It is to be explained why bromobenzene is insoluble in water but 7-bromocyclohepta-1, 3, 5-triene is water-soluble. Concept introduction: The major intermolecular interaction between the molecules of water is hydrogen bonding. Hydrogen bonding is a form of dipole-dipole interaction but with substantially higher energy than the usual dipole-dipole interactions. For a compound to be soluble in water, the type of intermolecular interactions between its molecules must be similar to that in water. It must exhibit substantial dipole-dipole interactions or a capability to form hydrogen bonds with water molecules. A polar solvent can induce heterolysis of a carbon-halogen bond, accompanied by solvation of the ions.

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Answer 1

Question

Chapter 14, Problem 14.56P

Interpretation Introduction

Interpretation:

It is to be explained why bromobenzene is insoluble in water but 7-bromocyclohepta-1, 3, 5-triene is water-soluble.

Concept introduction:

The major intermolecular interaction between the molecules of water is hydrogen bonding. Hydrogen bonding is a form of dipole-dipole interaction but with substantially higher energy than the usual dipole-dipole interactions.

For a compound to be soluble in water, the type of intermolecular interactions between its molecules must be similar to that in water. It must exhibit substantial dipole-dipole interactions or a capability to form hydrogen bonds with water molecules.

A polar solvent can induce heterolysis of a carbon-halogen bond, accompanied by solvation of the ions.

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Answer 2

Question

Chapter 14, Problem 14.56P

Interpretation Introduction

Interpretation:

It is to be explained why bromobenzene is insoluble in water but 7-bromocyclohepta-1, 3, 5-triene is water-soluble.

Concept introduction:

The major intermolecular interaction between the molecules of water is hydrogen bonding. Hydrogen bonding is a form of dipole-dipole interaction but with substantially higher energy than the usual dipole-dipole interactions.

For a compound to be soluble in water, the type of intermolecular interactions between its molecules must be similar to that in water. It must exhibit substantial dipole-dipole interactions or a capability to form hydrogen bonds with water molecules.

A polar solvent can induce heterolysis of a carbon-halogen bond, accompanied by solvation of the ions.

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Answer 3

Question

Chapter 14, Problem 14.56P

Interpretation Introduction

Interpretation:

It is to be explained why bromobenzene is insoluble in water but 7-bromocyclohepta-1, 3, 5-triene is water-soluble.

Concept introduction:

The major intermolecular interaction between the molecules of water is hydrogen bonding. Hydrogen bonding is a form of dipole-dipole interaction but with substantially higher energy than the usual dipole-dipole interactions.

For a compound to be soluble in water, the type of intermolecular interactions between its molecules must be similar to that in water. It must exhibit substantial dipole-dipole interactions or a capability to form hydrogen bonds with water molecules.

A polar solvent can induce heterolysis of a carbon-halogen bond, accompanied by solvation of the ions.

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Answer 4

Question

Chapter 14, Problem 14.56P

Interpretation Introduction

Interpretation:

It is to be explained why bromobenzene is insoluble in water but 7-bromocyclohepta-1, 3, 5-triene is water-soluble.

Concept introduction:

The major intermolecular interaction between the molecules of water is hydrogen bonding. Hydrogen bonding is a form of dipole-dipole interaction but with substantially higher energy than the usual dipole-dipole interactions.

For a compound to be soluble in water, the type of intermolecular interactions between its molecules must be similar to that in water. It must exhibit substantial dipole-dipole interactions or a capability to form hydrogen bonds with water molecules.

A polar solvent can induce heterolysis of a carbon-halogen bond, accompanied by solvation of the ions.

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Answer 5

Chapter 14, Problem 14.56P

Interpretation Introduction

Interpretation:

It is to be explained why bromobenzene is insoluble in water but 7-bromocyclohepta-1, 3, 5-triene is water-soluble.

Concept introduction:

The major intermolecular interaction between the molecules of water is hydrogen bonding. Hydrogen bonding is a form of dipole-dipole interaction but with substantially higher energy than the usual dipole-dipole interactions.

For a compound to be soluble in water, the type of intermolecular interactions between its molecules must be similar to that in water. It must exhibit substantial dipole-dipole interactions or a capability to form hydrogen bonds with water molecules.

A polar solvent can induce heterolysis of a carbon-halogen bond, accompanied by solvation of the ions.

Answer 6

Chapter 14, Problem 14.56P

Interpretation Introduction

Interpretation:

It is to be explained why bromobenzene is insoluble in water but 7-bromocyclohepta-1, 3, 5-triene is water-soluble.

Concept introduction:

The major intermolecular interaction between the molecules of water is hydrogen bonding. Hydrogen bonding is a form of dipole-dipole interaction but with substantially higher energy than the usual dipole-dipole interactions.

For a compound to be soluble in water, the type of intermolecular interactions between its molecules must be similar to that in water. It must exhibit substantial dipole-dipole interactions or a capability to form hydrogen bonds with water molecules.

A polar solvent can induce heterolysis of a carbon-halogen bond, accompanied by solvation of the ions.

Answer 7

Chapter 14, Problem 14.56P

Interpretation Introduction

Interpretation:

It is to be explained why bromobenzene is insoluble in water but 7-bromocyclohepta-1, 3, 5-triene is water-soluble.

Concept introduction:

The major intermolecular interaction between the molecules of water is hydrogen bonding. Hydrogen bonding is a form of dipole-dipole interaction but with substantially higher energy than the usual dipole-dipole interactions.

For a compound to be soluble in water, the type of intermolecular interactions between its molecules must be similar to that in water. It must exhibit substantial dipole-dipole interactions or a capability to form hydrogen bonds with water molecules.

A polar solvent can induce heterolysis of a carbon-halogen bond, accompanied by solvation of the ions.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 14 - Prob. 14.1P Ch. 14 - Prob. 14.2P Ch. 14 - Prob. 14.3P Ch. 14 - Prob. 14.4P Ch. 14 - Prob. 14.5P Ch. 14 - Prob. 14.6P Ch. 14 - Prob. 14.7P Ch. 14 - Prob. 14.8P Ch. 14 - Prob. 14.9P Ch. 14 - Prob. 14.10P

Solution Summary: The author explains why bromobenzene is insoluble in water but 7-bromacyclohepta-1, 3, 5-triene is water-soluble.

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