BURDGE CHEMISTRY VALUE ED (LL)
4th Edition
ISBN: 9781259995958
Author: VALUE EDITION
Publisher: MCG CUSTOM
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Question
Chapter 13, Problem 7QP
Interpretation Introduction
Interpretation:
The statement, “Dissolving a solid always leads to an increase in disorder,” is to be explained.
Concept introduction:
The extensive property of a
Crystalline structures have long-range order.
Solution does not have long-range order.
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Students have asked these similar questions
What are the IUPAC Names of all the compounds in the picture?
1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following
compounds. Please show your work. (8) SF2, CH,OH, C₂H₂
b) Based on your answers given above, list the compounds in order of their Boiling Point
from low to high. (8)
19.78 Write the products of the following sequences of reactions. Refer to your reaction road-
maps to see how the combined reactions allow you to "navigate" between the different
functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18
roadmaps along with your new Chapter 19 roadmap for these.
(a)
1. BHS
2. H₂O₂
3. H₂CrO4
4. SOCI₂
(b)
1. Cl₂/hv
2. KOLBU
3. H₂O, catalytic H₂SO4
4. H₂CrO4
Reaction
Roadmap
An alkene 5. EtOH
6.0.5 Equiv. NaOEt/EtOH
7. Mild H₂O
An alkane
1.0
2. (CH3)₂S
3. H₂CrO
(d)
(c)
4. Excess EtOH, catalytic H₂SO
OH
4. Mild H₂O*
5.0.5 Equiv. NaOEt/EtOH
An alkene 6. Mild H₂O*
A carboxylic
acid
7. Mild H₂O*
1. SOC₁₂
2. EtOH
3.0.5 Equiv. NaOEt/E:OH
5.1.0 Equiv. NaOEt
6.
NH₂
(e)
1. 0.5 Equiv. NaOEt/EtOH
2. Mild H₂O*
Br
(f)
i
H
An aldehyde
1. Catalytic NaOE/EtOH
2. H₂O*, heat
3. (CH,CH₂)₂Culi
4. Mild H₂O*
5.1.0 Equiv. LDA
Br
An ester
4. NaOH, H₂O
5. Mild H₂O*
6. Heat
7.
MgBr
8. Mild H₂O*
7. Mild H₂O+
Chapter 13 Solutions
BURDGE CHEMISTRY VALUE ED (LL)
Ch. 13.1 - Prob. 1PPACh. 13.1 - Prob. 1PPBCh. 13.1 - Prob. 1PPCCh. 13.2 - Prob. 1CPCh. 13.2 - Prob. 2CPCh. 13.2 - Practice Problem ATTEMPT
Determine (a) the...Ch. 13.2 - Practice Problem BUILD
Determine the molality of...Ch. 13.2 - Prob. 1PPCCh. 13.3 - Practice Problem ATTEMPT
An aqueous solution that...Ch. 13.3 - Practice Problem BUILD
Determine the percent...
Ch. 13.3 - Practice Problem CONCEPTUALIZE
The diagrams...Ch. 13.3 - Prob. 1CPCh. 13.3 - What is the molality of a solution prepared by...Ch. 13.3 - Prob. 3CPCh. 13.3 - Prob. 4CPCh. 13.4 - Practice ProblemATTEMPT Calculate the...Ch. 13.4 - Prob. 1PPBCh. 13.4 - Practice Problem CONCEPTUALIZE
The first diagram...Ch. 13.4 - The solubility of N2 in water at 25°C and an N 2...Ch. 13.4 - Calculate the molar concentration of O 2 in water...Ch. 13.5 - Practice ProblemATTEMPT Calculate the vapor...Ch. 13.5 - Prob. 1PPBCh. 13.5 - Practice ProblemCONCEPTUALIZE The diagrams...Ch. 13.5 - 13.5.1 A solution contains 75.0 g of glucose...Ch. 13.5 - Determine the boiling point and the freezing point...Ch. 13.5 - 13.5.3 Calculate the osmotic pressure of a...Ch. 13.5 - 13.5.4 A 1.00-m solution of has a freezing point...Ch. 13.6 - Prob. 1PPACh. 13.6 - Prob. 1PPBCh. 13.6 - Practice Problem CONCEPTUALIZE
The diagrams...Ch. 13.6 - 13.6.1 A solution made by dissolving 14.2 g of...Ch. 13.6 - Prob. 2CPCh. 13.7 - Practice ProblemATTEMPT The freezing-point...Ch. 13.7 - Practice ProblemBUILD Using the experimental van't...Ch. 13.7 - Practice Problem CONCEPTUALIZE
The diagram...Ch. 13.8 - Practice ProblemATTEMPT Determine the osmotic...Ch. 13.8 - Practice Problem BUILD
Determine the...Ch. 13.8 - Practice Problem CONCEPTUALIZE
The first diagram...Ch. 13.9 - Practice Problem ATTEMPT
Calculate the molar mass...Ch. 13.9 - Practice Problem BUILD
What mass of naphthalene...Ch. 13.9 - Practice Problem CONCEPTUALIZE
The first diagram...Ch. 13.10 - Practice Problem ATTEMPT A solution made by...Ch. 13.10 - Practice Problem BUILD What mass of insulin must...Ch. 13.10 - Practice ProblemCONCEPTUALIZE The first diagram...Ch. 13.11 - Practice Problem ATTEMPT An aqueous solution that...Ch. 13.11 - Practice Problem BUILD
An aqueous solution that is...Ch. 13.11 - Practice Problem CONCEPTUALIZE The diagrams...Ch. 13 - Which of the following processes is accompanied by...Ch. 13 - 13.2
For each of the processes depicted here,...Ch. 13 - 13.3
For each of the processes depicted here,...Ch. 13 - Prob. 4KSPCh. 13 - Describe and give examples of an unsaturated...Ch. 13 - Prob. 2QPCh. 13 - Prob. 3QPCh. 13 - Prob. 4QPCh. 13 - Prob. 5QPCh. 13 - As you know, some solution processes are...Ch. 13 - Prob. 7QPCh. 13 - 13.8 Describe the factors that affect the...Ch. 13 - Prob. 9QPCh. 13 - Prob. 10QPCh. 13 - Prob. 11QPCh. 13 - Prob. 12QPCh. 13 - Prob. 13QPCh. 13 - Prob. 14QPCh. 13 - Prob. 15QPCh. 13 - Prob. 16QPCh. 13 - Prob. 17QPCh. 13 - Prob. 18QPCh. 13 - Prob. 19QPCh. 13 - Prob. 20QPCh. 13 - 13.21 The alcohol content of hard liquor is...Ch. 13 - Prob. 22QPCh. 13 - Prob. 23QPCh. 13 - 13.24 The density of an aqueous solution...Ch. 13 - Prob. 25QPCh. 13 - Prob. 26QPCh. 13 - Prob. 27QPCh. 13 - What is thermal pollution? Why is it harmful to...Ch. 13 - Prob. 29QPCh. 13 - A student is observing two beakers of water. One...Ch. 13 - Prob. 31QPCh. 13 - Prob. 32QPCh. 13 - The solubility of KNO 3 is 155 g per 100 g of...Ch. 13 - Prob. 34QPCh. 13 - 13.35 The solubility of in water at What is its...Ch. 13 - Prob. 36QPCh. 13 - Prob. 37QPCh. 13 - Prob. 38QPCh. 13 - Prob. 39QPCh. 13 - Prob. 40QPCh. 13 - Prob. 41QPCh. 13 - Prob. 42QPCh. 13 - Prob. 43QPCh. 13 - Prob. 44QPCh. 13 - Prob. 45QPCh. 13 - 13.46 Write the equations relating boiling-point...Ch. 13 - Prob. 47QPCh. 13 - Prob. 48QPCh. 13 - Prob. 49QPCh. 13 - Prob. 50QPCh. 13 - Prob. 51QPCh. 13 - Prob. 52QPCh. 13 - Prob. 53QPCh. 13 - What are ion pairs? What effect does ion-pair...Ch. 13 - Prob. 55QPCh. 13 - Prob. 56QPCh. 13 - 13.57 A solution is prepared by dissolving 396 g...Ch. 13 - Prob. 58QPCh. 13 - Prob. 59QPCh. 13 - Prob. 60QPCh. 13 - Prob. 61QPCh. 13 - Prob. 62QPCh. 13 - Prob. 63QPCh. 13 - 13.64 How many liters of the antifreeze ethylene...Ch. 13 - Prob. 65QPCh. 13 - Prob. 66QPCh. 13 - Prob. 67QPCh. 13 - Prob. 68QPCh. 13 - 13.69 Both and are used to melt ice on roads and...Ch. 13 - Prob. 70QPCh. 13 - Prob. 71QPCh. 13 - Prob. 72QPCh. 13 - Prob. 73QPCh. 13 - Calculate the difference in osmotic pressure (in...Ch. 13 - 13.75 Which of the following aqueous solutions has...Ch. 13 - Prob. 76QPCh. 13 - 13.77 Arrange the following solutions in order of...Ch. 13 - Prob. 78QPCh. 13 - Indicate which compound in each of the following...Ch. 13 - Prob. 80QPCh. 13 - Prob. 81QPCh. 13 - Prob. 82QPCh. 13 - Prob. 83QPCh. 13 - The elemental analysis of an organic solid...Ch. 13 - 13.85 A solution of 2.50 g of a compound having...Ch. 13 - 13.86 The molar mass of benzoic acid determined...Ch. 13 - 13.87 A solution containing 0.8330 g of a polymer...Ch. 13 - Prob. 88QPCh. 13 - A solution of 6.85 g of a carbohydrate in 100.0 g...Ch. 13 - Prob. 90QPCh. 13 - Prob. 91QPCh. 13 - Prob. 92QPCh. 13 - Prob. 93QPCh. 13 - Prob. 94QPCh. 13 - Prob. 95APCh. 13 - Prob. 96APCh. 13 - 13.97 Acetic acid is a polar molecule and can form...Ch. 13 - Prob. 98APCh. 13 - Prob. 99APCh. 13 - Prob. 100APCh. 13 - Prob. 101APCh. 13 - Prob. 102APCh. 13 - Prob. 103APCh. 13 - Prob. 104APCh. 13 - Prob. 105APCh. 13 - A solution of 1.00 g of anhydrous aluminum...Ch. 13 - Explain why reverse osmosis is (theoretically)...Ch. 13 - A 1.32-g sample of a mixture of cyclohexane ( C 6...Ch. 13 - Prob. 109APCh. 13 - Prob. 110APCh. 13 - Prob. 111APCh. 13 - Prob. 112APCh. 13 - Prob. 113APCh. 13 - Prob. 114APCh. 13 - Prob. 115APCh. 13 - Iodine ( I 2 ) is only sparingly soluble in water...Ch. 13 - Concentrated hydrochloric acid is usually...Ch. 13 - Explain each of the following statements: (a) The...Ch. 13 - A mixture of NaCl and sucrose ( C 12 H 22 O 12 )...Ch. 13 - Prob. 120APCh. 13 - At 27°C, the vapor pressure of pure water is 23.76...Ch. 13 - A nonvolatile organic compound Z was used to make...Ch. 13 - Prob. 123APCh. 13 - Prob. 124APCh. 13 - Prob. 125APCh. 13 - Prob. 126APCh. 13 - Prob. 127APCh. 13 - Prob. 128APCh. 13 - Prob. 129APCh. 13 - Prob. 130APCh. 13 - Prob. 131APCh. 13 - Consider the three mercury manometers shown in the...Ch. 13 - Prob. 133APCh. 13 - Prob. 134APCh. 13 - Prob. 135APCh. 13 - 13.136 In the apparatus shown, what will happen if...Ch. 13 - Prob. 137APCh. 13 - Prob. 138APCh. 13 - Lysozyme is an enzyme that cleaves bacterial cell...Ch. 13 - Prob. 140APCh. 13 - Prob. 141APCh. 13 - Prob. 142APCh. 13 - Prob. 143APCh. 13 - Prob. 144APCh. 13 - Prob. 145APCh. 13 - What masses of sodium chloride, magnesium...Ch. 13 - Prob. 147APCh. 13 - Prob. 148APCh. 13 - Prob. 149APCh. 13 - Hemoglobin, the oxygen-transport protein, binds...Ch. 13 - Prob. 151APCh. 13 - 13.152 The vapor pressure of ethanol and the...Ch. 13 - Prob. 153APCh. 13 - A mixture of two volatile liquids is said to be...Ch. 13 - A mixture of two volatile liquids is said to be...Ch. 13 - Prob. 3SEPPCh. 13 - Prob. 4SEPP
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY