(a) Interpretation: The difference between central atom and terminal atom is to be stated. Concept introduction: Molecular geometry is the 3 − D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

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Answer 1

Question

Chapter 13, Problem 67E

Interpretation Introduction

(a)

Interpretation:

The difference between central atom and terminal atom is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(b)

Interpretation:

The difference between molecular geometry and electron pair geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(c)

Interpretation:

The difference between angular geometry and trigonal planar geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(d)

Interpretation:

The difference between trigonal planar geometry and trigonal pyramidal geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(e)

Interpretation:

The difference between Trigonal planar geometry and tetrahedral geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(f)

Interpretation:

The difference between Polar molecule and nonpolar molecule is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

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A solution contains 10-3 M (NH4)2CO3 plus 10-3 M CaCO3. (NH4+: pKa 9.26) a) Follow the four steps and list the species and equations that would have to be solved to determine the equilibrium solution composition. (15 pts) b) Prepare a log C-pH diagram for the solution. Use a full sheet of graph paper, and show the ranges 1≤ pH < 13 and -10≤ log C≤ -1. (10 pts) c) Use the graphical approach for the solution pH. What is the concentration of all species? (15 pts)

Keggin structure.

Answer 2

Question

Chapter 13, Problem 67E

Interpretation Introduction

(a)

Interpretation:

The difference between central atom and terminal atom is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(b)

Interpretation:

The difference between molecular geometry and electron pair geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(c)

Interpretation:

The difference between angular geometry and trigonal planar geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(d)

Interpretation:

The difference between trigonal planar geometry and trigonal pyramidal geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(e)

Interpretation:

The difference between Trigonal planar geometry and tetrahedral geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(f)

Interpretation:

The difference between Polar molecule and nonpolar molecule is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

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Answer 3

Question

Chapter 13, Problem 67E

Interpretation Introduction

(a)

Interpretation:

The difference between central atom and terminal atom is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(b)

Interpretation:

The difference between molecular geometry and electron pair geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(c)

Interpretation:

The difference between angular geometry and trigonal planar geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(d)

Interpretation:

The difference between trigonal planar geometry and trigonal pyramidal geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(e)

Interpretation:

The difference between Trigonal planar geometry and tetrahedral geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(f)

Interpretation:

The difference between Polar molecule and nonpolar molecule is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

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Answer 4

Question

Chapter 13, Problem 67E

Interpretation Introduction

(a)

Interpretation:

The difference between central atom and terminal atom is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(b)

Interpretation:

The difference between molecular geometry and electron pair geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(c)

Interpretation:

The difference between angular geometry and trigonal planar geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(d)

Interpretation:

The difference between trigonal planar geometry and trigonal pyramidal geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(e)

Interpretation:

The difference between Trigonal planar geometry and tetrahedral geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(f)

Interpretation:

The difference between Polar molecule and nonpolar molecule is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

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Answer 5

Chapter 13, Problem 67E

Interpretation Introduction

(a)

Interpretation:

The difference between central atom and terminal atom is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(b)

Interpretation:

The difference between molecular geometry and electron pair geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(c)

Interpretation:

The difference between angular geometry and trigonal planar geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(d)

Interpretation:

The difference between trigonal planar geometry and trigonal pyramidal geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(e)

Interpretation:

The difference between Trigonal planar geometry and tetrahedral geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(f)

Interpretation:

The difference between Polar molecule and nonpolar molecule is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 6

Chapter 13, Problem 67E

Interpretation Introduction

(a)

Interpretation:

The difference between central atom and terminal atom is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 7

Chapter 13, Problem 67E

Interpretation Introduction

(a)

Interpretation:

The difference between central atom and terminal atom is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The difference between molecular geometry and electron pair geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The difference between molecular geometry and electron pair geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The difference between angular geometry and trigonal planar geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The difference between angular geometry and trigonal planar geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The difference between trigonal planar geometry and trigonal pyramidal geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The difference between trigonal planar geometry and trigonal pyramidal geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The difference between Trigonal planar geometry and tetrahedral geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The difference between Trigonal planar geometry and tetrahedral geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 16

Interpretation Introduction

(f)

Interpretation:

The difference between Polar molecule and nonpolar molecule is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 17

Interpretation Introduction

(f)

Interpretation:

The difference between Polar molecule and nonpolar molecule is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 18

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Ch. 13 - Draw the Lewis diagrams for each of the following...Ch. 13 - Prob. 2E Ch. 13 - Prob. 3E Ch. 13 - Prob. 4E Ch. 13 - Draw the Lewis diagrams for each of the following...Ch. 13 - Prob. 6E Ch. 13 - Draw the Lewis diagrams for each of the following...Ch. 13 - Prob. 8E Ch. 13 - Prob. 9E Ch. 13 - Prob. 10E

Chapter 13 Solutions