The effect on the net reaction catalyzed by glyceraldehyde 3-phosphate dehydrogenase if phosphate were replaced by arsenate. Introduction: Arsenate (As) is chemically and structurally similar to inorganic phosphate and many other enzymes that need phosphate will also use arsenate. Organic compounds of arsenate are less stable compared to analogous phosphate compounds. On the other hand 1, 3-bisphosphoglycerate ( acyl phosphates ) is most stable and undergoes enzyme-catalyzed transformation in cells.

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Answer 1

Question

Chapter 14, Problem 14P

(a)

Summary Introduction

To determine: The effect on the net reaction catalyzed by glyceraldehyde 3-phosphate dehydrogenase if phosphate were replaced by arsenate.

Introduction:

Arsenate (As) is chemically and structurally similar to inorganic phosphate and many other enzymes that need phosphate will also use arsenate. Organic compounds of arsenate are less stable compared to analogous phosphate compounds. On the other hand 1, 3-bisphosphoglycerate (acyl phosphates) is most stable and undergoes enzyme-catalyzed transformation in cells.

(b1)

Summary Introduction

To determine: The consequence to an organism if arsenate was substituted for phosphate.

Introduction:

Arsenate is chemically and structurally similar to inorganic phosphate and many other enzymes that need phosphate will also use arsenate. Organic compounds of arsenate are less stable compared to analogous phosphate compounds.

(b2)

Summary Introduction

To explain: The reason that arsenate is very toxic to most organisms.

Introduction:

Arsenate is chemically and structurally similar to inorganic phosphate and many other enzymes that need phosphate will also use arsenate. Organic compounds of arsenate are less stable compared to analogous phosphate compounds.

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75.0 grams of an unknown metal was heated to 95.0°C, it was then placed into 150.0 grams of water at23.1°C, when the metal and water reached thermal equilibrium, the temperature was 27.8°C. Calculatethe specific heat of the metal. (Assume that the specific heat of water is 4.18 J/g °C)

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Answer 2

Question

Chapter 14, Problem 14P

(a)

Summary Introduction

To determine: The effect on the net reaction catalyzed by glyceraldehyde 3-phosphate dehydrogenase if phosphate were replaced by arsenate.

Introduction:

Arsenate (As) is chemically and structurally similar to inorganic phosphate and many other enzymes that need phosphate will also use arsenate. Organic compounds of arsenate are less stable compared to analogous phosphate compounds. On the other hand 1, 3-bisphosphoglycerate (acyl phosphates) is most stable and undergoes enzyme-catalyzed transformation in cells.

(b1)

Summary Introduction

To determine: The consequence to an organism if arsenate was substituted for phosphate.

Introduction:

Arsenate is chemically and structurally similar to inorganic phosphate and many other enzymes that need phosphate will also use arsenate. Organic compounds of arsenate are less stable compared to analogous phosphate compounds.

(b2)

Summary Introduction

To explain: The reason that arsenate is very toxic to most organisms.

Introduction:

Arsenate is chemically and structurally similar to inorganic phosphate and many other enzymes that need phosphate will also use arsenate. Organic compounds of arsenate are less stable compared to analogous phosphate compounds.

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Answer 3

Question

Chapter 14, Problem 14P

(a)

Summary Introduction

To determine: The effect on the net reaction catalyzed by glyceraldehyde 3-phosphate dehydrogenase if phosphate were replaced by arsenate.

Introduction:

Arsenate (As) is chemically and structurally similar to inorganic phosphate and many other enzymes that need phosphate will also use arsenate. Organic compounds of arsenate are less stable compared to analogous phosphate compounds. On the other hand 1, 3-bisphosphoglycerate (acyl phosphates) is most stable and undergoes enzyme-catalyzed transformation in cells.

(b1)

Summary Introduction

To determine: The consequence to an organism if arsenate was substituted for phosphate.

Introduction:

Arsenate is chemically and structurally similar to inorganic phosphate and many other enzymes that need phosphate will also use arsenate. Organic compounds of arsenate are less stable compared to analogous phosphate compounds.

(b2)

Summary Introduction

To explain: The reason that arsenate is very toxic to most organisms.

Introduction:

Arsenate is chemically and structurally similar to inorganic phosphate and many other enzymes that need phosphate will also use arsenate. Organic compounds of arsenate are less stable compared to analogous phosphate compounds.

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Answer 4

Question

Chapter 14, Problem 14P

(a)

Summary Introduction

To determine: The effect on the net reaction catalyzed by glyceraldehyde 3-phosphate dehydrogenase if phosphate were replaced by arsenate.

Introduction:

Arsenate (As) is chemically and structurally similar to inorganic phosphate and many other enzymes that need phosphate will also use arsenate. Organic compounds of arsenate are less stable compared to analogous phosphate compounds. On the other hand 1, 3-bisphosphoglycerate (acyl phosphates) is most stable and undergoes enzyme-catalyzed transformation in cells.

(b1)

Summary Introduction

To determine: The consequence to an organism if arsenate was substituted for phosphate.

Introduction:

Arsenate is chemically and structurally similar to inorganic phosphate and many other enzymes that need phosphate will also use arsenate. Organic compounds of arsenate are less stable compared to analogous phosphate compounds.

(b2)

Summary Introduction

To explain: The reason that arsenate is very toxic to most organisms.

Introduction:

Arsenate is chemically and structurally similar to inorganic phosphate and many other enzymes that need phosphate will also use arsenate. Organic compounds of arsenate are less stable compared to analogous phosphate compounds.

Expert Solution & Answer

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Answer 5

Chapter 14, Problem 14P

(a)

Summary Introduction

To determine: The effect on the net reaction catalyzed by glyceraldehyde 3-phosphate dehydrogenase if phosphate were replaced by arsenate.

Introduction:

Arsenate (As) is chemically and structurally similar to inorganic phosphate and many other enzymes that need phosphate will also use arsenate. Organic compounds of arsenate are less stable compared to analogous phosphate compounds. On the other hand 1, 3-bisphosphoglycerate (acyl phosphates) is most stable and undergoes enzyme-catalyzed transformation in cells.

(b1)

Summary Introduction

To determine: The consequence to an organism if arsenate was substituted for phosphate.

Introduction:

Arsenate is chemically and structurally similar to inorganic phosphate and many other enzymes that need phosphate will also use arsenate. Organic compounds of arsenate are less stable compared to analogous phosphate compounds.

(b2)

Summary Introduction

To explain: The reason that arsenate is very toxic to most organisms.

Introduction:

Arsenate is chemically and structurally similar to inorganic phosphate and many other enzymes that need phosphate will also use arsenate. Organic compounds of arsenate are less stable compared to analogous phosphate compounds.

Answer 6

Chapter 14, Problem 14P

(a)

Summary Introduction

To determine: The effect on the net reaction catalyzed by glyceraldehyde 3-phosphate dehydrogenase if phosphate were replaced by arsenate.

Introduction:

Arsenate (As) is chemically and structurally similar to inorganic phosphate and many other enzymes that need phosphate will also use arsenate. Organic compounds of arsenate are less stable compared to analogous phosphate compounds. On the other hand 1, 3-bisphosphoglycerate (acyl phosphates) is most stable and undergoes enzyme-catalyzed transformation in cells.

Answer 7

Chapter 14, Problem 14P

(a)

Summary Introduction

To determine: The effect on the net reaction catalyzed by glyceraldehyde 3-phosphate dehydrogenase if phosphate were replaced by arsenate.

Introduction:

Arsenate (As) is chemically and structurally similar to inorganic phosphate and many other enzymes that need phosphate will also use arsenate. Organic compounds of arsenate are less stable compared to analogous phosphate compounds. On the other hand 1, 3-bisphosphoglycerate (acyl phosphates) is most stable and undergoes enzyme-catalyzed transformation in cells.

Answer 8

(b1)

Summary Introduction

To determine: The consequence to an organism if arsenate was substituted for phosphate.

Introduction:

Arsenate is chemically and structurally similar to inorganic phosphate and many other enzymes that need phosphate will also use arsenate. Organic compounds of arsenate are less stable compared to analogous phosphate compounds.

Answer 9

(b1)

Summary Introduction

To determine: The consequence to an organism if arsenate was substituted for phosphate.

Introduction:

Arsenate is chemically and structurally similar to inorganic phosphate and many other enzymes that need phosphate will also use arsenate. Organic compounds of arsenate are less stable compared to analogous phosphate compounds.

Answer 10

(b2)

Summary Introduction

To explain: The reason that arsenate is very toxic to most organisms.

Introduction:

Arsenate is chemically and structurally similar to inorganic phosphate and many other enzymes that need phosphate will also use arsenate. Organic compounds of arsenate are less stable compared to analogous phosphate compounds.

Answer 11

(b2)

Summary Introduction

To explain: The reason that arsenate is very toxic to most organisms.

Introduction:

Arsenate is chemically and structurally similar to inorganic phosphate and many other enzymes that need phosphate will also use arsenate. Organic compounds of arsenate are less stable compared to analogous phosphate compounds.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 14 - Prob. 1P Ch. 14 - Prob. 2P Ch. 14 - Prob. 3P Ch. 14 - Prob. 4P Ch. 14 - Prob. 5P Ch. 14 - Prob. 6P Ch. 14 - Prob. 7P Ch. 14 - Prob. 8P Ch. 14 - Prob. 9P Ch. 14 - Prob. 10P

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Chapter 14 Solutions