vessel contained...Ch. 14 - Prob. 20PECh. 14 - During an experiment, 0.200molofH2and0.200molofI2...Ch. 14 - In an experiment, were placed in a 1.00 L vessel...Ch. 14 - At 25C, the reaction...Ch. 14 - In air at and 1.00 atm, the concentration is...Ch. 14 - Dynamic Equilibrium in Chemical Systems 14.1...Ch. 14 - Dynamic Equilibrium in Chemical Systems 14.2 Using...Ch. 14 - Dynamic Equilibrium in Chemical Systems Repeat the...Ch. 14 - Dynamic Equilibrium in Chemical Systems 14.4 Using...Ch. 14 - 14.5 What meanings do the terms reactants and...Ch. 14 - Equilibrium Laws 14.6 What is an equilibrium law?....Ch. 14 - Equilibrium Laws 14.7 How is the term reaction...Ch. 14 - Equilibrium Laws 14.8 When a chemical equation and...Ch. 14 - Equilibrium Laws 14.9 Under what conditions does...Ch. 14 - Equilibrium Laws 14.10 Describe in words how the...Ch. 14 - Equilibrium Laws Based on Pressures or...Ch. 14 - Equilibrium Laws Based on Pressures or...Ch. 14 - Equilibrium Laws Based on Pressures or...Ch. 14 - Equilibrium Laws Based on Pressures or...Ch. 14 - Equilibrium Laws for Heterogeneous Reactions 14.15...Ch. 14 - Equilibrium Laws for Heterogeneous Reactions 14.16...Ch. 14 - Position of Equilibrium and the Equilibrium...Ch. 14 - Position of Equilibrium and the Equilibrium...Ch. 14 - Position of Equilibrium and the Equilibrium...Ch. 14 - Position of Equilibrium and the Equilibrium...Ch. 14 - Equilibrium and Le Chtelier's Principle State Le...Ch. 14 - Equilibrium and Le Chtelier's Principle Explain,...Ch. 14 - Equilibrium and Le Chteliers Principle Halving the...Ch. 14 - Equilibrium and Le Chteliers Principle How will...Ch. 14 - Equilibrium and Le Châtelier's Principle 14.25 Why...Ch. 14 - Equilibrium and Le Chtelier's Principle Why doesnt...Ch. 14 - Equilibrium Laws 14.27 Write the equilibrium law...Ch. 14 - Equilibrium Laws 14.28 Write the equilibrium law...Ch. 14 - Write the equilibrium law for the following...Ch. 14 - Write the equilibrium law for the following...Ch. 14 - At 25C,Kc=11085 for the reaction...Ch. 14 - Use the following equilibria...Ch. 14 - Write the equilibrium law for each of the...Ch. 14 - 14.34 Write the equilibrium law for the...Ch. 14 - Equilibrium Laws Based on Pressures and...Ch. 14 - 14.36 Write the equilibrium law for the reactions...Ch. 14 - Prob. 37RQCh. 14 - Prob. 38RQCh. 14 - For which of the following reactions does Kp=Kc?...Ch. 14 - For which of the following reactions does KpKc?...Ch. 14 - 14.41 The reaction has a . What is the value of ...Ch. 14 - 14.42 The reaction has a . What is the value of ...Ch. 14 - 14.43 The reaction has a . What is the value of ...Ch. 14 - One possible way of removing NO from the exhaust...Ch. 14 - At 773C the reaction CO(g)+2H2(g)CH3OH(g) has...Ch. 14 - The reaction...Ch. 14 - Equilibrium Laws for Heterogeneous Reactions...Ch. 14 - Equilibrium Laws for Heterogeneous Reactions The...Ch. 14 - Equilibrium Laws for Heterogeneous Reactions 14.49...Ch. 14 - Equilibrium Laws for Heterogeneous Reactions 14.50...Ch. 14 - The heterogeneous reaction...Ch. 14 - At 25C,Kc=360 for the reaction...Ch. 14 - Equilibrium and Le Chtelier's Principle The...Ch. 14 - Equilibrium and Le Chtelier's Principle How will...Ch. 14 - 14.55 Consider the equilibrium In which direction...Ch. 14 - Consider the equilibrium 2NO(g)+Cl2(g)2NOCl(g) for...Ch. 14 - Calculating Equilibrium Constants At 773C, a...Ch. 14 - Calculating Equilibrium Constants Ethylene, C2H4,...Ch. 14 - At high temperature, 2.00 mol of HBr was placed in...Ch. 14 - A 0.050 mol sample of formaldehyde vapor, CH2O,...Ch. 14 - The reaction NO2(g)+NO(g)N2O(g)+O2(g) reached...Ch. 14 - At 25C,0.0560molO2and0.020molN2O were placed in a...Ch. 14 - Using Equilibrium Constants to Calculate...Ch. 14 - Using Equilibrium Constants to Calculate...Ch. 14 - 14.65 At a certain temperature, the reaction has...Ch. 14 - 14.66 for the reaction at a certain temperature....Ch. 14 - At 25C,Kc=0.145 for the following reaction in the...Ch. 14 - At 25C,Kc=0.145 for the following reaction in the...Ch. 14 - 14.69 The equilibrium constant, Kc, for the...Ch. 14 - For the reaction in Problem 14.69, a reaction...Ch. 14 - 14.71 At a certain temperature the reaction has ....Ch. 14 - At 25C,Kc=0.145 for the following reaction in the...Ch. 14 - The reaction...Ch. 14 - 14.74 At for the reaction If and are placed in...Ch. 14 - 14.75 At , the decomposition of , has . If a 1.00...Ch. 14 - At 500C, the decomposition of water into hydrogen...Ch. 14 - 14.77 At a certain temperature, for the...Ch. 14 - At 460C, the reaction SO2(g)+NO2(g)NO(g)+SO3(g)...Ch. 14 - 14.79 At a certain temperature, for the...Ch. 14 - At 25C,Kc=0.145 for the following reaction in the...Ch. 14 - *14.81 At a certain temperature, for the...Ch. 14 - The reaction...Ch. 14 - 14.83 The reaction at . In a reaction vessel...Ch. 14 - 14.84 At , the following concentrations were found...Ch. 14 - The following reaction in aqueous solution has...Ch. 14 - At a certain temperature, Kc=0.914 for the...Ch. 14 - At 27C,Kc=1.51018 for the reaction...Ch. 14 - Consider the equilibrium...Ch. 14 - At a certain temperature, Kc=0.914 for the...Ch. 14 - At a certain temperature, Kc=0.914 for the...Ch. 14 - 14.91 Two 1.00 L bulbs are filled with 0.500 atm...Ch. 14 - For the equilibrium 3NO2(g)N2O5(g)+NO(g)...Ch. 14 - To study the following reaction at 20C,...Ch. 14 - Describe in words how the mass action expression...Ch. 14 - *14.95 For the reaction below, A mixture of was...Ch. 14 - At 2000C, the decomposition of CO2,...Ch. 14 - *14.97 At , the reaction has are placed in a...Ch. 14 - At 200.0C,Kc=1.410-10 for the reaction...Ch. 14 - At 400C,Kc=2.9104 for the reaction:...Ch. 14 - *14.100 The reaction . Into a 4.50 L reaction...Ch. 14 - 14.101 In an equilibrium law, coefficients in the...Ch. 14 - Why are equilibrium concentrations useful to know?Ch. 14 - 14.103 Suppose we set up a system in which water...Ch. 14 - 14.104 Do equilibrium laws apply to other systems...Ch. 14 - What might prevent a system from reaching dynamic...Ch. 14 - 14.106 After many centuries the earth’s atmosphere...Ch. 14 - 14.107 If a mixture consisting of many small...Ch. 14 - Why doesnt Le Chteliers principle apply to the...Ch. 14 - 14.109 Le Châtelier’s principle qualitatively...

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