Nitrogen and oxygen react at high temperatures. (a) Write the expression for the equilibrium constant (K c ) for the reversible reaction N 2 ( g ) + O 2 ( g ) ⇌ 2NO ( g ) nH = − 181 kJ (b) What will happen to the concentrations of N 2 ,O 2 , and NO at equilibrium if more O 2 is added? (c) What will happen to the concentrations of N 2 , O 2 , and NO at equilibrium if N 2 is removed? (d) What will happen to the concentrations of N 2, O 2, and NO at equilibrium if NO is added? (e) What will happen to the concentrations of N 2 ,O 2 , and NO at equilibrium if the volume of the reaction vessel is decreased? (f) What will happen to the concentrations of N 2 ,O 2 , and NO at equilibrium if the temperature of the system is increased?
Nitrogen and oxygen react at high temperatures. (a) Write the expression for the equilibrium constant (K c ) for the reversible reaction N 2 ( g ) + O 2 ( g ) ⇌ 2NO ( g ) nH = − 181 kJ (b) What will happen to the concentrations of N 2 ,O 2 , and NO at equilibrium if more O 2 is added? (c) What will happen to the concentrations of N 2 , O 2 , and NO at equilibrium if N 2 is removed? (d) What will happen to the concentrations of N 2, O 2, and NO at equilibrium if NO is added? (e) What will happen to the concentrations of N 2 ,O 2 , and NO at equilibrium if the volume of the reaction vessel is decreased? (f) What will happen to the concentrations of N 2 ,O 2 , and NO at equilibrium if the temperature of the system is increased?
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Consider the "C NMR spectrum below.
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The spectrum belongs to which one of the following constitutional isomers of the compound C,H12? Select the single best answer.
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The structure of compound 1,3,5-trimethylbenzene (mesitylene) is given below.
How many signals would you expect to find in the 'H NMR spectrum of 1,3,5-trimethylbenzene (mesitylene)?
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How many signals do you expect in the 'H NMR spectrum for this molecule?
CI CI
Cl
Write the answer in the table below.
Also, in each of the drawing areas below is a copy of the molecule, with H atoms shown. In each copy, one of the H atoms is highlighted red. Highlight in red all
other H atoms that would contribute to the same signal as the H already highlighted red.
Note for advanced students: Remember, a multiplet is considered one signal in the 'H NMR spectrum.
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Number of signals in the 'H NMR spectrum.
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For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to the same
signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional H atoms to highlight in
top molecule
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute to the
same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at…
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