1st Edition

ISBN: 9781307092097

Author: Chang

Publisher: MCG/CREATE

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Chapter 14, Problem 14.114QP

The equilibrium constant (K_P) for the reaction

C ( s ) + CO 2 ( g ) ⇌ 2 CO ( g )

is 1.9 at 727°C. What total pressure must be applied to the reacting system to obtain 0.012 mole of CO2 and 0.025 mole of CO?

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Chapter 14, Problem 14.113QP

Chapter 14, Problem 14.115QP

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Part I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400

• Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peak

Could you redraw these and also explain how to solve them for me pleas

Chapter 14 Solutions

CHEMISTRY 1111 LAB MANUAL >C<

Ch. 14.1 - Consider the equilibrium XY, where the forward...Ch. 14.2 - Write Kc and Kp for the decomposition of...Ch. 14.2 - Carbonyl chloride (COCl2), also called phosgene,...Ch. 14.2 - Prob. 4PE Ch. 14.2 - Write equilibrium constant expressions for Kc and...Ch. 14.2 - Consider the following equilibrium at 395 K:...Ch. 14.2 - For which of the following reactions is Kc equal...Ch. 14.2 - You are given the equilibrium constant for the...Ch. 14.2 - Prob. 7PE Ch. 14.2 - From the following equilibrium constant...

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The equilibrium constant ( K P ) for the reaction C ( s ) + CO 2 ( g ) ⇌ 2 CO ( g ) is 1.9 at 727°C. What total pressure must be applied to the reacting system to obtain 0.012 mole of CO2 and 0.025 mole of CO?

Solution Summary: The author explains that the total pressure of the reacting system has to be calculated using the data.

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Chapter 14 Solutions