(a) Interpretation: The given transformation should be explained. Concept Introduction: The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO 4 − ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

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Answer 1

Question

Chapter 14, Problem 14.72P

Interpretation Introduction

(a)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Interpretation Introduction

(b)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Interpretation Introduction

(c)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Interpretation Introduction

(d)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Interpretation Introduction

(e)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

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AG/F-2° V 3. Before proceeding with this problem you may want to glance at p. 466 of your textbook where various oxo-phosphorus derivatives and their oxidation states are summarized. Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14: -0.93 +0.38 -0.50 -0.51 -0.06 H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3 Acidic solution Basic solution -0.28 -0.50 3--1.12 -1.57 -2.05 -0.89 PO HPO H₂PO₂ →P → PH3 -1.73 a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both processes; comment. (3 points) 0.5 PH P 0.0 -0.5 -1.0- -1.5- -2.0 H.PO, -2.3+ -3 -2 -1 1 2 3 2 H,PO, b) Frost diagram for phosphorus under acidic conditions is shown. Identify possible disproportionation and comproportionation processes; write out chemical equations describing them. (2 points) H,PO 4 S Oxidation stale, N

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2. Calculate the overall formation constant for [Fe(CN)6]³, given that the overall formation constant for [Fe(CN)6] 4 is ~1032, and that: Fe3+ (aq) + e = Fe²+ (aq) E° = +0.77 V [Fe(CN)6]³ (aq) + e¯ = [Fe(CN)6] (aq) E° = +0.36 V (4 points)

Answer 2

Question

Chapter 14, Problem 14.72P

Interpretation Introduction

(a)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Interpretation Introduction

(b)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Interpretation Introduction

(c)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Interpretation Introduction

(d)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Interpretation Introduction

(e)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

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Answer 3

Question

Chapter 14, Problem 14.72P

Interpretation Introduction

(a)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Interpretation Introduction

(b)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Interpretation Introduction

(c)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Interpretation Introduction

(d)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Interpretation Introduction

(e)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

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Answer 4

Question

Chapter 14, Problem 14.72P

Interpretation Introduction

(a)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Interpretation Introduction

(b)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Interpretation Introduction

(c)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Interpretation Introduction

(d)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Interpretation Introduction

(e)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

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Answer 5

Chapter 14, Problem 14.72P

Interpretation Introduction

(a)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Interpretation Introduction

(b)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Interpretation Introduction

(c)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Interpretation Introduction

(d)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Interpretation Introduction

(e)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Answer 6

Chapter 14, Problem 14.72P

Interpretation Introduction

(a)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Answer 7

Chapter 14, Problem 14.72P

Interpretation Introduction

(a)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The given transformation should be explained.

Concept Introduction:

The acid catalyzed hydration of alkenes result in the formation of alcohols. In this reaction, the hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation of carbocation. This carbocation can reacts with the lone pair on oxygen atom resulting substitution of hydronium ion group on the carbon having positive charge. The HSO4− ion so formed then abstract one hydrogen atom resulting the formation of alcohol.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 14.1 - Prob. 14.1P Ch. 14.1 - Prob. 14.2P Ch. 14.2 - Problem 14-3 Draw structural formulas for the...Ch. 14.2 - Prob. 14.4P Ch. 14.2 - Prob. 14.5P Ch. 14.3 - Problem 14-6 Write the common name for each ether.Ch. 14.4 - Prob. 14.7P Ch. 14 - 14-8 Answer true or false. The functional group of...Ch. 14 - 14-9 What is the difference in structure between a...Ch. 14 - 14-10 Which of the following are secondary...

Solution Summary: The author explains that acid catalyzed hydration of alkenes result in the formation of alcohols. The hydrogen ion from the acid reacts with the pi electrons of the double bond resulting formation

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