Bundle: Chemistry & Chemical Reactivity, Loose-Leaf Version, 9th + OWLv2, 4 terms (24 Months) Printed Access Card
9th Edition
ISBN: 9781305367425
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Chapter 13, Problem 93SCQ
When sails of Mg2+, Ca2+, and Be2+ are placed in water, the positive ion is hydrated (as is the negative ion). Which of these three cations is most strongly hydrated? Which one is least strongly hydrated?
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11. Complete the following esterification reaction with names of all the reactants and products under.
Hint: Remove the water and end up with ester
R-C-OH + ROH
R-C-OR + H₂O
A carboxylic acid
An alcohol
An ester
Water
BYJU'S
H-C-C
O-H
Нин
C-C-C-H
HAAA
H O-C-C-C-H
AAA
Ethanoic acid
Propanol
Water Propyl ethanoate
By com
CH3COOH + CH3CH2CH2CH₂CH₂OH →
Practice for alcohols aldehydes and ketones:
12. Draw the structures from the following names mixed of alcohol/aldehyde and ketone:
a. 4-methyl cyclohexanone
b. 3-methyl-2-pentenal
c. 2,3-dimethylcyclohexanone
d. 1,3propanediol or Propane 1,3 diol
13. Write systematic names for the following compounds identify
functional group:
a.
b. (CH3)2CH-C
OH
c) CH(CH₂)--
OH
-,-,
may you please show all steps! i am having a hard time understanding and applying in this format, thank you!
10. Complete the substitution reaction of 2 pentanol with these reagents.
Reagents & Reaction Conditions use practice sheet. Please write only
major products, minor product like water, other gases are not
required.
Hint: In substitution of alcohol, we generally substitute OH group
with Halogens like cl, Br, F using some reagent containing
halogens. Ensure to add halogens to the same carbon number
where you are removing OH from
Examples
Alcohols can be converted to Alkyl Halides with HX acids
HBr
H₂O
HCI
+ H₂O
HI
+
H₂O
CH,CH₂OH + SOCI₂
CH,CH₂OH + PCI₁₂
A
BBYJU'S
CH CHCI + SO₂+ HCI
CH₂CH CIP(OH), + HCI
CH,CH₂OH + PCI CHCHCI + POCI + HCI
CH,CH₂OH + PBr, CH,CH,Br + P(OH), + HBr
1. Reaction with HBr with 2 Pentanol
2.Reaction with HI with 2 pentanol
© Byjus.com
3.Reaction with HCI+ZnCl,, with 2 pentanol (Zncl2 is catalyst no role)
4.Reaction with SOCI,, with 2 Pentanol
5.Reaction with PBr; or PCl, with 2 pentanol
Chapter 13 Solutions
Bundle: Chemistry & Chemical Reactivity, Loose-Leaf Version, 9th + OWLv2, 4 terms (24 Months) Printed Access Card
Ch. 13.1 - (a) If you dissolve 10.0 g (about one heaping...Ch. 13.1 - You dissolve 1.0 mol of urea (H2NCONH2) in 270 g...Ch. 13.1 - 2. The concentration of acetic acid, CH3CO2H, in a...Ch. 13.2 - Use the data in Table 13.1 to calculate the...Ch. 13.2 - Given the enthalpy of formation data below,...Ch. 13.3 - Prob. 1CYUCh. 13.3 - Prob. 1RCCh. 13.3 - If the headspace of a soda is 25 mL and the...Ch. 13.3 - Prob. 2QCh. 13.3 - Prob. 3Q
Ch. 13.3 - Prob. 4QCh. 13.4 - Assume you dissolve 10.0 g of sucrose (C12H22O11)...Ch. 13.4 - What quantity of ethylene glycol, HOCH2CH2OH, must...Ch. 13.4 - In the northern United States, summer cottages are...Ch. 13.4 - Bradykinin is a small peptide (9 amino acids; 1060...Ch. 13.4 - An aluminum-containing compound has the empirical...Ch. 13.4 - A 1.40-g sample of polyethylene, a common plastic,...Ch. 13.4 - Calculate the freezing point of 525 g of water...Ch. 13.4 - 1. Vapor pressure: Arrange the following aqueous...Ch. 13.4 - Prob. 2RCCh. 13.4 - Samples of each of the substances listed below are...Ch. 13.4 - Motor mass: Erythritol is a compound that occurs...Ch. 13.5 - Prob. 1RCCh. 13.5 - The blue line on the diagram illustrates the...Ch. 13.5 - How many theoretical plates are required to...Ch. 13.5 - Prob. 3QCh. 13.5 - The vapor pressure of pure heptane is 361.5 mm Hg...Ch. 13 - You dissolve 2.56 g of succinic acid, C2H4(CO2H)2,...Ch. 13 - You dissolve 45.0 g of camphor, C10H16O, in 425 mL...Ch. 13 - Prob. 3PSCh. 13 - Prob. 4PSCh. 13 - Prob. 5PSCh. 13 - Prob. 6PSCh. 13 - Prob. 7PSCh. 13 - Prob. 8PSCh. 13 - Hydrochloric acid is sold as a concentrated...Ch. 13 - Concentrated sulfuric acid has a density of 1.84...Ch. 13 - The average lithium ion concentration in seawater...Ch. 13 - Silver ion has an average concentration of 28 ppb...Ch. 13 - Which pairs of liquids will be miscible? (a) H2O...Ch. 13 - Acetone, CH3COCH3, is quite soluble in water....Ch. 13 - Prob. 15PSCh. 13 - Use the following data to calculate the enthalpy...Ch. 13 - You make a saturated solution of NaCl at 25 C. No...Ch. 13 - Some lithium chloride, LiCl, is dissolved in 100...Ch. 13 - Prob. 19PSCh. 13 - The Henrys law constant for O2 in water at 25 is...Ch. 13 - An unopened soda can has an aqueous CO2...Ch. 13 - Hydrogen gas has a Henrys law constant of 7.8 104...Ch. 13 - A sealed flask contains water and oxygen gas at 25...Ch. 13 - Butane, C4H10, has been suggested as the...Ch. 13 - A 35.0-g sample of ethylene glycol, HOCH2CH2OH, is...Ch. 13 - Urea, (NH2)2CO, which is widely used in...Ch. 13 - Pure ethylene glycol, HOCH2CH2OH, is added 2.00 kg...Ch. 13 - Pure iodine (105 g) is dissolved in 325 g of CCl4...Ch. 13 - Prob. 29PSCh. 13 - What is the boiling point of a solution composed...Ch. 13 - Prob. 31PSCh. 13 - Prob. 32PSCh. 13 - Prob. 33PSCh. 13 - Some ethylene glycol, HOCH2CH2OH, is added to your...Ch. 13 - You dissolve 15.0 g of sucrose, C12H22O11, in a...Ch. 13 - A typical bottle of wine consists of an 11%...Ch. 13 - Prob. 37PSCh. 13 - Estimate the osmotic pressure of human blood at 37...Ch. 13 - An aqueous solution containing 1.00 g of bovine...Ch. 13 - Calculate the osmotic pressure of a 0.0120 M...Ch. 13 - You add 0.255 g of an orange, crystalline compound...Ch. 13 - Butylated hydroxyanisole (BHA) is used in...Ch. 13 - Benzyl acetate is one of the active components of...Ch. 13 - Anthracene, a hydrocarbon obtained from coal, has...Ch. 13 - An aqueous solution contains 0.180 g of an...Ch. 13 - Aluminon, an organic compound, is used as a...Ch. 13 - Prob. 47PSCh. 13 - To make homemade ice cream, you cool the milk and...Ch. 13 - List the following aqueous solutions in order of...Ch. 13 - Arrange the following aqueous solutions in order...Ch. 13 - When solutions of BaCl2 and Na2SO4 are mixed, the...Ch. 13 - The dispersed phase of a certain colloidal...Ch. 13 - Phenylcarbinol is used in nasal sprays as a...Ch. 13 - (a) Which aqueous solution is expected to have the...Ch. 13 - Arrange the following aqueous solutions in order...Ch. 13 - Prob. 56GQCh. 13 - Dimethylglyoxime [DMG, (CH3CNOH)2] is used as a...Ch. 13 - A 10.7 m solution of NaOH has a density of 1.33...Ch. 13 - Concentrated aqueous ammonia has a molarity of...Ch. 13 - Prob. 60GQCh. 13 - If you want a solution that is 0.100 m in ions,...Ch. 13 - Consider the following aqueous solutions: (i) 0.20...Ch. 13 - (a) Which solution is expected to have the higher...Ch. 13 - The solubility of NaCl in water at 100 C is 39.1...Ch. 13 - Instead of using NaCl to melt the ice on your...Ch. 13 - The smell of ripe raspberries is due to...Ch. 13 - Hexachlorophene has been used in germicidal soap....Ch. 13 - The solubility of ammonium formate, NH4CHO2, in...Ch. 13 - How much N2 can dissolve in water at 25 C if the...Ch. 13 - Cigars are best stored in a humidor at 18 C and...Ch. 13 - An aqueous solution containing 10.0 g of starch...Ch. 13 - Prob. 72GQCh. 13 - Calculate the enthalpies of solution for Li2SO4...Ch. 13 - Water at 25 C has a density of 0.997 g/cm3....Ch. 13 - If a volatile solute is added to a volatile...Ch. 13 - A solution is made by adding 50.0 mL of ethanol...Ch. 13 - A 2.0% (by mass) aqueous solution of novocainium...Ch. 13 - A solution is 4.00% (by mass) maltose and 96.00%...Ch. 13 - The following table lists the concentrations of...Ch. 13 - A tree is 10.0 m tall. (a) What must be the total...Ch. 13 - Prob. 81GQCh. 13 - A compound is known to be a potassium halide, KX....Ch. 13 - Prob. 85GQCh. 13 - If one is very careful, it is possible to float a...Ch. 13 - A solution of benzoic acid in benzene has a...Ch. 13 - You dissolve 5.0 mg of iodine, I2, in 25 mL of...Ch. 13 - Prob. 89ILCh. 13 - In a police forensics lab, you examine a package...Ch. 13 - An organic compound contains carbon (71.17%),...Ch. 13 - Prob. 92ILCh. 13 - When sails of Mg2+, Ca2+, and Be2+ are placed in...Ch. 13 - Explain why a cucumber shrivels up when it is...Ch. 13 - Prob. 95SCQCh. 13 - A 100.-gram sample of sodium chloride (NaCl) is...Ch. 13 - Prob. 97SCQCh. 13 - Prob. 98SCQCh. 13 - Starch contains CC, CH, CO, and OH bonds....Ch. 13 - Prob. 100SCQCh. 13 - You have two aqueous solutions separated by a...Ch. 13 - Prob. 102SCQCh. 13 - Sodium chloride (NaCl) is commonly used to melt...Ch. 13 - Prob. 105SCQCh. 13 - Prob. 106SCQCh. 13 - Prob. 107SCQ
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY