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Concept explainers
(a)
Interpretation:
The reaction of ethanal with Tollens’ reagent has to be written.
Concept Introduction:
Tollens’ reagent is basic solution of silver ammonia complex. It is mainly used for oxidation of aldehydes. The silver ion is reduced to silver metal as the aldehyde is oxidized to a carboxylate anion. Silver metal precipitates from the solution and coats the flask, producing a smooth silver mirror. The test is often called tollens’ silver mirror test.
Ketones cannot be oxidized acids and do not react with the tollens’ reagent.
The general reaction is,
(b)
Interpretation:
The reaction of propanone with Tollens’ reagent has to be written.
Concept Introduction:
Refer to part (a).
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Chapter 13 Solutions
General, Organic, and Biochemistry
- #1. Retro-Electrochemical Reaction: A ring has been made, but the light is causing the molecule to un- cyclize. Undo the ring into all possible molecules. (2pts, no partial credit) hvarrow_forwardDon't used Ai solutionarrow_forwardI have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."arrow_forward
- 2. 200 LOD For an unknown compound with a molecular ion of 101 m/z: a. Use the molecular ion to propose at least two molecular formulas. (show your work) b. What is the DU for each of your possible formulas? (show your work) C. Solve the structure and assign each of the following spectra. 8 6 4 2 (ppm) 150 100 50 ō (ppm) 4000 3000 2000 1500 1000 500 HAVENUMBERI-11arrow_forwardComplete the spectroscopy with structurearrow_forwardComplete the spectroscopy with structurearrow_forward
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