Chemistry
3rd Edition
ISBN: 9780073402734
Author: Julia Burdge
Publisher: MCGRAW-HILL HIGHER EDUCATION
expand_more
expand_more
format_list_bulleted
Question
Chapter 14, Problem 128AP
Interpretation Introduction
Interpretation:
The order of reaction and time required to hydrolyze
Concept introduction:
The order of reaction is the number that relates the rate of a
The equation which relates the rate of a reaction to the concentration of reactants is the rate law. For the reaction as:
The rate law is as follows:
Rate constant for a reaction is the proportionality constantthatrelates the
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
The reaction of ethanol with oxygen to yield carbon dioxide and water. (This is the reaction in a flambéed dessert or when an alcoholic beverage is ignited.)
C2H6O + O2 → CO2 + H2O
mole
5. The average human requires 120 grams of glucose, C&H12O6 per day. How many grams of CO2
are required to produce this amount of glucose in plants?
The photosynthetic reaction is:
6 CO2 + 6 H2O →
C,H12O6 + 6O2
Energy, and Reaction Rates
25 pts
st: Heat, Energy, and Reaction Rates
Answered
✓ SKETCHPAD
Question 11
Draw a complete enthalpy diagram for the following reaction:
→
4Na(s) + O2(g) 2Na₂(s) AH = 178 kJ
T
PENCIL THIN ♥
BLACK Y
Chapter 14 Solutions
Chemistry
Ch. 14.1 - Practice Problem ATTEMPT
Write the rate...Ch. 14.1 - Practice ProblemBUILD Write the balanced equation...Ch. 14.1 - Prob. 1PPCCh. 14.1 - 14.1.1 Which expressions are correct for the rate...Ch. 14.1 - 14.1.2 In the same reaction:
if the concentration...Ch. 14.2 - Practice Problem ATTEMPT Consider the reaction:...Ch. 14.2 - Practice Problem BUILD Consider the following...Ch. 14.2 - Practice Problem CONCEPTUALIZE
Consider the...Ch. 14.2 - Answer questions 14.2.1 through 14.2.4 using the...Ch. 14.2 - Answer questions 14.2.1 through 14.2.4 using the...
Ch. 14.2 - Answer questions 14.2.1 through 14.2.4 using the...Ch. 14.2 - Answer questions 14.2.1 through 14.2.4 using the...Ch. 14.2 - 14.2.5 The diagrams represent three experiments in...Ch. 14.3 - Prob. 1PPACh. 14.3 - Practice Problem BUILD
For the following general...Ch. 14.3 - Practice Problem CONCEPTUALIZE
Three initial-rate...Ch. 14.3 - The first-order decomposition of dinitrogen...Ch. 14.3 - The first-order decomposition of dinitrogen...Ch. 14.3 - 14.3.3 Consider the first-order reaction in which...Ch. 14.3 - Which figure below represents the numbers of...Ch. 14.3 - 14.3.5 Of the plots shown here, ___________...Ch. 14.4 - Practice Problem ATTEMPT
The rate constant for the...Ch. 14.4 - Practice Problem BUILD
Refer again to the reaction...Ch. 14.4 - Practice Problem CONCEPTUALIZE
The diagrams on...Ch. 14.4 - Use the table of data collected for a first-order...Ch. 14.4 - Prob. 2CPCh. 14.4 - Prob. 3CPCh. 14.5 - Practice Problem ATTEMPT Ethyl iodide ( C 2 H 5 I)...Ch. 14.5 - Practice Problem BUILD Use the calculated k from...Ch. 14.5 - Practice Problem CONCEPTUALIZE
Use the graph in...Ch. 14.5 - Use the following information to answer questions...Ch. 14.5 - Use the following information to answer questions...Ch. 14.5 - Use the following information to answer questions...Ch. 14.5 - 14.5.4 A plausible mechanism for the reaction:
Ch. 14.6 - Practice ProblemATTEMPT Calculate the half-life of...Ch. 14.6 - Practice ProblemBUILD Calculate the rate constant...Ch. 14.6 - Practice Problem CONCEPTUALIZE
The diagrams show a...Ch. 14.7 - Practice Problem ATTEMPT
The reaction is second...Ch. 14.7 - Practice Problem BUILD
Determine the initial...Ch. 14.7 - Practice ProblemCONCEPTUALIZE The diagrams below...Ch. 14.8 - Practice ProblemATTEMPT The second-order rate...Ch. 14.8 - Practice Problem BUILD Use the graph to determine...Ch. 14.8 - Prob. 1PPCCh. 14.9 - Practice ProblemATTEMPT Use the data in the...Ch. 14.9 - Practice ProblemBUILD Based on the data shown in...Ch. 14.9 - Practice Problem CONCEPTUALIZE
According to the...Ch. 14.10 - Practice ProblemATTEMPT Calculate the rate...Ch. 14.10 - Practice ProblemBUILD Calculate the rate constant...Ch. 14.10 - Practice ProblemCONCEPTUALIZE According to the...Ch. 14.11 - Practice Problem ATTEMPT
The reaction between and...Ch. 14.11 - Practice ProblemBUILD Propose a plausible...Ch. 14.11 - Practice Problem CONCEPTUALIZE
How many steps are...Ch. 14.12 - Practice Problem ATTEMPT
Show that the following...Ch. 14.12 - Practice Problem BUILD
The reaction proceeds via...Ch. 14.12 - Practice Problem CONCEPTUALIZE
The reaction of is...Ch. 14 - Prob. 1KSPCh. 14 - Prob. 2KSPCh. 14 - Prob. 3KSPCh. 14 - Prob. 4KSPCh. 14 - 14.1 What is meant by the rate of a chemical...Ch. 14 - Distinguish between average rate and instantaneous...Ch. 14 - What are the advantages of measuring the initial...Ch. 14 - Identify two reactions that are very slow (take...Ch. 14 - Write the reaction rate expressions for the...Ch. 14 - Write the reaction rate expressions for the...Ch. 14 - Consider the reaction: 2NO ( g ) + O 2 ( g ) → 2NO...Ch. 14 - 14.8 Consider the reaction:
Suppose that at a...Ch. 14 - 14.9 Explain what is meant by the rate law of a...Ch. 14 - Prob. 10QPCh. 14 - What are the units for the rate constants of...Ch. 14 - 14.12 Consider the zeroth-order reaction: a ...Ch. 14 - 14.13 The rate constant of a first-order reaction...Ch. 14 - Identify two reactions that are very slow (take...Ch. 14 - The rate law for the reaction: N H 4 + ( a q )+N O...Ch. 14 - Use the data in Table 14.2 to calculate the rate...Ch. 14 - 14.17 Consider the reaction:
From the following...Ch. 14 - Consider the reaction: X + Y → Z From the...Ch. 14 - Determine the overall orders of the reactions to...Ch. 14 - 14.20 Consider the reaction:
The rate of the...Ch. 14 - Cyclobutane decomposes to ethylene according to...Ch. 14 - The following gas-phase reaction was studied at...Ch. 14 - Write an equation relating the concentration of a...Ch. 14 - 14.24 Define half-life. Write the equation...Ch. 14 - Prob. 25QPCh. 14 - 14.26 For a first-order reaction, how long will it...Ch. 14 - What is the half-life of a compound if 75 percent...Ch. 14 - 14.28 The thermal decomposition of phosphine into...Ch. 14 - The rate constant for the second-order reaction:...Ch. 14 - The rate constant for the second-order reaction:...Ch. 14 - 14.31 The second-order rate constant for the...Ch. 14 - Prob. 32QPCh. 14 - 14.33 The reaction shown here follows first-order...Ch. 14 - 14 34 Define activation energy. What role does...Ch. 14 - Prob. 35QPCh. 14 - Prob. 36QPCh. 14 - The burning of methane in oxygen is a highly...Ch. 14 - Sketch a potential-energy versus reaction progress...Ch. 14 - The reaction H+H 2 → H 2 +H has been studied for...Ch. 14 - Over the range of about ±3°C from normal body...Ch. 14 - For the reaction: NO ( g ) + O 3 ( g ) → NO 2 ( g...Ch. 14 - The rate constant of a first-order reaction is 4...Ch. 14 - The rate constants of some reactions double with...Ch. 14 - 14.44 The rate at which tree crickets chirp is ...Ch. 14 - The rate of bacterial hydrolysis of fish muscle is...Ch. 14 - Prob. 46QPCh. 14 - Given the same reactant concentrations, the...Ch. 14 - 14.48 Variation of the rate constant with...Ch. 14 - 14.49 Diagram A describes the initial state of...Ch. 14 - 14 50 What do we mean by the mechanism of a...Ch. 14 - 14.51 What is an elementary step? What is the...Ch. 14 - 14.52 Classify the following elementary reactions...Ch. 14 - Reactions can be classified as unimolecular,...Ch. 14 - Determine the molecularity, and write the rate law...Ch. 14 - 14.55 What is the rate-determining step of a...Ch. 14 - 14.56 The equation for the combustion of ethane ...Ch. 14 - Specify which of the following species cannot be...Ch. 14 - Classify each of the following elementary steps as...Ch. 14 - 14.59 The rate law for the reaction:
is given by...Ch. 14 - For the reaction x 2 + y + z → x y + x z , it is...Ch. 14 - The rate law for the reaction: 2H 2 ( g ) + 2NO (...Ch. 14 - 14.62 The rate law for the decomposition of ozone...Ch. 14 - 14.63 How does a catalyst increase the rate of a...Ch. 14 - 14.64 What are the characteristics of a...Ch. 14 - A certain reaction is known to proceed slowly at...Ch. 14 - Most reactions, including enzyme-catalyzed...Ch. 14 - 14.67 Are enzyme-catalyzed reactions examples of...Ch. 14 - The concentrations of enzymes in cells are usually...Ch. 14 - When fruits such as apples and pears are cut. the...Ch. 14 - The first-order rate constant for the dehydration...Ch. 14 - Which two potential-energy profiles represent the...Ch. 14 - Consider the following mechanism for the...Ch. 14 - List four factors that influence the rate of a...Ch. 14 - 14.71 Suggest experimental means by which the...Ch. 14 - 14.75 “The rate constant for the reaction:
is .”...Ch. 14 - Prob. 76APCh. 14 - The following diagrams represent the progress of...Ch. 14 - The following diagrams show the progress of the...Ch. 14 - Prob. 79APCh. 14 - Prob. 80APCh. 14 - 14.81 When methyl phosphate is heated in acid...Ch. 14 - The rate of the reaction: CH 3 COOC 2 H 5 ( a q )...Ch. 14 - Explain why most metals used in catalysis are...Ch. 14 - Prob. 84APCh. 14 - The bromination of acetone is acid-catalyzed: CH 3...Ch. 14 - The decomposition of N 2 O to N 2 and O 2 is a...Ch. 14 - 14.87 The reaction proceeds slowly in aqueous...Ch. 14 - Prob. 88APCh. 14 - The integrated rate law for the zeroth-order...Ch. 14 - 14.90 A flask contains a mixture of compounds A...Ch. 14 - Prob. 91APCh. 14 - 14.92 The rate law for the reaction . Which of the...Ch. 14 - 14.93 The reaction of to form 2EG is exothermic,...Ch. 14 - 14.94 The activation energy for the decomposition...Ch. 14 - Prob. 95APCh. 14 - 14.96 When 6 g of granulated Zn is added to a...Ch. 14 - Prob. 97APCh. 14 - 14.98 A certain first-order reaction is 35.5...Ch. 14 - 14.99 The decomposition of dinitrogen pentoxide...Ch. 14 - 14.100 The thermal decomposition of obeys...Ch. 14 - 14.101 When a mixture of methane and bromine is...Ch. 14 - 14.102 The rate of the reaction between to form...Ch. 14 - The rate constant for the gaseous reaction: H 2 (...Ch. 14 - A gas mixture containing CH 3 fragments. C 2 H 6...Ch. 14 - Consider the following elementary step: X + 2Y →...Ch. 14 - 14.106 The following scheme in which A is...Ch. 14 - 14.107 (a) Consider two reactions, A and B. If the...Ch. 14 - The rate law for the following reaction: CO ( g )...Ch. 14 - Consider the following elementary steps for a...Ch. 14 - Prob. 110APCh. 14 - Consider the following potential-energy profile...Ch. 14 - The rate of a reaction was followed by the...Ch. 14 - 14.113 The first-order rate constant for the...Ch. 14 - 14.114 Many reactions involving heterogeneous...Ch. 14 - Thallium(I) is oxidized by cerium(IV) as follows:...Ch. 14 - The activation energy for the reaction: N 2 O ( g...Ch. 14 - Δ H ° for the reaction in Problem 14.116 is -164...Ch. 14 - 14.118 At a certain elevated temperature, ammonia...Ch. 14 - 14.119 The following expression shows the...Ch. 14 - In a certain industrial process involving a...Ch. 14 - Strontium-90, a radioactive isotope, is a major...Ch. 14 - Prob. 122APCh. 14 - Prob. 123APCh. 14 - A factory that specializes in the refinement of...Ch. 14 - 14.125 When the concentration of A in the reaction...Ch. 14 - 14.126 The activity of a radioactive sample is the...Ch. 14 - Prob. 127APCh. 14 - Prob. 128APCh. 14 - Prob. 129APCh. 14 - Prob. 130APCh. 14 - Prob. 131APCh. 14 - Prob. 132APCh. 14 - Prob. 133APCh. 14 - 14.134 At a certain elevated temperature, ammonia...Ch. 14 - Polyethylene is used in many items, including...Ch. 14 - In recent years, ozone in the stratosphere has...Ch. 14 - Metastron, an aqueous solution of 89 SrCl 2 , is a...Ch. 14 - Metastron, an aqueous solution of 89 SrCl 2 , is a...Ch. 14 - Metastron, an aqueous solution of 89 SrCl 2 , is a...Ch. 14 - Metastron, an aqueous solution of 89 SrCl 2 , is a...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- What is incomplete combustion of fossil fuels? Why can this be a problem?arrow_forwardClassify the following processes according to their rates as very slow, slow, or fast: a.The souring of milk stored in a refrigerator b.The cooking of an egg in boiling water c.The rusting of a shovel left in the garden over the winter d.The growing of corn during a warm summer e.The burning of a lighted match.arrow_forwardxplain why aluminum cans make good storage containers for soft drinks. Styrofoam cups can be used to keep coffee hot and cola cold. How can this be?arrow_forward
- One of the components of polluted air is NO. It is formed in the high-temperature environment of internal combustion engines by the following reaction: N2(g)+O2(g)2NO(g)H=180KJ Why are high temperatures needed to convert N2 and O2 to NO?arrow_forward4.60 Why are fuel additives used?arrow_forwardWhen table sugar (sucrose), C12H22O11(s) is digested, it is broken down by reacting with water to produce two simple sugars, glucose and fructose, each with the formula C6H12O6(s). [T/3] C12H22O11(s) + H2O(l) → C6H12O6(s) + C6H12O6(s) An experiment was performed and the following data were obtained: Run Initial [sucrose] (mol/L) Rate (mol/(L s)) 1 0.050 3.09 10–5 2 0.100 6.17 10–5 3 0.250 1.54 10–4 Determine the value of the rate constant.arrow_forward
- The addition of HBr to CH2=CH2, an exothermic reaction. Define this ?arrow_forwardEthylene (C2H4) plays an important role in the ripening of certain fruits and vegetables. It is sometimes supplemented under controlled conditions at produce—processing facilities but is also produced naturally by many fruit-bearing plants. Although the actual process by which plants produce ethylene is a complex one, imagine that it is produced by the simple breakdown of glucose according to the equation: C6H12O6 (s) --> 3 C2H4 (g) + 3 O2 (g) Given S°= 212.1 J/molK, ▲G°= -910.56 kJ/mol and ▲H°= -1274.5 kJ/mol for C6H12O6 (s). a.) Determine the sign of ▲S° for the reaction. b.) Calculate ▲S° for the reaction. c.) Using the tabulated ▲G° values in the appendix, calculate ▲G° for the reaction. d.) Above what temperature (in °C) is the reaction spontaneous? Hint: you will first have to calculate H° using tabulated values.arrow_forwardWhich statement is TRUE regarding a catalyst and the function it serves in a chemical reaction? O A catalyst is consumed in a reaction O A catalyst often targets the fastest step in the reaction mechanism O A catalyst lowers the energy of the products of the reaction O A catalyst does not change the enthalpy change of the net reactionarrow_forward
- 21arrow_forwardIn the oxidation of carbon monoxide to carbon dioxide, 2CO(g) + O₂(g) - 2CO₂(g)arrow_forward4. Given the following equation: Cu + 2 AgNO; → Cu(NO3), + 2 Ag How many moles of Cu are needed to react with 350 g AgNO,? If 89.5 grams of Ag were produced, how many grams of Cu reacted? DELL & $ 7 3 4 r y e d. f g h. 23arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Introductory Chemistry: A FoundationChemistryISBN:9781285199030Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
- World of Chemistry, 3rd editionChemistryISBN:9781133109655Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCostePublisher:Brooks / Cole / Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Introductory Chemistry: A Foundation
Chemistry
ISBN:9781285199030
Author:Steven S. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
World of Chemistry, 3rd edition
Chemistry
ISBN:9781133109655
Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Publisher:Brooks / Cole / Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Kinetics: Chemistry's Demolition Derby - Crash Course Chemistry #32; Author: Crash Course;https://www.youtube.com/watch?v=7qOFtL3VEBc;License: Standard YouTube License, CC-BY