Concept explainers
(a)
Interpretation:
The precursor, oxo-acid and reaction for formation of the oxide has to be given. Also, draw the Lewis structure of
Concept Introduction:
Lewis structure: This is the only way to show the sharing of electrons between atom in polar covalent bonds or covalent bond. This is often called as Lewis structure. This structure denotes valence electrons of an atom by dots and also it shows the way of valence electron distributed within a molecule.
(b)
Interpretation:
The reason for bonds to the terminal oxygen are shorter than the bonds to the bridging oxygen has to be given.
Concept Introduction:
Bond length is inversely proportional to the bond order.
A higher bond order results in a shorter bond for a given pair of atoms.
(c)
Interpretation:
The balanced equation between
Concept Introduction:
Balanced Chemical equation:
A balanced chemical equation is an equation which contains same elements in same number on both the sides (reactant and product side) of the chemical equation thereby obeying the law of conservation of mass.
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Chapter 14 Solutions
CHEMISTRY:MOLEC NAT PRINT COMPANION
- Nonearrow_forward3. A molecular form of "dicarbon", C2, can be generated in gas phase. Its bond dissociation energy has been determined at 599 kJ/mol. Use molecular orbital theory to explain why energy of dissociation for C₂+ is 513 kJ/mol, and that for C2² is 818 kJ/mol. (10 points)arrow_forward9.73 g of lead(IV) chloride contains enough Cl- ions to make ____ g of magnesium chloride.arrow_forward
- 6. a) C2's. Phosphorus pentafluoride PF5 belongs to D3h symmetry group. Draw the structure of the molecule, identify principal axis of rotation and perpendicular (4 points) b) assume that the principal axis of rotation is aligned with z axis, assign symmetry labels (such as a1, b2, etc.) to the following atomic orbitals of the P atom. (character table for this group is included in the Supplemental material). 3s 3pz (6 points) 3dz²arrow_forward2. Construct Lewis-dot structures, and draw VESPR models for the ions listed below. a) SiF5 (4 points) b) IOF4 (4 points)arrow_forward5. Complex anion [AuCl2]¯ belongs to Doh symmetry point group. What is the shape of this ion? (4 points)arrow_forward
- 4. Assign the following molecules to proper point groups: Pyridine N 1,3,5-triazine N Narrow_forward7. a) Under normal conditions (room temperature & atmospheric pressure) potassium assumes bcc lattice. Atomic radius for 12-coordinate K atom is listed as 235 pm. What is the radius of potassium atom under normal conditions? (3 points) b) Titanium metal crystallyzes in hcp lattice. Under proper conditions nitrogen can be absorbed into the lattice of titanium resulting in an alloy of stoichiometry TiNo.2. Is this compound likely to be a substitutional or an interstitial alloy? (Radius of Ti (12-coordinate) is 147 pm; radius of N atom is 75 pm. (3 points)arrow_forwardcan someone answer the questions and draw out the complete mechanismarrow_forward
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