The product formed by the oxidation of cyclohexanol with potassium dichromate should be determined. Concept Introduction: The oxidation of primary alcohols with potassium dichromate, K 2 Cr 2 O 7 , results in the formation of aldehyde of corresponding alcohol which on further oxidation gives carboxylic acid . Whereas the oxidation of secondary alcohols with potassium dichromate, K 2 Cr 2 O 7 , results in the formation of ketone of corresponding alcohol.

Question

One liter of N2(g) at 2.1 bar and two liters of Ar(g) at 3.4 bar are mixed in a 4.0 liter flask to form an ideal gas mixture. Calculate the value of the final pressure of the mixture if the initial and final temperature of the gases are the same. Repeat this calculation if the initial temperature of the N2(g) and Ar(g) are 304 K and 402 K, respectively, and the final temperature of the mixture is 377 K.

Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 13.2, Problem 13.5QC

Interpretation Introduction

Interpretation:

The product formed by the oxidation of cyclohexanol with potassium dichromate should be determined.

Concept Introduction:

The oxidation of primary alcohols with potassium dichromate, K₂ Cr₂ O₇, results in the formation of aldehyde of corresponding alcohol which on further oxidation gives carboxylic acid. Whereas the oxidation of secondary alcohols with potassium dichromate, K₂ Cr₂ O₇, results in the formation of ketone of corresponding alcohol.

Interpretation Introduction

Interpretation:

The product formed by the oxidation of 2-pentanol with potassium dichromate should be determined.

Concept Introduction: The oxidation of primary alcohols with potassium dichromate, K₂ Cr₂ O₇, results in the formation of aldehyde of corresponding alcohol which on further oxidation gives carboxylic acid. Whereas the oxidation of secondary alcohols with potassium dichromate, K₂ Cr₂ O₇, results in the formation of ketone of corresponding alcohol.

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One liter of N2(g) at 2.1 bar and two liters of Ar(g) at 3.4 bar are mixed in a 4.0 liter flask to form an ideal gas mixture. Calculate the value of the final pressure of the mixture if the initial and final temperature of the gases are the same. Repeat this calculation if the initial temperature of the N2(g) and Ar(g) are 304 K and 402 K, respectively, and the final temperature of the mixture is 377 K.

10 5 4. These four 'H NMR spectra were recorded from different isomers with molecular formula CsH,CIO. They all contain a carbonyl group. Determine the structure of the different isomers. 0 10 5 0 10 5 10 9 8 7 6 5 4 3. 1 0 9 10 10 66 9 0 10 9 10 5 1 8 7 6 5 3 2 -a 8 7 6 5 1 10 9 8 7 6 5 22 2 1 0 3 2 16 1 0 3 2 1 2 6 0

Use the expression below to ⚫ calculate its value and report it to the proper number of significant digits (you may need to round your answer). ⚫ calculate the % error (or % relative error or % inherent error) ⚫ calculate the absolute error. (20.54±0.02 × 0.254±0.003) / (3.21±0.05) = Value: % Error: Absolute error: ± | % (only 1 significant digit) (only 1 significant digit)

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 13.2, Problem 13.5QC

Interpretation Introduction

Interpretation:

The product formed by the oxidation of cyclohexanol with potassium dichromate should be determined.

Concept Introduction:

The oxidation of primary alcohols with potassium dichromate, K₂ Cr₂ O₇, results in the formation of aldehyde of corresponding alcohol which on further oxidation gives carboxylic acid. Whereas the oxidation of secondary alcohols with potassium dichromate, K₂ Cr₂ O₇, results in the formation of ketone of corresponding alcohol.

Interpretation Introduction

Interpretation:

The product formed by the oxidation of 2-pentanol with potassium dichromate should be determined.

Concept Introduction: The oxidation of primary alcohols with potassium dichromate, K₂ Cr₂ O₇, results in the formation of aldehyde of corresponding alcohol which on further oxidation gives carboxylic acid. Whereas the oxidation of secondary alcohols with potassium dichromate, K₂ Cr₂ O₇, results in the formation of ketone of corresponding alcohol.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 13.2, Problem 13.5QC

Interpretation Introduction

Interpretation:

The product formed by the oxidation of cyclohexanol with potassium dichromate should be determined.

Concept Introduction:

The oxidation of primary alcohols with potassium dichromate, K₂ Cr₂ O₇, results in the formation of aldehyde of corresponding alcohol which on further oxidation gives carboxylic acid. Whereas the oxidation of secondary alcohols with potassium dichromate, K₂ Cr₂ O₇, results in the formation of ketone of corresponding alcohol.

Interpretation Introduction

Interpretation:

The product formed by the oxidation of 2-pentanol with potassium dichromate should be determined.

Concept Introduction: The oxidation of primary alcohols with potassium dichromate, K₂ Cr₂ O₇, results in the formation of aldehyde of corresponding alcohol which on further oxidation gives carboxylic acid. Whereas the oxidation of secondary alcohols with potassium dichromate, K₂ Cr₂ O₇, results in the formation of ketone of corresponding alcohol.

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 13.2, Problem 13.5QC

Interpretation Introduction