Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
8th Edition
ISBN: 9780134421377
Author: Charles H Corwin
Publisher: PEARSON
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Chapter 13, Problem 1ST
Interpretation Introduction
Interpretation:
The option that corresponds to the conditions in which carbon-dioxide is more soluble is to be stated.
Concept introduction:
Solutions of gases are generally affected by both temperature and pressure. When the temperature of a solution increases, the solubility of gas decreases. On the other hand, when the pressure of a solution increases, the solubility of gas decreases.
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
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-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
4. For the following complexes, draw the structures and give a d-electron count of the
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b) Hexabromoplatinate(2-)
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Fe3+ (aq) + e
= Fe²+ (aq)
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Chapter 13 Solutions
Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
Ch. 13 - Prob. 1CECh. 13 - Prob. 2CECh. 13 - Prob. 3CECh. 13 - Prob. 4CECh. 13 - Prob. 5CECh. 13 - Prob. 6CECh. 13 - Prob. 7CECh. 13 - Prob. 8CECh. 13 - Prob. 9CECh. 13 - Prob. 10CE
Ch. 13 - Prob. 11CECh. 13 - Prob. 12CECh. 13 - Prob. 1KTCh. 13 - Prob. 2KTCh. 13 - Prob. 3KTCh. 13 - Prob. 4KTCh. 13 - Prob. 5KTCh. 13 - Prob. 6KTCh. 13 - Prob. 7KTCh. 13 - Prob. 8KTCh. 13 - Prob. 9KTCh. 13 - Prob. 10KTCh. 13 - Prob. 11KTCh. 13 - Prob. 12KTCh. 13 - Prob. 13KTCh. 13 - Prob. 14KTCh. 13 - Prob. 15KTCh. 13 - Prob. 16KTCh. 13 - Prob. 17KTCh. 13 - Prob. 18KTCh. 13 - Prob. 19KTCh. 13 - Prob. 20KTCh. 13 - Prob. 1ECh. 13 - Prob. 2ECh. 13 - Prob. 3ECh. 13 - Prob. 4ECh. 13 - Prob. 5ECh. 13 - Prob. 6ECh. 13 - Prob. 7ECh. 13 - Prob. 8ECh. 13 - Prob. 9ECh. 13 - Prob. 10ECh. 13 - Prob. 11ECh. 13 - Prob. 12ECh. 13 - Prob. 13ECh. 13 - Prob. 14ECh. 13 - Prob. 15ECh. 13 - Prob. 16ECh. 13 - Prob. 17ECh. 13 - Prob. 18ECh. 13 - Prob. 19ECh. 13 - Prob. 20ECh. 13 - Prob. 21ECh. 13 - Prob. 22ECh. 13 - Prob. 23ECh. 13 - Prob. 24ECh. 13 - Prob. 25ECh. 13 - Prob. 26ECh. 13 - Prob. 27ECh. 13 - Prob. 28ECh. 13 - Prob. 29ECh. 13 - Prob. 30ECh. 13 - Prob. 31ECh. 13 - Prob. 32ECh. 13 - Prob. 33ECh. 13 - Prob. 34ECh. 13 - Prob. 35ECh. 13 - Prob. 36ECh. 13 - Prob. 37ECh. 13 - Prob. 38ECh. 13 - Prob. 39ECh. 13 - Prob. 40ECh. 13 - Prob. 41ECh. 13 - Prob. 42ECh. 13 - Prob. 43ECh. 13 - Prob. 44ECh. 13 - Prob. 45ECh. 13 - Prob. 46ECh. 13 - Prob. 47ECh. 13 - Prob. 48ECh. 13 - Prob. 49ECh. 13 - Prob. 50ECh. 13 - Prob. 51ECh. 13 - Prob. 52ECh. 13 - Prob. 53ECh. 13 - Prob. 54ECh. 13 - Prob. 55ECh. 13 - Prob. 56ECh. 13 - Prob. 57ECh. 13 - Prob. 58ECh. 13 - Prob. 59ECh. 13 - Prob. 60ECh. 13 - Prob. 61ECh. 13 - Prob. 62ECh. 13 - Prob. 63ECh. 13 - Prob. 64ECh. 13 - Prob. 65ECh. 13 - Prob. 66ECh. 13 - Prob. 67ECh. 13 - Prob. 68ECh. 13 - Prob. 70ECh. 13 - Prob. 71ECh. 13 - Prob. 72ECh. 13 - Prob. 73ECh. 13 - Prob. 74ECh. 13 - Prob. 75ECh. 13 - Prob. 76ECh. 13 - Prob. 77ECh. 13 - Prob. 78ECh. 13 - Prob. 79ECh. 13 - Prob. 80ECh. 13 - Prob. 81ECh. 13 - Prob. 82ECh. 13 - Prob. 83ECh. 13 - Prob. 84ECh. 13 - Prob. 1STCh. 13 - Prob. 2STCh. 13 - Prob. 3STCh. 13 - Prob. 4STCh. 13 - Prob. 5STCh. 13 - Prob. 6STCh. 13 - Prob. 7STCh. 13 - Prob. 8STCh. 13 - Prob. 9STCh. 13 - Prob. 10STCh. 13 - Prob. 11STCh. 13 - Prob. 12STCh. 13 - Prob. 13STCh. 13 - Prob. 14STCh. 13 - Prob. 15STCh. 13 - Prob. 16ST
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