(a) Interpretation: The Lewis structure of isopropylacetylene is to be drawn. Concept introduction: Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

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Answer 1

Question

Chapter 14, Problem 14.2P

Interpretation Introduction

(a)

Interpretation:

The Lewis structure of isopropylacetylene is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(b)

Interpretation:

The Lewis structure of cyclononyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(c)

Interpretation:

The Lewis structure of 4-methyl-1-pentyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(d)

Interpretation:

The Lewis structure of 1-ethynylcyclohexanol is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(e)

Interpretation:

The Lewis structure of 2-butoxy-3-heptyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(f)

Interpretation:

The Lewis structure of 1, 3-hexadiyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below. Find the following: (a) The no. of protons corresponding to each signal in the spectra (6) Give the structure of the compound and assign the signals to each proton in the compound. a 70.2 Integration Values C5H10O2 b 47.7 C 46.5 d 69.5 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 Chemical Shift (ppm) 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8

Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below. Answer the following: (a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure of the molecule below. (b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible. complex splitting patterns assuming J values are not similar. там Br 22 2 3 6 4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0 Chemical Shift (ppm) ra. Br 2 3 6 6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8 Chemical Shift (ppm) 2 2 Br 7.3 7.2 7.1 7.0 6.9 6.7 6.6 6.5 6.4 6.3 6.2 6.1 6.0 Chemical Shift (ppm) 5.9 5.8 5.7 5.5 5.4 5.3 5.2 5.0 4.9

1600° 1538°C 1493°C In the diagram, the letter L indicates that it is a liquid. Indicate its components in the upper region where only L is indicated. The iron-iron carbide phase diagram. Temperature (°C) 1400 8 1394°C y+L 1200 2.14 y, Austenite 10000 912°C 800a 0.76 0.022 600 400 (Fe) a, Ferrite Composition (at% C) 15 1147°C a + Fe3C 2 3 Composition (wt% C) L 2500 4.30 2000 y + Fe3C 727°C 1500 Cementite (Fe3C) 1000 4 5 6 6.70 Temperature (°F)

Answer 2

Question

Chapter 14, Problem 14.2P

Interpretation Introduction

(a)

Interpretation:

The Lewis structure of isopropylacetylene is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(b)

Interpretation:

The Lewis structure of cyclononyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(c)

Interpretation:

The Lewis structure of 4-methyl-1-pentyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(d)

Interpretation:

The Lewis structure of 1-ethynylcyclohexanol is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(e)

Interpretation:

The Lewis structure of 2-butoxy-3-heptyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(f)

Interpretation:

The Lewis structure of 1, 3-hexadiyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

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Answer 3

Question

Chapter 14, Problem 14.2P

Interpretation Introduction

(a)

Interpretation:

The Lewis structure of isopropylacetylene is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(b)

Interpretation:

The Lewis structure of cyclononyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(c)

Interpretation:

The Lewis structure of 4-methyl-1-pentyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(d)

Interpretation:

The Lewis structure of 1-ethynylcyclohexanol is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(e)

Interpretation:

The Lewis structure of 2-butoxy-3-heptyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(f)

Interpretation:

The Lewis structure of 1, 3-hexadiyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

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Answer 4

Question

Chapter 14, Problem 14.2P

Interpretation Introduction

(a)

Interpretation:

The Lewis structure of isopropylacetylene is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(b)

Interpretation:

The Lewis structure of cyclononyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(c)

Interpretation:

The Lewis structure of 4-methyl-1-pentyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(d)

Interpretation:

The Lewis structure of 1-ethynylcyclohexanol is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(e)

Interpretation:

The Lewis structure of 2-butoxy-3-heptyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(f)

Interpretation:

The Lewis structure of 1, 3-hexadiyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

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Answer 5

Chapter 14, Problem 14.2P

Interpretation Introduction

(a)

Interpretation:

The Lewis structure of isopropylacetylene is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(b)

Interpretation:

The Lewis structure of cyclononyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(c)

Interpretation:

The Lewis structure of 4-methyl-1-pentyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(d)

Interpretation:

The Lewis structure of 1-ethynylcyclohexanol is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(e)

Interpretation:

The Lewis structure of 2-butoxy-3-heptyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Interpretation Introduction

(f)

Interpretation:

The Lewis structure of 1, 3-hexadiyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Answer 6

Chapter 14, Problem 14.2P

Interpretation Introduction

(a)

Interpretation:

The Lewis structure of isopropylacetylene is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Answer 7

Chapter 14, Problem 14.2P

Interpretation Introduction

(a)

Interpretation:

The Lewis structure of isopropylacetylene is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The Lewis structure of cyclononyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The Lewis structure of cyclononyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The Lewis structure of 4-methyl-1-pentyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The Lewis structure of 4-methyl-1-pentyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The Lewis structure of 1-ethynylcyclohexanol is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The Lewis structure of 1-ethynylcyclohexanol is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The Lewis structure of 2-butoxy-3-heptyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The Lewis structure of 2-butoxy-3-heptyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Answer 16

Interpretation Introduction

(f)

Interpretation:

The Lewis structure of 1, 3-hexadiyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Answer 17

Interpretation Introduction

(f)

Interpretation:

The Lewis structure of 1, 3-hexadiyne is to be drawn.

Concept introduction:

Lewis diagram is a representation of the chemical formula of substance with valance electrons of atoms. The Lewis structures are also called electron dot structures. In the Lewis structure, electrons are denoted by dots. Only the valence electrons are presented as dots in the Lewis structure.

Answer 18

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Answer 19

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Answer 20

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Answer 21

Ch. 14 - Prob. 14.1P Ch. 14 - Prob. 14.2P Ch. 14 - Prob. 14.3P Ch. 14 - Prob. 14.4P Ch. 14 - Prob. 14.5P Ch. 14 - Prob. 14.6P Ch. 14 - Prob. 14.7P Ch. 14 - Prob. 14.8P Ch. 14 - Prob. 14.9P Ch. 14 - Prob. 14.10P

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Chapter 14 Solutions