Lehninger Principles of Biochemistry
Lehninger Principles of Biochemistry
7th Edition
ISBN: 9781464126116
Author: David L. Nelson, Michael M. Cox
Publisher: W. H. Freeman
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Chapter 13, Problem 30P
Summary Introduction

Introduction: The “standard free-energy change” for an “oxidation-reduction reaction” is directly proportional to the “difference in standard reduction potentials” of “two half-cells”. The formula is ΔG°=ηFΔE° and ΔG°=RTlnΔKeq .

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CH3 17. Which one of the compounds below is the HNO3 H2 1. NaNO2, HCI Br₂ 1. LiAlH4 major organic product H2SO4 Ni 2. CuCN, KCN FeBr3 2. H₂O, H+ obtained from the following series of reactions? CH3 toluene CH3 CH3 Br Br Br CH3 CH3 && Br Br NH₂ A NH₂ NH₂ B C NH₂ ΝΗΣ D E
13. Which one of the compounds below is the major organic product obtained from the following series of reactions? A + H2C=CH-CO Me heat (CH3)2NH 1. LiAlH4 2. H₂O ? 1,3-butadiene OH 'N' B C 14. Which one of the compounds below is the major organic product obtained from the following series of reactions? 'N' D 'N' E 1. XS CH3I 'N' 2. Ag₂O 3. H₂O, A A B с D E N
A NH2 NH2 B C H₂N. NH₂ D 5. The five compounds above all have molecular weights close to 75 g/mol. Which one has the highest boiling point? 6. The five compounds above all have molecular weights close to 75 g/mol. Which one has the lowest boiling point? E NH₂
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