CHEMISTRY IN FOCUS (LL)-TEXT
7th Edition
ISBN: 9781337399845
Author: Tro
Publisher: CENGAGE L
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Chapter 13, Problem 43E
Suppose that the stomach contains
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SH
0
2.
Please consider the two all 'cis' isomers of trimethylcyclohexane drawn below. Draw the
two chair conformers of each stereoisomer below (1 and 2) and calculate their torsional interaction
energies in order to identify the lower energy conformer for each stereoisomer. Based on your
calculations, state which of the two stereoisomers 1 and 2 is less stable and which is more stable.
[1,3-diaxial CH3 CH3 = 3.7kcal/mol; 1,3-diaxial CH3 H = 0.88kcal/mol; cis-1,2 (axial:equatorial) CH3
CH3 = 0.88kcal/mol; trans-1,2-diequatorial CH3 CH3 = 0.88kcal/mol)
all-cis-1,2,3-
1
all-cis-1,2,4-
2
None
Chapter 13 Solutions
CHEMISTRY IN FOCUS (LL)-TEXT
Ch. 13 - Which property is not generally associated with...Ch. 13 - Prob. 2SCCh. 13 - The ideal pH of a swimming pool is 7.2. You...Ch. 13 - Prob. 13.1YTCh. 13 - Identify the Brnsted-Lowry acid and base in the...Ch. 13 - Prob. 1ECh. 13 - What are the properties of acids?Ch. 13 - Prob. 3ECh. 13 - Prob. 4ECh. 13 - List five common laboratory acids and their uses.
Ch. 13 - Why are bases not commonly found in foods?Ch. 13 - List four common laboratory bases and their uses.Ch. 13 - What are the Arrhenius definitions of acids and...Ch. 13 - What are the Brnsted-Lowry definitions of acids...Ch. 13 - What is the difference between a strong acid and a...Ch. 13 - Prob. 11ECh. 13 - What pH range is considered acidic? Basic?...Ch. 13 - What acid is responsible for the sour taste of...Ch. 13 - What is pickling? What acid is responsible for the...Ch. 13 - Prob. 15ECh. 13 - Prob. 16ECh. 13 - List several common acids and where they might be...Ch. 13 - Prob. 18ECh. 13 - Prob. 19ECh. 13 - What causes acid indigestion? List some common...Ch. 13 - Prob. 21ECh. 13 - Explain how a leavening agent works.Ch. 13 - Prob. 23ECh. 13 - Prob. 24ECh. 13 - Prob. 25ECh. 13 - Prob. 26ECh. 13 - Prob. 27ECh. 13 - Prob. 28ECh. 13 - Write a chemical equation to show the...Ch. 13 - Write a chemical equation to show the...Ch. 13 - Identify the Brnsted-Lowry acid and base in each...Ch. 13 - Identify the Brnsted-Lowry acid and base in each...Ch. 13 - Write a chemical equation using Lewis structures...Ch. 13 - Write a chemical equation using Lewis structures...Ch. 13 - A chemist makes two solutions. One is a 0.01-MHCl...Ch. 13 - A chemist makes a 0.001-MNaOH solution and a...Ch. 13 - Give the pH that corresponds to each solution and...Ch. 13 - Give the pH that corresponds to each solution and...Ch. 13 - What is the [H3O+] in a solution with a pH of 4?Ch. 13 - What is the [H3O+] in a solution with a pH of 11?Ch. 13 - Write chemical reactions to show how each antacid...Ch. 13 - Write chemical reactions to show how each antacid...Ch. 13 - Suppose that the stomach contains...Ch. 13 - Suppose that 250.0 mL of a basic solution is 0.100...Ch. 13 - Prob. 45ECh. 13 - Write a chemical reaction to show how NO2 forms...Ch. 13 - Prob. 47ECh. 13 - Prob. 50ECh. 13 - Determine from the following molecular view of a...Ch. 13 - Determine from the following molecular view of a...
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- What is the mechanism by which the 1,4 product is created? Please draw it by hand with arrows and stuff.arrow_forwardWhat is the relationship between A and B? H3C A Br Cl H3C B Br relationship (check all that apply) O same molecule O enantiomer O diastereomer structural isomer O stereoisomer isomer O need more information to decide O same molecule ☐ enantiomer Br Br Br CH3 Br CI CH3 O diastereomer ☐ structural isomer ☐ stereoisomer isomer O need more information to decide O same molecule O enantiomer Odiastereomer structural isomer O stereoisomer ☐ isomer O need more information to decidearrow_forwardb. Please complete the zig-zag conformation of the compound (3R,4S)-3,4-dichloro-2,5-dimethylhexane by writing the respective atoms in the boxes. 4arrow_forward
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- 206 Pb 82 Express your answers as integers. Enter your answers separated by a comma. ▸ View Available Hint(s) VAΣ ΜΕ ΑΣΦ Np, N₁ = 82,126 Submit Previous Answers ? protons, neutronsarrow_forwardPlease draw the inverted chair forms of the products for the two equilibrium reactions shown below. Circle the equilibrium reaction that would have a AG = 0, i.e., the relative energy of the reactant (to the left of the equilibrium arrows) equals the relative energy of the product? [No requirement to show or do calculations.] CH3 CH3 HH CH3 1 -CH3arrow_forward5. Please consider the Newman projection of tartaric acid drawn below as an eclipsed conformer (1). Please draw the most stable conformer and two intermediate energy conformers noting that staggered conformers are lower in energy than eclipsed forms even if the staggered conformers have gauche relationships between groups. [Draw the substituents H and OH on the front carbons and H, OH and CO₂H on the back carbons based on staggered forms. -CO₂H is larger than -OH.] OH COH ICOOH COOH COOH 1 2 COOH COOH 3 4 Staggered Staggered Staggered (most stable) Indicate the number of each conformer above (1, 2, 3 and 4) that corresponds to the relative energies below. Ref=0 Rotation 6. (60 points) a. Are compounds 1 and 2 below enantiomers, diastereomers or identical? OH OH HO HO LOH HO HO OH 2 OH OH b. Please complete the zig-zag conformation of the compound (3R,4S)-3,4-dichloro-2,5-dimethylhexane by writing the respective atoms in the boxes. 3.arrow_forward
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