EBK INTRODUCTORY CHEMISTRY: AN ACTIVE L
6th Edition
ISBN: 9780100547506
Author: CRACOLICE
Publisher: YUZU
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Textbook Question
Chapter 13, Problem 70E
Draw Lewis diagrams for these five acids of bromine:
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Use the References to access important values if needed for this question.
What is the IUPAC name of each of the the following?
0
CH3CHCNH₂
CH3
CH3CHCNHCH2CH3
CH3
You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Chapter 13 Solutions
EBK INTRODUCTORY CHEMISTRY: AN ACTIVE L
Ch. 13 - Draw the Lewis diagrams for each of the following...Ch. 13 - Prob. 2ECh. 13 - Prob. 3ECh. 13 - Prob. 4ECh. 13 - Draw the Lewis diagrams for each of the following...Ch. 13 - Prob. 6ECh. 13 - Draw the Lewis diagrams for each of the following...Ch. 13 - Prob. 8ECh. 13 - Prob. 9ECh. 13 - Prob. 10E
Ch. 13 - Prob. 11ECh. 13 - Prob. 12ECh. 13 - Prob. 13ECh. 13 - Prob. 14ECh. 13 - Prob. 15ECh. 13 - Prob. 16ECh. 13 - Prob. 17ECh. 13 - Prob. 18ECh. 13 - Prob. 19ECh. 13 - Prob. 20ECh. 13 - Prob. 21ECh. 13 - Prob. 22ECh. 13 - Prob. 23ECh. 13 - Prob. 24ECh. 13 - Prob. 25ECh. 13 - Prob. 26ECh. 13 - Prob. 27ECh. 13 - Prob. 28ECh. 13 - Prob. 29ECh. 13 - Prob. 30ECh. 13 - Prob. 31ECh. 13 - Prob. 32ECh. 13 - Prob. 33ECh. 13 - Prob. 34ECh. 13 - Prob. 35ECh. 13 - Prob. 36ECh. 13 - Prob. 37ECh. 13 - Prob. 38ECh. 13 - Prob. 39ECh. 13 - Prob. 40ECh. 13 - Prob. 41ECh. 13 - Prob. 42ECh. 13 - Prob. 43ECh. 13 - Prob. 44ECh. 13 - Is the carbon tetrachloride molecule, CCl4, which...Ch. 13 - Prob. 46ECh. 13 - Describe the shapes and compare the polarities of...Ch. 13 - Prob. 48ECh. 13 - Prob. 49ECh. 13 - Prob. 50ECh. 13 - Prob. 51ECh. 13 - Prob. 52ECh. 13 - Prob. 53ECh. 13 - Prob. 54ECh. 13 - Prob. 55ECh. 13 - Prob. 56ECh. 13 - Prob. 57ECh. 13 - Prob. 58ECh. 13 - Prob. 59ECh. 13 - Prob. 60ECh. 13 - Prob. 61ECh. 13 - Prob. 62ECh. 13 - Prob. 63ECh. 13 - Prob. 64ECh. 13 - Prob. 65ECh. 13 - Prob. 66ECh. 13 - Prob. 67ECh. 13 - Classify each of the following statements as true...Ch. 13 - Prob. 69ECh. 13 - Draw Lewis diagrams for these five acids of...Ch. 13 - Prob. 71ECh. 13 - Prob. 72ECh. 13 - Describe the shapes of C2H6 and C2H4. In doing so,...Ch. 13 - Prob. 74ECh. 13 - Prob. 75ECh. 13 - C4H10O is the formula of diethyl ether. The same...Ch. 13 - Prob. 77ECh. 13 - Prob. 78ECh. 13 - Draw Lewis diagrams for water and dihydrogen...Ch. 13 - Prob. 2PECh. 13 - Prob. 3PECh. 13 - Prob. 4PECh. 13 - Prob. 5PECh. 13 - What is the Lewis diagram of butane, C4H10?Ch. 13 - Prob. 7PECh. 13 - Prob. 8PECh. 13 - Prob. 9PECh. 13 - Prob. 10PECh. 13 - In the gas phase, tin (II) chloride is a...Ch. 13 - Prob. 12PECh. 13 - Determine the molecular geometry around each...Ch. 13 - Describe the molecular geometry around each carbon...Ch. 13 - Is the difluoromethane molecule polar or nonpolar?...Ch. 13 - Prob. 1LDRECh. 13 - Prob. 2LDRECh. 13 - Prob. 3LDRECh. 13 - Prob. 4LDRECh. 13 - Prob. 5LDRECh. 13 - Prob. 6LDRECh. 13 - Prob. 7LDRECh. 13 - Prob. 8LDRECh. 13 - Prob. 9LDRECh. 13 - Prob. 10LDRE
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- Part I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward• Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forward
- In the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forwardNonearrow_forwardNonearrow_forward
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