(a) Interpretation: The ligand-to-metal ratio in the product should be determined. Concept introduction: In the method of continuous variation, cation and ligand solutions which have same concentration are mixed in such a way that total number of moles of reactants and the total volume of each mixture are constant. But the mole ratio varies. Then the absorbance of the mixture is measured and absorbance is corrected. The corrected absorbance is plotted against volume fraction of one reactant. A maximum or a minimum occur at metal to ligand volume ratio equals to the combined ratio of metal to ligand.

Question

What is the missing reactant in this organic reaction? R+ HO-C-CH2-CH3 0= CH3 CH3 —CH, C−NH—CH CH3 + H₂O Specifically, in the drawing area below draw the condensed structure of R. If there is more than one reasonable answer, you can draw any one of them. If there is no reasonable answer, check the No answer box under the drawing area. Note for advanced students: you may assume no products other than those shown above are formed. No Answer Click anywhere to draw the first atom of your structure. €

Answer 1

Question

Chapter 14, Problem 14.18QAP

Interpretation Introduction

(a)

Interpretation:

The ligand-to-metal ratio in the product should be determined.

Concept introduction:

In the method of continuous variation, cation and ligand solutions which have same concentration are mixed in such a way that total number of moles of reactants and the total volume of each mixture are constant. But the mole ratio varies. Then the absorbance of the mixture is measured and absorbance is corrected. The corrected absorbance is plotted against volume fraction of one reactant. A maximum or a minimum occur at metal to ligand volume ratio equals to the combined ratio of metal to ligand.

Interpretation Introduction

(b)

Interpretation:

Average molar absorptivity of the complex and its uncertainty should be calculated.

Concept introduction:

In the method of continuous variation, cation and ligand solutions which have same concentration are mixed in such a way that total number of moles of reactants and the total volume of each mixture are constant. But the mole ratio varies. Then the absorbance of the mixture is measured and absorbance is corrected. The corrected absorbance is plotted against volume fraction of one reactant. A maximum or a minimum occur at metal to ligand volume ratio equals to the combined ratio of metal to ligand.

Interpretation Introduction

(c)

Interpretation:

K_f for the complex should be determined

Concept introduction:

In the method of continuous variation, cation and ligand solutions which have same concentration are mixed in such a way that total number of moles of reactants and the total volume of each mixture are constant. But the mole ratio varies. Then the absorbance of the mixture is measured and absorbance is corrected. The corrected absorbance is plotted against volume fraction of one reactant. A maximum or a minimum occur at metal to ligand volume ratio equals to the combined ratio of metal to ligand.

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What is the missing reactant in this organic reaction? R+ HO-C-CH2-CH3 0= CH3 CH3 —CH, C−NH—CH CH3 + H₂O Specifically, in the drawing area below draw the condensed structure of R. If there is more than one reasonable answer, you can draw any one of them. If there is no reasonable answer, check the No answer box under the drawing area. Note for advanced students: you may assume no products other than those shown above are formed. No Answer Click anywhere to draw the first atom of your structure. €

个 CHEM&131 9267 - $25 - Intro to Mail - Hutchison, Allison (Student x Aktiv Learnin https://app.aktiv.com Draw the product of the reaction shown below. Ignore inorganic byproducts. + Na2Cr2O7 Acetone, H2SO4 Type here to search Dryng OH W Pr

Predict the products of this organic reaction: OH + NaOH A? Specifically, in the drawing area below draw the skeletal ("line") structure of the product, or products, of this reaction. (If there's more than one product, draw them in any arrangement you like, so long as they aren't touching.) If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area. No reaction Click and drag to start drawing a structure. ✓ S

Answer 2

Question

Chapter 14, Problem 14.18QAP

Interpretation Introduction

(a)

Interpretation:

The ligand-to-metal ratio in the product should be determined.

Concept introduction:

In the method of continuous variation, cation and ligand solutions which have same concentration are mixed in such a way that total number of moles of reactants and the total volume of each mixture are constant. But the mole ratio varies. Then the absorbance of the mixture is measured and absorbance is corrected. The corrected absorbance is plotted against volume fraction of one reactant. A maximum or a minimum occur at metal to ligand volume ratio equals to the combined ratio of metal to ligand.

Interpretation Introduction

(b)

Interpretation:

Average molar absorptivity of the complex and its uncertainty should be calculated.

Concept introduction:

In the method of continuous variation, cation and ligand solutions which have same concentration are mixed in such a way that total number of moles of reactants and the total volume of each mixture are constant. But the mole ratio varies. Then the absorbance of the mixture is measured and absorbance is corrected. The corrected absorbance is plotted against volume fraction of one reactant. A maximum or a minimum occur at metal to ligand volume ratio equals to the combined ratio of metal to ligand.

Interpretation Introduction

(c)

Interpretation:

K_f for the complex should be determined

Concept introduction:

In the method of continuous variation, cation and ligand solutions which have same concentration are mixed in such a way that total number of moles of reactants and the total volume of each mixture are constant. But the mole ratio varies. Then the absorbance of the mixture is measured and absorbance is corrected. The corrected absorbance is plotted against volume fraction of one reactant. A maximum or a minimum occur at metal to ligand volume ratio equals to the combined ratio of metal to ligand.

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Answer 3

Question

Chapter 14, Problem 14.18QAP

Interpretation Introduction

(a)

Interpretation:

The ligand-to-metal ratio in the product should be determined.

Concept introduction:

In the method of continuous variation, cation and ligand solutions which have same concentration are mixed in such a way that total number of moles of reactants and the total volume of each mixture are constant. But the mole ratio varies. Then the absorbance of the mixture is measured and absorbance is corrected. The corrected absorbance is plotted against volume fraction of one reactant. A maximum or a minimum occur at metal to ligand volume ratio equals to the combined ratio of metal to ligand.

Interpretation Introduction

(b)

Interpretation:

Average molar absorptivity of the complex and its uncertainty should be calculated.

Concept introduction:

In the method of continuous variation, cation and ligand solutions which have same concentration are mixed in such a way that total number of moles of reactants and the total volume of each mixture are constant. But the mole ratio varies. Then the absorbance of the mixture is measured and absorbance is corrected. The corrected absorbance is plotted against volume fraction of one reactant. A maximum or a minimum occur at metal to ligand volume ratio equals to the combined ratio of metal to ligand.

Interpretation Introduction

(c)

Interpretation:

K_f for the complex should be determined

Concept introduction:

In the method of continuous variation, cation and ligand solutions which have same concentration are mixed in such a way that total number of moles of reactants and the total volume of each mixture are constant. But the mole ratio varies. Then the absorbance of the mixture is measured and absorbance is corrected. The corrected absorbance is plotted against volume fraction of one reactant. A maximum or a minimum occur at metal to ligand volume ratio equals to the combined ratio of metal to ligand.

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Answer 4

Question

Chapter 14, Problem 14.18QAP

Interpretation Introduction

(a)

Interpretation:

The ligand-to-metal ratio in the product should be determined.

Concept introduction:

In the method of continuous variation, cation and ligand solutions which have same concentration are mixed in such a way that total number of moles of reactants and the total volume of each mixture are constant. But the mole ratio varies. Then the absorbance of the mixture is measured and absorbance is corrected. The corrected absorbance is plotted against volume fraction of one reactant. A maximum or a minimum occur at metal to ligand volume ratio equals to the combined ratio of metal to ligand.

Interpretation Introduction

(b)

Interpretation:

Average molar absorptivity of the complex and its uncertainty should be calculated.

Concept introduction:

In the method of continuous variation, cation and ligand solutions which have same concentration are mixed in such a way that total number of moles of reactants and the total volume of each mixture are constant. But the mole ratio varies. Then the absorbance of the mixture is measured and absorbance is corrected. The corrected absorbance is plotted against volume fraction of one reactant. A maximum or a minimum occur at metal to ligand volume ratio equals to the combined ratio of metal to ligand.

Interpretation Introduction

(c)

Interpretation:

K_f for the complex should be determined

Concept introduction:

In the method of continuous variation, cation and ligand solutions which have same concentration are mixed in such a way that total number of moles of reactants and the total volume of each mixture are constant. But the mole ratio varies. Then the absorbance of the mixture is measured and absorbance is corrected. The corrected absorbance is plotted against volume fraction of one reactant. A maximum or a minimum occur at metal to ligand volume ratio equals to the combined ratio of metal to ligand.

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Answer 5

Chapter 14, Problem 14.18QAP

Interpretation Introduction

(a)

Interpretation:

The ligand-to-metal ratio in the product should be determined.

Concept introduction:

In the method of continuous variation, cation and ligand solutions which have same concentration are mixed in such a way that total number of moles of reactants and the total volume of each mixture are constant. But the mole ratio varies. Then the absorbance of the mixture is measured and absorbance is corrected. The corrected absorbance is plotted against volume fraction of one reactant. A maximum or a minimum occur at metal to ligand volume ratio equals to the combined ratio of metal to ligand.

Interpretation Introduction

(b)

Interpretation:

Average molar absorptivity of the complex and its uncertainty should be calculated.

Concept introduction:

In the method of continuous variation, cation and ligand solutions which have same concentration are mixed in such a way that total number of moles of reactants and the total volume of each mixture are constant. But the mole ratio varies. Then the absorbance of the mixture is measured and absorbance is corrected. The corrected absorbance is plotted against volume fraction of one reactant. A maximum or a minimum occur at metal to ligand volume ratio equals to the combined ratio of metal to ligand.

Interpretation Introduction

(c)

Interpretation:

K_f for the complex should be determined

Concept introduction:

In the method of continuous variation, cation and ligand solutions which have same concentration are mixed in such a way that total number of moles of reactants and the total volume of each mixture are constant. But the mole ratio varies. Then the absorbance of the mixture is measured and absorbance is corrected. The corrected absorbance is plotted against volume fraction of one reactant. A maximum or a minimum occur at metal to ligand volume ratio equals to the combined ratio of metal to ligand.

Answer 6

Chapter 14, Problem 14.18QAP

Interpretation Introduction

(a)

Interpretation:

The ligand-to-metal ratio in the product should be determined.

Concept introduction:

In the method of continuous variation, cation and ligand solutions which have same concentration are mixed in such a way that total number of moles of reactants and the total volume of each mixture are constant. But the mole ratio varies. Then the absorbance of the mixture is measured and absorbance is corrected. The corrected absorbance is plotted against volume fraction of one reactant. A maximum or a minimum occur at metal to ligand volume ratio equals to the combined ratio of metal to ligand.

Answer 7

Chapter 14, Problem 14.18QAP

Interpretation Introduction

(a)

Interpretation:

The ligand-to-metal ratio in the product should be determined.

Concept introduction:

In the method of continuous variation, cation and ligand solutions which have same concentration are mixed in such a way that total number of moles of reactants and the total volume of each mixture are constant. But the mole ratio varies. Then the absorbance of the mixture is measured and absorbance is corrected. The corrected absorbance is plotted against volume fraction of one reactant. A maximum or a minimum occur at metal to ligand volume ratio equals to the combined ratio of metal to ligand.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Average molar absorptivity of the complex and its uncertainty should be calculated.

Concept introduction:

In the method of continuous variation, cation and ligand solutions which have same concentration are mixed in such a way that total number of moles of reactants and the total volume of each mixture are constant. But the mole ratio varies. Then the absorbance of the mixture is measured and absorbance is corrected. The corrected absorbance is plotted against volume fraction of one reactant. A maximum or a minimum occur at metal to ligand volume ratio equals to the combined ratio of metal to ligand.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Average molar absorptivity of the complex and its uncertainty should be calculated.

Concept introduction:

In the method of continuous variation, cation and ligand solutions which have same concentration are mixed in such a way that total number of moles of reactants and the total volume of each mixture are constant. But the mole ratio varies. Then the absorbance of the mixture is measured and absorbance is corrected. The corrected absorbance is plotted against volume fraction of one reactant. A maximum or a minimum occur at metal to ligand volume ratio equals to the combined ratio of metal to ligand.

Answer 10

Interpretation Introduction

(c)

Interpretation:

K_f for the complex should be determined

Concept introduction:

In the method of continuous variation, cation and ligand solutions which have same concentration are mixed in such a way that total number of moles of reactants and the total volume of each mixture are constant. But the mole ratio varies. Then the absorbance of the mixture is measured and absorbance is corrected. The corrected absorbance is plotted against volume fraction of one reactant. A maximum or a minimum occur at metal to ligand volume ratio equals to the combined ratio of metal to ligand.

Answer 11

Interpretation Introduction

(c)

Interpretation:

K_f for the complex should be determined

Concept introduction:

In the method of continuous variation, cation and ligand solutions which have same concentration are mixed in such a way that total number of moles of reactants and the total volume of each mixture are constant. But the mole ratio varies. Then the absorbance of the mixture is measured and absorbance is corrected. The corrected absorbance is plotted against volume fraction of one reactant. A maximum or a minimum occur at metal to ligand volume ratio equals to the combined ratio of metal to ligand.

Answer 12

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Ch. 14 - Prob. 14.1QAP Ch. 14 - A 0.4740-g pesticide sample was decomposed by wet...Ch. 14 - Sketch a photometric titration curve for the...Ch. 14 - Prob. 14.4QAP Ch. 14 - Prob. 14.5QAP Ch. 14 - The accompanying data (1.00-cm cells) were...Ch. 14 - A 3.03-g petroleum specimen was decomposed by wet...Ch. 14 - Prob. 14.8QAP Ch. 14 - Prob. 14.9QAP Ch. 14 - The acid-base indicator HIn undergoes the...

Solution Summary: The author explains that the ligand-to-metal ratio in the product should be determined.

Chapter 14 Solutions