Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357119303
Author: Bettelheim, Frederick A., Brown, William H., Campbell, Mary K., FARRELL, Shawn O., Torres, Omar
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
thumb_up100%
Chapter 13, Problem 3P
14-10 Which of the following are secondary alcohols?
(b) (CHqKCOH
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
Indicate whether the product of the reaction between Naphthalene and CrO3 in acetic acid at 25ºC is 1,4 naphthoquinone or phthalic anhydride.
Indicate the products of the reaction between CH3COCH2COOC2H5 and Na+-OC2H5.
Primary, Secondary, and
Tertiary Alcohols
O-H
O-H
O-H
R₁-C-H
R₁-C-H
R₁-C-R₁
H
R₂
R₂
Primary
Alcohol
Secondary
Alcohol
ChemistryLearner.com
R stands for Carbon group like ethyl methyl propyl
Tertiary
Alcohol
If 1 carbon group with two H attached to alcoholic carbon, then primary
If 2 carbon group and 1 H are attached to alcoholic carbon, then secondary
IF 3 carbon group and no H attach to alcoholic carbon then tertiary.
The bottom line
Starting
"Weak" oxidant
material
PCC, DMP, Swern, etc
Primary alcohol
Aldehyde
OH
Secondary alcohol
Ketone
OH
"Strong" oxidant
KMnO4, H₂CrO4
(or equivalent)
OH
Carboxylic acid
요
Ketone
No reaction
No reaction
Tertiary alcohol
1. Is ethanol a primary, secondary, or tertiary alcohol? Write out the
structures of
ethanol and any oxidation products of ethanol. If there is more than one
oxidation product, give the structure of each of the products.
2. Is 2-propanol a primary, secondary, or tertiary alcohol? Write out the
structures of
2-propanol and any…
Chapter 13 Solutions
Introduction to General, Organic and Biochemistry
Ch. 13.1 - Prob. 13.1QCCh. 13.1 - Prob. 13.2QCCh. 13.2 - Problem 14-3 Draw structural formulas for the...Ch. 13.2 - Prob. 13.4QCCh. 13.2 - Prob. 13.5QCCh. 13.3 - Problem 14-6 Write the common name for each ether.Ch. 13.4 - Prob. 13.7QCCh. 13.4 - Prob. 13.8QCCh. 13 - 14-8 Answer true or false. The functional group of...Ch. 13 - 14-9 What is the difference in structure between a...
Ch. 13 - 14-10 Which of the following are secondary...Ch. 13 - 14-11 Which of the alcohols in Problem 14-10 are...Ch. 13 - 14-12 Write the 1UPAC name of each compound. (e)...Ch. 13 - Prob. 6PCh. 13 - Prob. 7PCh. 13 - 14-15 Both alcohols and phenols contain an —OH...Ch. 13 - Prob. 9PCh. 13 - 14-17 Explain in terms of noncovalent interactions...Ch. 13 - Prob. 11PCh. 13 - Prob. 12PCh. 13 - 14-20 Show hydrogen bonding between methanol and...Ch. 13 - 14-21 Show hydrogen bonding between the oxygen of...Ch. 13 - 14-22 Arrange these compounds in order of...Ch. 13 - 14-23 Arrange these compounds in order of...Ch. 13 - 14-24 2-Propanol (isopropyl alcohol) is commonly...Ch. 13 - Prob. 18PCh. 13 - Prob. 19PCh. 13 - Prob. 20PCh. 13 - 14-28 Give the structural formula of an alkene or...Ch. 13 - Prob. 22PCh. 13 - 14-30 Show how to distinguish between cyclohexanol...Ch. 13 - 14-31 Compare the acidity of alcohols and phenols,...Ch. 13 - 14-32 Both 2,6-diisopropylcyclohexanol and the...Ch. 13 - 14-33 Write equations for the reaction of...Ch. 13 - 14-34 Write equations for the reaction of...Ch. 13 - 14-35 Write equations for the reaction of each of...Ch. 13 - 14-36 Show how to convert cyclohexanol to these...Ch. 13 - Prob. 30PCh. 13 - Prob. 31PCh. 13 - 14-39 Name two important alcohols derived from...Ch. 13 - 14-40 Name two important alcohols derived from...Ch. 13 - Prob. 34PCh. 13 - 14-42 Write the common name for each ether. ch3...Ch. 13 - Prob. 36PCh. 13 - 14-44 Answer true or false. (a) The functional...Ch. 13 - Prob. 38PCh. 13 - Write the common name for each thiol in Problem 38...Ch. 13 - 14-47 Following are structural formulas for...Ch. 13 - 14-48 Explain why methanethiol, CH3SH, has a lower...Ch. 13 - 14-49 Answer true or false. Today, the major...Ch. 13 - (Chemical Connections 13A ) As stated in the...Ch. 13 - Prob. 44PCh. 13 - Prob. 45PCh. 13 - Prob. 46PCh. 13 - Prob. 47PCh. 13 - (Chemical Connections 13D ) Show that enflurane...Ch. 13 - Prob. 49PCh. 13 - 14-60 Write a balanced equation for the complete...Ch. 13 - 14-61 Knowing what you do about electronegativity,...Ch. 13 - 14-62 Draw structural formulas and write IUPAC...Ch. 13 - Prob. 53PCh. 13 - 14-64 Explain why the boiling point of ethylene...Ch. 13 - Prob. 55PCh. 13 - 14-66 1,4-Butanediol, hexane, and 1-pentanol have...Ch. 13 - 14-67 Of the three compounds given in Problem...Ch. 13 - Prob. 58PCh. 13 - 14-69 Show how to prepare each compound from...Ch. 13 - 14-70 Show how to prepare each compound from...Ch. 13 - 14-71 The mechanism of the acid-catalyzed...Ch. 13 - Prob. 62PCh. 13 - 14-73 Lipoic acid is a growth factor for many...Ch. 13 - 14-74 Following is a structural formula for the...Ch. 13 - Prob. 65PCh. 13 - Prob. 66PCh. 13 - Prob. 67PCh. 13 - 14-78 Consider alkenes A, B, and C. each of which...Ch. 13 - Prob. 69P
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Complete the following equations hand written pleasearrow_forwardComplete the following equations please hand written pleasearrow_forwardUsing the Nernst equation to calculate nonstandard cell voltage A galvanic cell at a temperature of 25.0 °C is powered by the following redox reaction: 3+ 3Cu²+ (aq) +2Al(s) → 3 Cu(s)+2A1³* (aq) 2+ Suppose the cell is prepared with 5.29 M Cu in one half-cell and 2.49 M A1³+ in the other. Calculate the cell voltage under these conditions. Round your answer to 3 significant digits. x10 μ ☑ 00. 18 Ar Иarrow_forward
- Please help me solve this homework problemarrow_forwardPlease help me answer this homework questionarrow_forwardCalculating standard reaction free energy from standard reduction... Using standard reduction potentials from the ALEKS Data tab, calculate the standard reaction free energy AG° for the following redox reaction. Be sure your answer has the correct number of significant digits. 3+ H2(g)+2OH¯ (aq) + 2Fe³+ (aq) → 2H₂O (1)+2Fe²+ (aq) 0 kJ x10 Х ? olo 18 Ararrow_forward
- Calculating the pH of a weak base titrated with a strong acid An analytical chemist is titrating 184.2 mL of a 0.7800M solution of dimethylamine ((CH3) NH with a 0.3000M solution of HClO4. The pK₁ of dimethylamine is 3.27. Calculate the pH of the base solution after the chemist has added 424.1 mL of the HClO solution to it. 2 4 Note for advanced students: you may assume the final volume equals the initial volume of the solution plus the volume of HClO 4 solution added. Round your answer to 2 decimal places. pH = ☐ ☑ ? 000 18 Ar 1 Barrow_forwardUsing the Nernst equation to calculate nonstandard cell voltage A galvanic cell at a temperature of 25.0 °C is powered by the following redox reaction: MnO2 (s)+4H* (aq)+2Cr²+ (aq) → Mn²+ (aq)+2H₂O (1)+2Cr³+ (aq) + 2+ 2+ 3+ Suppose the cell is prepared with 7.44 M H* and 0.485 M Cr²+ in one half-cell and 7.92 M Mn² and 3.73 M Cr³+ in the other. Calculate the cell voltage under these conditions. Round your answer to 3 significant digits. ☐ x10 μ Х 5 ? 000 日。arrow_forwardCalculating standard reaction free energy from standard reduction... Using standard reduction potentials from the ALEKS Data tab, calculate the standard reaction free energy AG° for the following redox reaction. Be sure your answer has the correct number of significant digits. NO (g) +H₂O (1) + Cu²+ (aq) → HNO₂ (aq) +H* (aq)+Cu* (aq) kJ - ☐ x10 x10 olo 18 Ararrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
Organic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,
General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Cengage Learning
Organic And Biological Chemistry
Chemistry
ISBN:9781305081079
Author:STOKER, H. Stephen (howard Stephen)
Publisher:Cengage Learning,
General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
ENVIRONMENTAL POLLUTION; Author: 7activestudio;https://www.youtube.com/watch?v=oxtMFmDTv3Q;License: Standard YouTube License, CC-BY