The equilibrium constant ( K P ) for the formation of the air pollutant nitric oxide (NO) in an automobile engine at 530°C is 2.9 × 10 −11 : N 2 ( g ) + O 2 ( g ) ⇌ 2 NO ( g ) (a) Calculate the partial pressure of NO under these conditions if the partial pressures of nitrogen and oxygen are 3.0 atm and 0.012 atm, respectively. (b) Repeat the calculation for atmospheric conditions where the partial pressures of nitrogen and oxygen are 0.78 atm and 0.21 atm and the temperature is 25°C. (The K P for the reaction is 4.0 × 10 −31 at this temperature.) (c) Is the formation of NO endothermic or exothermic? (d) What natural phenomenon promotes the formation of NO? Why?
The equilibrium constant ( K P ) for the formation of the air pollutant nitric oxide (NO) in an automobile engine at 530°C is 2.9 × 10 −11 : N 2 ( g ) + O 2 ( g ) ⇌ 2 NO ( g ) (a) Calculate the partial pressure of NO under these conditions if the partial pressures of nitrogen and oxygen are 3.0 atm and 0.012 atm, respectively. (b) Repeat the calculation for atmospheric conditions where the partial pressures of nitrogen and oxygen are 0.78 atm and 0.21 atm and the temperature is 25°C. (The K P for the reaction is 4.0 × 10 −31 at this temperature.) (c) Is the formation of NO endothermic or exothermic? (d) What natural phenomenon promotes the formation of NO? Why?
The equilibrium constant (KP) for the formation of the air pollutant nitric oxide (NO) in an automobile engine at 530°C is 2.9 × 10−11:
N
2
(
g
)
+
O
2
(
g
)
⇌
2
NO
(
g
)
(a) Calculate the partial pressure of NO under these conditions if the partial pressures of nitrogen and oxygen are 3.0 atm and 0.012 atm, respectively. (b) Repeat the calculation for atmospheric conditions where the partial pressures of nitrogen and oxygen are 0.78 atm and 0.21 atm and the temperature is 25°C. (The KP for the reaction is 4.0 × 10−31 at this temperature.) (c) Is the formation of NO endothermic or exothermic? (d) What natural phenomenon promotes the formation of NO? Why?
How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
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