ATKINS' PHYSICAL CHEMISTRY
11th Edition
ISBN: 9780190053956
Author: ATKINS
Publisher: Oxford University Press
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Chapter 14, Problem 14E.1ST
Interpretation Introduction
Interpretation:
The value of
Concept introduction:
The value of
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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
90
80
70
-26
60
50
40
46
30
20
115
10
1.0 0.9 0.8
0
-10
Q: Arrange BCC and Fec
metals, in sequence from the
Fable (Dr. R's slides) and
Calculate Volume and Density.
Aa
BCC
V
52 5
SFCC
None
Chapter 14 Solutions
ATKINS' PHYSICAL CHEMISTRY
Ch. 14 - Prob. 14A.1STCh. 14 - Prob. 14A.2STCh. 14 - Prob. 14B.1STCh. 14 - Prob. 14C.1STCh. 14 - Prob. 14C.2STCh. 14 - Prob. 14D.1STCh. 14 - Prob. 14D.2STCh. 14 - Prob. 14E.1STCh. 14 - Prob. 14A.1DQCh. 14 - Prob. 14A.2DQ
Ch. 14 - Prob. 14A.3DQCh. 14 - Prob. 14A.1AECh. 14 - Prob. 14A.1BECh. 14 - Prob. 14A.2AECh. 14 - Prob. 14A.2BECh. 14 - Prob. 14A.3AECh. 14 - Prob. 14A.3BECh. 14 - Prob. 14A.4AECh. 14 - Prob. 14A.4BECh. 14 - Prob. 14A.5AECh. 14 - Prob. 14A.5BECh. 14 - Prob. 14A.6AECh. 14 - Prob. 14A.6BECh. 14 - Prob. 14A.7AECh. 14 - Prob. 14A.7BECh. 14 - Prob. 14A.8AECh. 14 - Prob. 14A.8BECh. 14 - Prob. 14A.9AECh. 14 - Prob. 14A.9BECh. 14 - Prob. 14A.1PCh. 14 - Prob. 14A.2PCh. 14 - Prob. 14A.3PCh. 14 - Prob. 14A.4PCh. 14 - Prob. 14A.5PCh. 14 - Prob. 14A.6PCh. 14 - Prob. 14A.7PCh. 14 - Prob. 14A.8PCh. 14 - Prob. 14A.10PCh. 14 - Prob. 14A.12PCh. 14 - Prob. 14A.13PCh. 14 - Prob. 14B.1DQCh. 14 - Prob. 14B.2DQCh. 14 - Prob. 14B.3DQCh. 14 - Prob. 14B.4DQCh. 14 - Prob. 14B.5DQCh. 14 - Prob. 14B.1AECh. 14 - Prob. 14B.1BECh. 14 - Prob. 14B.2AECh. 14 - Prob. 14B.2BECh. 14 - Prob. 14B.3AECh. 14 - Prob. 14B.3BECh. 14 - Prob. 14B.4AECh. 14 - Prob. 14B.4BECh. 14 - Prob. 14B.5AECh. 14 - Prob. 14B.5BECh. 14 - Prob. 14B.6AECh. 14 - Prob. 14B.6BECh. 14 - Prob. 14B.1PCh. 14 - Prob. 14B.2PCh. 14 - Prob. 14B.3PCh. 14 - Prob. 14B.4PCh. 14 - Prob. 14B.5PCh. 14 - Prob. 14B.6PCh. 14 - Prob. 14B.7PCh. 14 - Prob. 14B.8PCh. 14 - Prob. 14B.10PCh. 14 - Prob. 14C.1DQCh. 14 - Prob. 14C.2DQCh. 14 - Prob. 14C.1AECh. 14 - Prob. 14C.1BECh. 14 - Prob. 14C.2AECh. 14 - Prob. 14C.2BECh. 14 - Prob. 14C.3AECh. 14 - Prob. 14C.3BECh. 14 - Prob. 14C.4AECh. 14 - Prob. 14C.4BECh. 14 - Prob. 14C.1PCh. 14 - Prob. 14C.2PCh. 14 - Prob. 14D.1DQCh. 14 - Prob. 14D.2DQCh. 14 - Prob. 14D.3DQCh. 14 - Prob. 14D.4DQCh. 14 - Prob. 14D.5DQCh. 14 - Prob. 14D.1AECh. 14 - Prob. 14D.1BECh. 14 - Prob. 14D.2AECh. 14 - Prob. 14D.2BECh. 14 - Prob. 14D.3AECh. 14 - Prob. 14D.3BECh. 14 - Prob. 14D.4AECh. 14 - Prob. 14D.4BECh. 14 - Prob. 14D.5AECh. 14 - Prob. 14D.5BECh. 14 - Prob. 14D.6AECh. 14 - Prob. 14D.6BECh. 14 - Prob. 14D.8AECh. 14 - Prob. 14D.8BECh. 14 - Prob. 14D.9AECh. 14 - Prob. 14D.9BECh. 14 - Prob. 14D.2PCh. 14 - Prob. 14D.3PCh. 14 - Prob. 14D.4PCh. 14 - Prob. 14D.6PCh. 14 - Prob. 14D.7PCh. 14 - Prob. 14D.8PCh. 14 - Prob. 14D.9PCh. 14 - Prob. 14D.10PCh. 14 - Prob. 14E.1DQCh. 14 - Prob. 14E.2DQCh. 14 - Prob. 14E.3DQCh. 14 - Prob. 14E.4DQCh. 14 - Prob. 14E.5DQCh. 14 - Prob. 14E.1AECh. 14 - Prob. 14E.1BECh. 14 - Prob. 14E.1PCh. 14 - Prob. 14E.3PCh. 14 - Prob. 14.1IACh. 14 - Prob. 14.2IACh. 14 - Prob. 14.6IACh. 14 - Prob. 14.8IA
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