
Masteringchemistry with Pearson Etext -- Standalone Access Card -- For Chemistry
3rd Edition
ISBN: 9780321806383
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 14, Problem 12E
Interpretation Introduction
To determine: Reaction quotient for a reaction and its use.
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Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
Chapter 14 Solutions
Masteringchemistry with Pearson Etext -- Standalone Access Card -- For Chemistry
Ch. 14 - Prob. 1SAQCh. 14 - Q2. The equilibrium constant for the reaction...Ch. 14 - Q3. Use the data shown here to find the...Ch. 14 - Prob. 4SAQCh. 14 - Prob. 5SAQCh. 14 - Q6. For the reaction 2 A(g) B(g), the equilibrium...Ch. 14 - Q7. Consider the reaction between iodine gas and...Ch. 14 - Prob. 8SAQCh. 14 - Prob. 9SAQCh. 14 - Prob. 10SAQ
Ch. 14 - Prob. 11SAQCh. 14 - Prob. 12SAQCh. 14 - 1. How does a developing fetus get oxygen in the...Ch. 14 - Prob. 2ECh. 14 - Prob. 3ECh. 14 - Prob. 4ECh. 14 - Prob. 5ECh. 14 - Prob. 6ECh. 14 - Prob. 7ECh. 14 - Prob. 8ECh. 14 - Prob. 9ECh. 14 - Prob. 10ECh. 14 - Prob. 11ECh. 14 - Prob. 12ECh. 14 - Prob. 13ECh. 14 - Prob. 14ECh. 14 - Prob. 15ECh. 14 - Prob. 16ECh. 14 - Prob. 17ECh. 14 - Prob. 18ECh. 14 - Prob. 19ECh. 14 - Prob. 20ECh. 14 - Prob. 21ECh. 14 - Prob. 22ECh. 14 - 23. When this reaction comes to equilibrium, will...Ch. 14 - Prob. 24ECh. 14 - 25. H2 and I2 are combined in a flask and allowed...Ch. 14 - Prob. 26ECh. 14 - Prob. 27ECh. 14 - 28. This reaction has an equilibrium constant of...Ch. 14 - 29. Consider the reactions and their respective...Ch. 14 - 30. Use the reactions and their equilibrium...Ch. 14 - 31. Calculate Kc for each reaction.
a. I2(g) 2...Ch. 14 - 32. Calculate Kp for each reaction.
a. N2O4(g) 2...Ch. 14 - 33. Write an equilibrium expression for each...Ch. 14 - 34. Find and fix the mistake in the equilibrium...Ch. 14 - 35. Consider the reaction:
CO(g) + 2 H2(g) ...Ch. 14 - 36. Consider the reaction:
NH4HS(s) NH3(g) +...Ch. 14 - 37. Consider the reaction:
N2(g) + 3 H2(g) 2...Ch. 14 - 38. Consider the following reaction:
H2(g) + I2(g)...Ch. 14 - 39. Consider the reaction:
2 NO(g) + Br2(g) 2...Ch. 14 - 40. Consider the reaction:
SO2Cl2(g) SO2(g) +...Ch. 14 - 41. For the reaction A(g) 2 B(g), a reaction...Ch. 14 - 42. For the reaction 2 A(g) B(g) + 2 C(g), a...Ch. 14 - 43. Consider the reaction:
Fe3+(aq) + SCN–(aq) ...Ch. 14 - 44. Consider the reaction:
SO2Cl2(g) SO2(g) +...Ch. 14 - 45. Consider the reaction:
H2(g) + I2(g) 2...Ch. 14 - 46. Consider the reaction:
CO(g) + 2 H2(g) ...Ch. 14 - 47. Consider the reaction:
NH4HS(s) NH3(g) +...Ch. 14 - 48. Consider the reaction:
2 H2S(g) 2 H2(g) +...Ch. 14 - 49. Silver sulfate dissolves in water according to...Ch. 14 - 50. Nitrogen dioxide dimerizes according to the...Ch. 14 - 51. Consider the reaction and the associated...Ch. 14 - 52. Consider the reaction and the associated...Ch. 14 - 53. For the reaction shown here, Kc = 0.513 at 500...Ch. 14 - 54. For the reaction shown here, Kc = 255 at 1000...Ch. 14 - 55. Consider the reaction:
NiO(s) + CO(g) Ni(s) +...Ch. 14 - 56. Consider the reaction:
CO(g) + H2O(g) CO2(g)...Ch. 14 - 57. Consider the reaction:
HC2H3O2(aq) + H2O(l) ...Ch. 14 - 58. Consider the reaction:
SO2Cl2(g) SO2(g) +...Ch. 14 - 59. Consider the reaction:
Br2(g) + Cl2(g) 2...Ch. 14 - 60. Consider the reaction:
CO(g) + H2O(g) CO2(g)...Ch. 14 - Prob. 61ECh. 14 - Prob. 62ECh. 14 - Prob. 63ECh. 14 - 64. Consider this reaction at equilibrium:
2...Ch. 14 - 65. Consider this reaction at equilibrium:
2...Ch. 14 - 66. Consider this reaction at equilibrium:
C(s) +...Ch. 14 - 67. Each reaction is allowed to come to...Ch. 14 - Prob. 68ECh. 14 - Prob. 69ECh. 14 - Prob. 70ECh. 14 - Prob. 71ECh. 14 - Prob. 72ECh. 14 - 73. Carbon monoxide replaces oxygen in oxygenated...Ch. 14 - Prob. 74ECh. 14 - Prob. 75ECh. 14 - 76. A mixture of water and graphite is heated to...Ch. 14 - 77. At 650 K, the reaction MgCO3(s) MgO(s) +...Ch. 14 - 78. A system at equilibrium contains I2(g) at a...Ch. 14 - Prob. 79ECh. 14 - Prob. 80ECh. 14 - Prob. 81ECh. 14 - Prob. 82ECh. 14 - Prob. 83ECh. 14 - Prob. 84ECh. 14 - 85. The system described by the reaction: CO(g) +...Ch. 14 - Prob. 86ECh. 14 - 87. At 70 K, CCl4 decomposes to carbon and...Ch. 14 - 88. The equilibrium constant for the reaction...Ch. 14 - 89. A sample of CaCO3(s) is introduced into a...Ch. 14 - Prob. 90ECh. 14 - Prob. 91ECh. 14 - Prob. 92ECh. 14 - Prob. 93ECh. 14 - Prob. 94ECh. 14 - Prob. 95ECh. 14 - Prob. 96ECh. 14 - Prob. 97ECh. 14 - 98. When N2O5(g) is heated, it dissociates into...Ch. 14 - 99. A sample of SO3 is introduced into an...Ch. 14 - 100. A reaction A(g) B(g) has an equilibrium...Ch. 14 - Prob. 101ECh. 14 - Prob. 102ECh. 14 - Prob. 103ECh. 14 - Prob. 104E
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