Organic Chemistry

8th Edition

ISBN: 9781305580350

Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher: Cengage Learning

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Textbook Question

Chapter 13.5, Problem 13.2P

State the number of sets of equivalent hydrogens in each compound and the number of hydrogens in each set.

(a) 3-Methylpentane
(b) 2,2,4-Trimethylpentane

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Chapter 13.2, Problem 13.1P

Chapter 13.5, Problem 13.3P

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Chapter 13 Solutions

Organic Chemistry

Ch. 13.2 - Calculate the ratio of nuclei in the higher spin...Ch. 13.5 - State the number of sets of equivalent hydrogens...Ch. 13.5 - Each compound gives only one signal in its 1H-NMR...Ch. 13.6 - The line of integration of the two signals in the...Ch. 13.7 - Following are two constitutional isomers with the...Ch. 13.8 - Following are pairs of constitutional isomers....Ch. 13.10 - Following is a 1H-NMR spectrum of 2-butanol....Ch. 13.11 - Explain how to distinguish between the members of...Ch. 13 - Prob. 13.9P Ch. 13 - Prob. 13.10P

Ch. 13 - Prob. 13.11P Ch. 13 - Following are structural formulas for three...Ch. 13 - Following arc structural formulas for the cis...Ch. 13 - Prob. 13.14P Ch. 13 - Following are three compounds with the molecular...Ch. 13 - Following are 1H-NMR spectra for compounds D, E,...Ch. 13 - Following are 1H-NMR spectra for compounds G, H,...Ch. 13 - Propose a structural formula for compound J,...Ch. 13 - Compound K, molecular formula C6H14O, readily...Ch. 13 - Compound M, molecular formula C5H10O, readily...Ch. 13 - Following is the 1H-NMR spectrum of compound O,...Ch. 13 - Treatment of compound P with BH3 followed by...Ch. 13 - The 1H-NMR spectrum of compound R, C6H14O,...Ch. 13 - Write structural formulas for the following...Ch. 13 - Prob. 13.25P Ch. 13 - Ascaridole is a natural product that has been used...Ch. 13 - The 13C-NMR spectrum of 3-methyl-2-butanol shows...Ch. 13 - Prob. 13.28P

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State the number of sets of equivalent hydrogens in each compound and the number of hydrogens in each set. (a) 3-Methylpentane (b) 2,2,4-Trimethylpentane

Solution Summary: The author explains that the number of sets of equivalent hydrogens in each compound, and their chemical shift values, has to be identifed.

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