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Each of the following names is wrong. Give the structure and correct name of
each compound.
a
b
c.
d.
![Check Mark](/static/check-mark.png)
(a)
Interpretation:
The structural formula of
Concept introduction:
The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.
Rules for writing the structural formula from IUPAC are:
• First identify the word root for the given compound.
• The suffix used in the compound like –ane, ene, yne, ol, al and so on.
• Identify the position, location, and number of the substituent bonded to the carbon chain.
Aldehydes and ketones contain carbonyl functional group in their parent chain and are named by adding suffix –al and –one to the name of the parent alkane.
Answer to Problem 14.11E
The structural formula of
The correct name is
Explanation of Solution
The given name is
Figure 1
The longest carbon chain contains five carbon atoms. One methyl substituent is attached to the third carbon atom. The functional group present in the given compound is ketone
The structural formula is shown in Figure 1.
The correct name of the compound is
![Check Mark](/static/check-mark.png)
(b)
Interpretation:
The structural formula of
Concept introduction:
The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.
Rules for writing the structural formula from IUPAC are:
• First identify the word root for the given compound.
• The suffix used in the compound like –ane, ene, yne, ol, al and so on.
• Identify the position, location, and number of the substituent bonded to the carbon chain.
Aldehydes and ketones contain carbonyl functional group in their parent chain and are named by adding suffix –al and –one to the name of the parent alkane.
Answer to Problem 14.11E
The structural formula of
The correct name is
Explanation of Solution
The given name is
Figure 2
The longest carbon chain contains four carbon atoms. One methyl substituent is attached to the second carbon atom. The functional group present in the given compound is aldehyde
The structural formula is shown in Figure 2.
The correct name of the compound is
![Check Mark](/static/check-mark.png)
(c)
Interpretation:
The structural formula of
Concept introduction:
The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.
Rules for writing the structural formula from IUPAC are:
• First identify the word root for the given compound.
• The suffix used in the compound like –ane, ene, yne, ol, al and so on.
• Identify the position, location, and number of the substituent bonded to the carbon chain.
Aldehydes and ketones contain carbonyl functional group in their parent chain and are named by adding suffix –al and –one to the name of the parent alkane.
Answer to Problem 14.11E
The structural formula of
The correct name is
Explanation of Solution
The given name is
Figure 3
The longest carbon chain contains eight carbon atoms. One methyl substituent is attached to the fourth carbon atom and the other methyl group is attached to the fifth carbon atom. The functional group present in the given compound is ketone
The structural formula is shown in Figure 3.
The correct name of the compound is
![Check Mark](/static/check-mark.png)
(d)
Interpretation:
The structural formula of
Concept introduction:
The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done in such a way that the structure of organic compound is correctly interpreted from the name.
Rules for writing the structural formula from IUPAC are:
• First identify the word root for the given compound.
• The suffix used in the compound like –ane, ene, yne, ol, al and so on.
• Identify the position, location, and number of the substituent bonded to the carbon chain.
Aldehydes and ketones contain carbonyl functional group in their parent chain and are named by adding suffix –al and –one to the name of the parent alkane.
Answer to Problem 14.11E
The structural formula of
The correct name is
Explanation of Solution
The given name is
Figure 4
The longest carbon chain contains three carbon atoms. One phenyl substituent is attached to the second carbon atom. The functional group present in the given compound is aldehyde
The structural formula is shown in Figure 4.
The correct name of the compound is
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Chapter 14 Solutions
Study Guide with Student Solutions Manual for Seager/Slabaugh/Hansen's Chemistry for Today: General, Organic, and Biochemistry, 9th Edition
- Q1: For each molecule, assign each stereocenter as R or S. Circle the meso compounds. Label each compound as chiral or achiral. OH HO CI Br H CI CI Br CI CI Xf x f g Br D OH Br Br H₂N R. IN Ill I -N S OMe D II H CO₂H 1/111 DuckDuckGarrow_forwardThese are synthesis questions. You need to show how the starting material can be converted into the product(s) shown. You may use any reactions we have learned. Show all the reagents you need. Show each molecule synthesized along the way and be sure to pay attention to the regiochemistry and stereochemistry preferences for each reaction. If a racemic molecule is made along the way, you need to draw both enantiomers and label the mixture as "racemic". All of the carbon atoms of the products must come from the starting material! ? H Harrow_forwardQ5: Draw every stereoisomer for 1-bromo-2-chloro-1,2-difluorocyclopentane. Clearly show stereochemistry by drawing the wedge-and-dashed bonds. Describe the relationship between each pair of the stereoisomers you have drawn.arrow_forward
- Classify each pair of molecules according to whether or not they can participate in hydrogen bonding with one another. Participate in hydrogen bonding CH3COCH3 and CH3COCH2CH3 H2O and (CH3CH2)2CO CH3COCH3 and CH₂ CHO Answer Bank Do not participate in hydrogen bonding CH3CH2OH and HCHO CH3COCH2CH3 and CH3OHarrow_forwardNonearrow_forwardQ4: Comparing (3S,4S)-3,4-dimethylhexane and (3R,4S)-3,4-dimethylhexane, which one is optically active? Briefly explain.arrow_forward
- Nonearrow_forwardNonearrow_forwardGiven the standard enthalpies of formation for the following substances, determine the reaction enthalpy for the following reaction. 4A (g) + 2B (g) → 2C (g) + 7D (g) AHrxn =?kJ Substance AH in kJ/mol A (g) - 20.42 B (g) + 32.18 C (g) - 72.51 D (g) - 17.87arrow_forward
- Determine ASran for Zn(s) + 2HCl(aq) = ZnCl2(aq) + H2(aq) given the following information: Standard Entropy Values of Various Substance Substance So (J/mol • K) 60.9 Zn(s) HCl(aq) 56.5 130.58 H2(g) Zn2+(aq) -106.5 55.10 CI (aq)arrow_forward3) Catalytic hydrogenation of the compound below produced the expected product. However, a byproduct with molecular formula C10H12O is also formed in small quantities. What is the by product?arrow_forwardWhat is the ΔHorxn of the reaction? NaOH(aq) + HCl(aq) → H2O(l) + NaCl(aq) ΔHorxn 1= ________ kJ/molarrow_forward
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