Indicate how each of the following will affect the equilibrium concentration of
a. adding more
b. increasing the temperature
c. increasing the volume of the container
d. adding more
e. removing some
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EP BASIC CHEMISTRY-STANDALONE ACCESS
- the cyclization of a farnesyl pyrophosphate to give epi-cedrol, A. Provide a stepwise mechanism for the formation of nerolidyl pyrophosphate from farnesylpyrophosphate B. Provide a stepwise mechanism for the formation of carbocation 1 from nerolidyl pyrophosphate. Number the backbone carbons of nerolidyl pyrophosphate from 1 to 11 as shown, and include the carbon numbering in your structure of 1 C. Following from B, give an arrow-pushing mechanism to convert 1 to 2 and 2 to 3. Use the backbone carbon numbering from 1 to indicate where carbon atoms ended up in 2 and 3 D. In addition to forming epi-cedrol, carbocation 3 gives three minor byproducts: a diastereomeric alcohol and two alkenes. Draw mechanisms that could give rise to these three productsarrow_forwardLequel des composés ci-dessous pourrait être utilisé comme réactif de départ dans la réaction suivante?arrow_forward(please correct answer and don't use hand rating) Lequel des composés ci-dessous pourrait être utilisé comme réactif de départ dans la réaction suivante?arrow_forward
- Please correct answer and don't use hand ratingarrow_forwardCalculate the volume of 0.2445 M NaOH solution required to give 0.825g of NaOH. Use dimensional analysis.arrow_forwardIron carbonyl can be made by the direct reaction of iron metal and carbon monoxide. Fe(s) + 5 CO(g) → Fe(CO)5(s) What is the theoretical yield of Fe(CO)5 if 3.52-g of iron (Fe) istreated with CO gas having a pressure of 732-torr in a 5.50-L flask at 23 deC?arrow_forward
- Consider the two isoprenoid precursors IPP and DMAPP.A. Which one is more susceptible to SN1 reaction? Explain your answer B. Which is a more likely nucleophile? Explain your answerarrow_forwardThe compound 5,9,12,16-tetramethyleicosane was synthesized as part of a study of the male sex pheromone of a Brazilian bug that feeds on the leaves and fruit of tomato plants. (J. Chem. Ecol. 2012, 38, 814-824) The synthesis of this alkane was reported using compounds A-C.arrow_forwardDraw the mechanism to show how each product was obtained and then categorize as major vs minor. EtOH Heat Br OEt 02.05.0 OEtarrow_forward
- 26. What would be the major organic product for the following reaction? -O Na + ? Br -OH a) b) racemic 27. What would be the major substitution product for the following reaction? a) HO ■CI CH3 ??? c) d) 28. What would be the major organic product for the following reaction? a) Br NaF DMSO ? b). c) d) e) 29. What would be the major organic product for the following reaction? Br CHS Na+ ? DMSO a) S b) S c) ༠༤། d) racemic racemic racemic 30. What would be the major elimination product for the following reaction? CH3 CH3OH CI ??? CH3 CH3 a) b) ос c) " OCH 3 e) OCH 3 racemicarrow_forwardDraw the enol form of Thymine, and show how this tautomer could form a Watson-Crick base pair with Guanine. If this happened, what would be the consequence?arrow_forwardProblem 11-56 Order each of the following sets of compounds concerning SN1 reactivity. Most reactive=1; Least reactive=3. CH3 H3C-C-Cl CH3 (a) CS Scanned with CamScanner H3C CH3 Cl NH 2 1 CH3CH2CHCH3arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning