Study Guide for Chemistry: The Central Science
14th Edition
ISBN: 9780134554075
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus, James C. Hill
Publisher: PEARSON
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Chapter 13, Problem 1E
Rank the contents of the following containers in order of increasing entropy: [Section 13.1]
![Chapter 13, Problem 1E, Rank the contents of the following containers in order of increasing entropy: [Section 13.1]](https://content.bartleby.com/tbms-images/9780134414232/Chapter-13/images/html_14232-13-1e_image001.jpg)
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14. Consider two ionic solids, both composed of singly-charged ions, that have
different lattice energies. Which solid will be more soluble in water, the one with the
larger lattice energy or the one with the smaller lattice energy? Assume that solute-
solvent interactions are the same for both solids.
(A) The solid with the larger lattice energy, if entropy increases as a result of
mixing, and the solid with the smaller lattice energy, if entropy decreases as a
result of mixing.
(B) The solid with the smaller lattice energy, if entropy increases as a result of
mixing, and the solid with the larger lattice energy, if entropy decreases as a
result of mixing.
(C) The solid with the smaller lattice energy.
(D) The solid with the larger lattice energy.
(E) They will have the same or very similar solubilities.
The freezing point of an aqueous solution
of barium nitrate is -2.65°C. Determine the
apparent molal concentration of barium nitrate.
a) An amount of 7.5 g polymer A is dissolved in 150 mL water. At 25.0 °C, the osmotic
pressure of the solution is 0.272 atm. Determine the molar mass of polymer A.
Chapter 13 Solutions
Study Guide for Chemistry: The Central Science
Ch. 13.3 - Prob. 13.1.1PECh. 13.3 - Prob. 13.1.2PECh. 13.3 - Prob. 13.2.1PECh. 13.3 - Prob. 13.2.2PECh. 13.4 - Prob. 13.3.1PECh. 13.4 - Prob. 13.3.2PECh. 13.4 - Prob. 13.4.1PECh. 13.4 - Prob. 13.4.2PECh. 13.4 - Prob. 13.5.1PECh. 13.4 - Prob. 13.5.2PE
Ch. 13.4 - Prob. 13.6.1PECh. 13.4 - Prob. 13.6.2PECh. 13.5 - Prob. 13.7.1PECh. 13.5 - Prob. 13.7.2PECh. 13.5 - Which aqueous solution will have the lowest...Ch. 13.5 - Prob. 13.8.2PECh. 13.5 - Prob. 13.9.1PECh. 13.5 - Prob. 13.9.2PECh. 13.5 - Prob. 13.10.1PECh. 13.5 - Practice Exercise 2
Camphor (C10 H16 O) melts at...Ch. 13.5 - Prob. 13.11.1PECh. 13.5 - Prob. 13.11.2PECh. 13 - Prob. 1DECh. 13 - Rank the contents of the following containers in...Ch. 13 - This figure shows the interaction of a cation with...Ch. 13 - Consider two ionic solids, both composed of singly...Ch. 13 - Which two statements about gas mixtures are true?...Ch. 13 - Prob. 5ECh. 13 - 13.6 If you compare the solubilities of the noble...Ch. 13 - Prob. 7ECh. 13 - Prob. 8ECh. 13 - Prob. 9ECh. 13 - Prob. 10ECh. 13 - Suppose you had a balloon made of some highly...Ch. 13 - Prob. 12ECh. 13 - Indicate whether each statement is true or false:...Ch. 13 - Indicate whether each statement is true or false:...Ch. 13 - Indicate the type of solute-solvent interaction...Ch. 13 - Indicate the principal type of solute-solvent...Ch. 13 - An ionic compound has a very negative H soln in...Ch. 13 - When ammonium chloride dissolves in water, the...Ch. 13 - Prob. 19ECh. 13 - Prob. 20ECh. 13 - Prob. 21ECh. 13 - KBr is relatively soluble in water, yet its...Ch. 13 - The solubility of Cr (NO3)3 . 9 H2O in water is...Ch. 13 - The solubility of MnSO4 . H2 O in water at 20 C is...Ch. 13 - Prob. 25ECh. 13 - Prob. 26ECh. 13 - Prob. 27ECh. 13 - Prob. 28ECh. 13 - Prob. 29ECh. 13 - Prob. 30ECh. 13 - Would you expect stearic acid, CH3 (CH2)16COOH, to...Ch. 13 - Prob. 32ECh. 13 - Prob. 33ECh. 13 - Prob. 34ECh. 13 - Indicate whether each statement is true or false:...Ch. 13 - 13.36 Indicate whether each statement is true or...Ch. 13 - The Henry’s law constant for helium gas in water...Ch. 13 - Prob. 38ECh. 13 - Prob. 39ECh. 13 - Prob. 40ECh. 13 - Prob. 41ECh. 13 - Prob. 42ECh. 13 - 13.43 Calculate the morality of the following...Ch. 13 - Prob. 44ECh. 13 - Calculate the molality of each of the following...Ch. 13 - (a) What is the molality of a solution formed by...Ch. 13 - Prob. 47ECh. 13 - Prob. 48ECh. 13 - Prob. 49ECh. 13 - The density of toluene (C7H8) is 0.867 g\mL, and...Ch. 13 - Calculate the number of moles of solute present in...Ch. 13 - Calculate the number of moles of solute present in...Ch. 13 - Prob. 53ECh. 13 - Describe how you would prepare each of the...Ch. 13 - Commercial aqueous nitric acid has a density of...Ch. 13 - Prob. 56ECh. 13 - Prob. 57ECh. 13 - Prob. 58ECh. 13 - Prob. 59ECh. 13 - Prob. 60ECh. 13 - Prob. 61ECh. 13 - Prob. 62ECh. 13 - Consider two solutions, one formed by adding 10 g...Ch. 13 - Prob. 64ECh. 13 - Prob. 65ECh. 13 - (a) Calculate the vapor pressure of water above a...Ch. 13 - Prob. 67ECh. 13 - At 20 oC, the vapor pressure of benzene (C6 H6) is...Ch. 13 - Prob. 69ECh. 13 - Prob. 70ECh. 13 - Prob. 71ECh. 13 - Prob. 72ECh. 13 - Using data from Table 13.3, calculate the freezing...Ch. 13 - Prob. 74ECh. 13 - Prob. 75ECh. 13 - Prob. 76ECh. 13 - Prob. 77ECh. 13 - Prob. 78ECh. 13 - Prob. 79ECh. 13 - Lauryl alcohol is obtained from coconut oil and is...Ch. 13 - Prob. 81ECh. 13 - Prob. 82ECh. 13 - The osmotic pressure of a 0.010 M aqueous solution...Ch. 13 - Based on the given data in Table 13.4, which...Ch. 13 - (a) Do colloids made only of gases exist? Why or...Ch. 13 - Prob. 86ECh. 13 - An “emulsifying agent” is a compound that helps...Ch. 13 - Aerosols are important components of the...Ch. 13 - Prob. 89ECh. 13 - Soaps consist of compounds such as sodium state,...Ch. 13 - Prob. 91AECh. 13 - Prob. 92AECh. 13 - Most fish need at least 4 ppm dissolved O2 in...Ch. 13 - The presence of the radioactive gas radon (Rn) in...Ch. 13 - Prob. 95AECh. 13 - Prob. 96AECh. 13 - The maximum allowable concentration of lead in...Ch. 13 - Prob. 98AECh. 13 - Prob. 99AECh. 13 - Prob. 100AECh. 13 - Prob. 101AECh. 13 - The normal boiling point of ethanol, is 78.4 0C....Ch. 13 - Prob. 103AECh. 13 - Carbon disulfide (CS2) boils at 46.30 o C and has...Ch. 13 - Prob. 105AECh. 13 - Prob. 106IECh. 13 - At ordinary body temperature (37 o C), the...Ch. 13 - Prob. 108IECh. 13 - Prob. 109IECh. 13 - Prob. 110IECh. 13 - Prob. 111IECh. 13 - Prob. 112IECh. 13 - At 35 o C the vapor pressure of acetone, (CH3)2CO,...Ch. 13 - Prob. 114IE
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- The osmotic pressure of a solution containing 7.0 g of insulin per liter is 23 torr at 25 C. What is the molar mass of insulin?arrow_forwardFor each of the following pairs of solutions, select the solution for which solute solubility is greatest. a. Oxygen gas in water with P = 1 atm and T = 10C Oxygen gas in water with P = 1 atm and T = 20C b. Nitrogen gas in water with P = 2 atm and T = 50C Nitrogen gas in water with P = 1 atm and T = 70C c. Table salt in water with P = 1 atm and T = 40C Table salt in water with P = 1 atm and T = 70C d. Table sugar in water with P = 3 atm and T = 30C Table sugar in water with P = 1 atm and T = 80Carrow_forwardIn a mountainous location, the boiling point of pure water is found to be 95C. How many grams of sodium chloride must be added to 1 kg of water to bring the boiling point back to 100C? Assume that i = 2.arrow_forward
- 6-111 As noted in Section 6-8C, the amount of external pressure that must be applied to a more concentrated solution to stop the passage of solvent molecules across a semipermeable membrane is known as the osmotic pressure The osmotic pressure obeys a law similar in form to the ideal gas law (discussed in Section 5-4), where Substituting for pressure and solving for osmotic pressures gives the following equation: RT MRT, where M is the concentration or molarity of the solution. (a) Determine the osmotic pressure at 25°C of a 0.0020 M sucrose (C12H22O11) solution. (b) Seawater contains 3.4 g of salts for every liter of solution. Assuming the solute consists entirely of NaCl (and complete dissociation of the NaCI salt), calculate the osmotic pressure of seawater at 25°C. (c) The average osmotic pressure of blood is 7.7 atm at 25°C. What concentration of glucose (C6H12O6) will be isotonic with blood? (d) Lysozyme is an enzyme that breaks bacterial cell walls. A solution containing 0.150 g of this enzyme in 210. mL of solution has an osmotic pressure of 0.953 torr at 25°C. What is the molar mass of lysozyme? (e) The osmotic pressure of an aqueous solution of a certain protein was measured in order to determine the protein's molar mass. The solution contained 3.50 mg of protein dissolved in sufficient water to form 5.00 mL of solution. The osmotic pressure of the solution at 25°C was found to be 1.54 torr. Calculate the molar mass of the protein.arrow_forwardFor each of the following pairs of solutions, select the solution for which solute solubility is greatest. a. Ammonia gas in water with P = 1 atm and T = 50C Ammonia gas in water with P = 1 atm and T = 90C b. Carbon dioxide gas in water with P = 2 atm and T = 50C Carbon dioxide gas in water with P = 1 atm and T = 50C c. Table salt in water with P = 1 atm and T = 60C Table salt in water with P = 1 atm and T = 50C d. Table sugar in water with P = 2 atm and T = 40C Table sugar in water with P = 1 atm and T = 70Carrow_forwardRefer to Figure 13.10 ( Sec. 13-4b) to answer these questions. (a) Does a saturated solution occur when 65.0 g LiCl is present in 100 g H2O at 40 C? Explain your answer. (b) Consider a solution that contains 95.0 g LiCl in 100 g H2O at 40 C. Is the solution unsaturated, saturated, or supersaturated? Explain your answer. (c) Consider a solution that contains 50. g Li2SO4 in 200. g H2O at 50 C. Is this solution unsaturated, saturated, or supersaturated? Explain your answer. Figure 13.10 Solubility of ionic compounds versus temperature.arrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY