The one that occurs at larger wavenumber has to be identified. Concept introduction: IR frequency (cm -1 ): It is the number of wave crests that pass by a given point in one second frequency has units of hertz (Hz). Wavelength: I t identified the distance from any point on one wave to the corresponding point on the next wave, or its wavelength is generally measured in nanometers (1 nm=10 -9 m). Stretch vibrations: it is a vibration occurring along the line of the bond a stretching vibration changes the bond length. Bending vibrations: It is a vibration that does not occur along the line of the bond, bending vibration changes the bond angle.

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Answer 1

Question

Chapter 13.13, Problem 21P

(a)

Interpretation Introduction

Interpretation:

The one that occurs at larger wavenumber has to be identified.

Concept introduction:

IR frequency (cm^-1): It is the number of wave crests that pass by a given point in one second frequency has units of hertz (Hz).

Wavelength: It identified the distance from any point on one wave to the corresponding point on the next wave, or its wavelength is generally measured in nanometers (1 nm=10^-9 m).

Stretch vibrations: it is a vibration occurring along the line of the bond a stretching vibration changes the bond length.

Bending vibrations: It is a vibration that does not occur along the line of the bond, bending vibration changes the bond angle.

(b)

Interpretation Introduction

Interpretation:

The one which occurs at largest wavenumber has to be identified.

Concept introduction:

IR frequency (cm^-1): It is the number of wave crests that pass by a given point in one second frequency has units of hertz (Hz).

Wavelength: It identified the distance from any point on one wave to the corresponding point on the next wave, or its wavelength is generally measured in nanometers (1 nm=10^-9 m).

Stretch vibrations: it is a vibration occurring along the line of the bond a stretching vibration changes the bond length.

Bending vibrations: It is a vibration that does not occur along the line of the bond, bending vibration changes the bond angle.

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2CIO2 + 20H-1 CIO31 + CIO2 + H2O Experiment [CIO2], M [OH-1], M 1 0.0500 0.100 23 2 0.100 0.100 3 0.100 0.0500 Initial Rate, M/s 0.0575 0.230 0.115 ... Given this date, calculate the overall order of this reaction.

2 3 .(be)_[Ɔ+(be)_OI ← (b²)_IƆO+ (be)_I Experiment [1-] M 0.005 [OCI-] 0.005 Initial Rate M/min 0.000275 0.0025 0.005 0.000138 0.0025 0.0025 0.000069 4 0.0025 0.0025 0.000140 Calculate the rate constant of this reaction using the table data.

1 2 3 4 I(aq) +OCl(aq) → IO¯¯(aq) + Cl¯(aq) Experiment [I-] M 0.005 [OCI-] 0.005 Initial Rate M/min 0.000275 0.0025 0.005 0.000138 0.0025 0.0025 Calculate the overall order of this reaction using the table data. 0.0025 0.000069 0.0025 0.000140

Answer 2

Question

Chapter 13.13, Problem 21P

(a)

Interpretation Introduction

Interpretation:

The one that occurs at larger wavenumber has to be identified.

Concept introduction:

IR frequency (cm^-1): It is the number of wave crests that pass by a given point in one second frequency has units of hertz (Hz).

Wavelength: It identified the distance from any point on one wave to the corresponding point on the next wave, or its wavelength is generally measured in nanometers (1 nm=10^-9 m).

Stretch vibrations: it is a vibration occurring along the line of the bond a stretching vibration changes the bond length.

Bending vibrations: It is a vibration that does not occur along the line of the bond, bending vibration changes the bond angle.

(b)

Interpretation Introduction

Interpretation:

The one which occurs at largest wavenumber has to be identified.

Concept introduction:

IR frequency (cm^-1): It is the number of wave crests that pass by a given point in one second frequency has units of hertz (Hz).

Wavelength: It identified the distance from any point on one wave to the corresponding point on the next wave, or its wavelength is generally measured in nanometers (1 nm=10^-9 m).

Stretch vibrations: it is a vibration occurring along the line of the bond a stretching vibration changes the bond length.

Bending vibrations: It is a vibration that does not occur along the line of the bond, bending vibration changes the bond angle.

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Answer 3

Question

Chapter 13.13, Problem 21P

(a)

Interpretation Introduction

Interpretation:

The one that occurs at larger wavenumber has to be identified.

Concept introduction:

IR frequency (cm^-1): It is the number of wave crests that pass by a given point in one second frequency has units of hertz (Hz).

Wavelength: It identified the distance from any point on one wave to the corresponding point on the next wave, or its wavelength is generally measured in nanometers (1 nm=10^-9 m).

Stretch vibrations: it is a vibration occurring along the line of the bond a stretching vibration changes the bond length.

Bending vibrations: It is a vibration that does not occur along the line of the bond, bending vibration changes the bond angle.

(b)

Interpretation Introduction

Interpretation:

The one which occurs at largest wavenumber has to be identified.

Concept introduction:

IR frequency (cm^-1): It is the number of wave crests that pass by a given point in one second frequency has units of hertz (Hz).

Wavelength: It identified the distance from any point on one wave to the corresponding point on the next wave, or its wavelength is generally measured in nanometers (1 nm=10^-9 m).

Stretch vibrations: it is a vibration occurring along the line of the bond a stretching vibration changes the bond length.

Bending vibrations: It is a vibration that does not occur along the line of the bond, bending vibration changes the bond angle.

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Answer 4

Question

Chapter 13.13, Problem 21P

(a)

Interpretation Introduction

Interpretation:

The one that occurs at larger wavenumber has to be identified.

Concept introduction:

IR frequency (cm^-1): It is the number of wave crests that pass by a given point in one second frequency has units of hertz (Hz).

Wavelength: It identified the distance from any point on one wave to the corresponding point on the next wave, or its wavelength is generally measured in nanometers (1 nm=10^-9 m).

Stretch vibrations: it is a vibration occurring along the line of the bond a stretching vibration changes the bond length.

Bending vibrations: It is a vibration that does not occur along the line of the bond, bending vibration changes the bond angle.

(b)

Interpretation Introduction

Interpretation:

The one which occurs at largest wavenumber has to be identified.

Concept introduction:

IR frequency (cm^-1): It is the number of wave crests that pass by a given point in one second frequency has units of hertz (Hz).

Wavelength: It identified the distance from any point on one wave to the corresponding point on the next wave, or its wavelength is generally measured in nanometers (1 nm=10^-9 m).

Stretch vibrations: it is a vibration occurring along the line of the bond a stretching vibration changes the bond length.

Bending vibrations: It is a vibration that does not occur along the line of the bond, bending vibration changes the bond angle.

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Answer 5

Chapter 13.13, Problem 21P

(a)

Interpretation Introduction

Interpretation:

The one that occurs at larger wavenumber has to be identified.

Concept introduction:

IR frequency (cm^-1): It is the number of wave crests that pass by a given point in one second frequency has units of hertz (Hz).

Wavelength: It identified the distance from any point on one wave to the corresponding point on the next wave, or its wavelength is generally measured in nanometers (1 nm=10^-9 m).

Stretch vibrations: it is a vibration occurring along the line of the bond a stretching vibration changes the bond length.

Bending vibrations: It is a vibration that does not occur along the line of the bond, bending vibration changes the bond angle.

(b)

Interpretation Introduction

Interpretation:

The one which occurs at largest wavenumber has to be identified.

Concept introduction:

IR frequency (cm^-1): It is the number of wave crests that pass by a given point in one second frequency has units of hertz (Hz).

Wavelength: It identified the distance from any point on one wave to the corresponding point on the next wave, or its wavelength is generally measured in nanometers (1 nm=10^-9 m).

Stretch vibrations: it is a vibration occurring along the line of the bond a stretching vibration changes the bond length.

Bending vibrations: It is a vibration that does not occur along the line of the bond, bending vibration changes the bond angle.

Answer 6

Chapter 13.13, Problem 21P

(a)

Interpretation Introduction

Interpretation:

The one that occurs at larger wavenumber has to be identified.

Concept introduction:

IR frequency (cm^-1): It is the number of wave crests that pass by a given point in one second frequency has units of hertz (Hz).

Wavelength: It identified the distance from any point on one wave to the corresponding point on the next wave, or its wavelength is generally measured in nanometers (1 nm=10^-9 m).

Stretch vibrations: it is a vibration occurring along the line of the bond a stretching vibration changes the bond length.

Bending vibrations: It is a vibration that does not occur along the line of the bond, bending vibration changes the bond angle.

Answer 7

Chapter 13.13, Problem 21P

(a)

Interpretation Introduction

Interpretation:

The one that occurs at larger wavenumber has to be identified.

Concept introduction:

IR frequency (cm^-1): It is the number of wave crests that pass by a given point in one second frequency has units of hertz (Hz).

Wavelength: It identified the distance from any point on one wave to the corresponding point on the next wave, or its wavelength is generally measured in nanometers (1 nm=10^-9 m).

Stretch vibrations: it is a vibration occurring along the line of the bond a stretching vibration changes the bond length.

Bending vibrations: It is a vibration that does not occur along the line of the bond, bending vibration changes the bond angle.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The one which occurs at largest wavenumber has to be identified.

Concept introduction:

IR frequency (cm^-1): It is the number of wave crests that pass by a given point in one second frequency has units of hertz (Hz).

Wavelength: It identified the distance from any point on one wave to the corresponding point on the next wave, or its wavelength is generally measured in nanometers (1 nm=10^-9 m).

Stretch vibrations: it is a vibration occurring along the line of the bond a stretching vibration changes the bond length.

Bending vibrations: It is a vibration that does not occur along the line of the bond, bending vibration changes the bond angle.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The one which occurs at largest wavenumber has to be identified.

Concept introduction:

IR frequency (cm^-1): It is the number of wave crests that pass by a given point in one second frequency has units of hertz (Hz).

Wavelength: It identified the distance from any point on one wave to the corresponding point on the next wave, or its wavelength is generally measured in nanometers (1 nm=10^-9 m).

Stretch vibrations: it is a vibration occurring along the line of the bond a stretching vibration changes the bond length.

Bending vibrations: It is a vibration that does not occur along the line of the bond, bending vibration changes the bond angle.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 13.1 - Which of the following fragments produced in a...Ch. 13.2 - What distinguishes the mass spectrum of...Ch. 13.2 - What is the most likely m/z value for the base...Ch. 13.3 - Prob. 5P Ch. 13.3 - a. Suggest possible molecular formulas for a...Ch. 13.3 - If a compound has a molecular ion with an...Ch. 13.3 - Identify the hydrocarbon that has a molecular ion...Ch. 13.4 - Predict the relative intensities of the molecular...Ch. 13.5 - Which molecular formula has an exact molecular...Ch. 13.5 - Prob. 11P

Solution Summary: The author explains IR frequency, stretch vibration, and bend vibrations, which are occurring along the line of the bond.

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Chapter 13 Solutions