(a) Interpretation: Oleic acid is water soluble or fat soluble is to be predicted. Concept introduction: The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

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Answer 1

Question

Chapter 13, Problem 19E

Interpretation Introduction

(a)

Interpretation:

Oleic acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

Interpretation Introduction

(b)

Interpretation:

Citric acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

Interpretation Introduction

(c)

Interpretation:

Lactic acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

Interpretation Introduction

(d)

Interpretation:

Stearic acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

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3. SYNTHESIS. Propose a sequence of synthetic steps (FGI) that convert the starting material (SM) into the Target molecule. For each FGI in your proposed synthesis, specify the reagents / conditions, and draw the product(s) of that FGI. DO NOT INCLUDE the FGI mxn in the answer you submit. If an FGI requires two reagent sets, specify the order in which the reagent sets are added, e.g., i) Hg(OAc)2 / H₂O; ii) NaBH4/MeOH. Indicate the stereochemistry (if any) of the products of each FGI. FGI 1. Me Starting Material Source of all carbons in the Target molecule (can use multiple copies) Me Me Target molecule + enantiomer

curved arrows are used to illustate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction mechanism steps

Answer 2

Question

Chapter 13, Problem 19E

Interpretation Introduction

(a)

Interpretation:

Oleic acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

Interpretation Introduction

(b)

Interpretation:

Citric acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

Interpretation Introduction

(c)

Interpretation:

Lactic acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

Interpretation Introduction

(d)

Interpretation:

Stearic acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

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Answer 3

Question

Chapter 13, Problem 19E

Interpretation Introduction

(a)

Interpretation:

Oleic acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

Interpretation Introduction

(b)

Interpretation:

Citric acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

Interpretation Introduction

(c)

Interpretation:

Lactic acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

Interpretation Introduction

(d)

Interpretation:

Stearic acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

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Answer 4

Question

Chapter 13, Problem 19E

Interpretation Introduction

(a)

Interpretation:

Oleic acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

Interpretation Introduction

(b)

Interpretation:

Citric acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

Interpretation Introduction

(c)

Interpretation:

Lactic acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

Interpretation Introduction

(d)

Interpretation:

Stearic acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

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Answer 5

Chapter 13, Problem 19E

Interpretation Introduction

(a)

Interpretation:

Oleic acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

Interpretation Introduction

(b)

Interpretation:

Citric acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

Interpretation Introduction

(c)

Interpretation:

Lactic acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

Interpretation Introduction

(d)

Interpretation:

Stearic acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

Answer 6

Chapter 13, Problem 19E

Interpretation Introduction

(a)

Interpretation:

Oleic acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

Answer 7

Chapter 13, Problem 19E

Interpretation Introduction

(a)

Interpretation:

Oleic acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Citric acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Citric acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Lactic acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Lactic acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

Answer 12

Interpretation Introduction

(d)

Interpretation:

Stearic acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

Answer 13

Interpretation Introduction

(d)

Interpretation:

Stearic acid is water soluble or fat soluble is to be predicted.

Concept introduction:

The liquids having polar molecules are called a polar solvent. If there is some net dipole moment in the molecule then it will be a polar molecule. The liquid having non-polar molecules are called non-polar solvent. If the net dipole moment is zero, the molecule will be non-polar.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 13 - Prob. 1CE Ch. 13 - Prob. 2CE Ch. 13 - Prob. 3CE Ch. 13 - Prob. 4CE Ch. 13 - Prob. 5CE Ch. 13 - Prob. 6CE Ch. 13 - Prob. 7CE Ch. 13 - Prob. 8CE Ch. 13 - Prob. 9CE Ch. 13 - Prob. 10CE

Solution Summary: The author explains that the solubility of two substances depends on the "like dissolves like" principle.

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Chapter 13 Solutions