The metal oxide that can be reduced to from metal on reaction with C atom from the given list needs to be determined using the coupled reactions method. Concept introduction: A non-spontaneous reaction can be changed to spontaneous reaction either by changing the reaction’s conditions like temperature or by combining the reaction with other reaction to get an overall spontaneous reaction. The spontaneity of the reaction can be determined with the help of sign of ΔrG ° of the reaction. If the sign is negative, reaction is considered as a spontaneous reaction. At standard conditions, the ΔrG ° can also calculate with the help of ΔrG ° of reactant and products. ΔrG° = ΔrG°(product) - ΔrG°(reactant)
The metal oxide that can be reduced to from metal on reaction with C atom from the given list needs to be determined using the coupled reactions method. Concept introduction: A non-spontaneous reaction can be changed to spontaneous reaction either by changing the reaction’s conditions like temperature or by combining the reaction with other reaction to get an overall spontaneous reaction. The spontaneity of the reaction can be determined with the help of sign of ΔrG ° of the reaction. If the sign is negative, reaction is considered as a spontaneous reaction. At standard conditions, the ΔrG ° can also calculate with the help of ΔrG ° of reactant and products. ΔrG° = ΔrG°(product) - ΔrG°(reactant)
Solution Summary: The author explains how NiO can be reduced to metal by spontaneous reaction with carbon at 1000 K.
The metal oxide that can be reduced to from metal on reaction with C atom from the given list needs to be determined using the coupled reactions method.
Concept introduction:
A non-spontaneous reaction can be changed to spontaneous reaction either by changing the reaction’s conditions like temperature or by combining the reaction with other reaction to get an overall spontaneous reaction. The spontaneity of the reaction can be determined with the help of sign of ΔrG° of the reaction. If the sign is negative, reaction is considered as a spontaneous reaction.
At standard conditions, the ΔrG° can also calculate with the help of ΔrG° of reactant and products.
1.
For an unknown compound with a molecular formula of C8H100:
a.
What is the DU? (show your work)
b.
Solve the structure and assign each of the following spectra.
8
6
2
ō (ppm)
4
2
0
200
150
100
50
ō (ppm)
LOD
D
4000
3000
2000
1500
1000
500
HAVENUMBERI -11
16. The proton NMR spectral information shown in this problem is for a compound with formula
CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec-
tral results, including DEPT-135 and DEPT-90 results, are tabulated:
7
J
Normal Carbon
DEPT-135
DEPT-90
19 ppm
Positive
No peak
122
Positive
Positive
cus
и
124
Positive
Positive
126
Positive
Positive
128
No peak
No peak
4°
129
Positive
Positive
130
Positive
Positive
(144
No peak
No peak
148
No peak
No peak
150
Positive
Positive
してし
3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing
mechanism below, but make sure to draw the product of each proposed step (3 points).
+ En
CN
CN
Chapter 13 Solutions
General Chemistry: Principles And Modern Applications Plus Mastering Chemistry With Pearson Etext -- Access Card Package (11th Edition)