Chemistry In Focus
7th Edition
ISBN: 9781337399692
Author: Tro, Nivaldo J.
Publisher: Cengage Learning,
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Chapter 13, Problem 19E
Interpretation Introduction
Interpretation:
Alkaloids are to be defined.
Concept Introduction:
It is a class of nitrogenous organic compounds of plant origin, which has a notable action on humans. This class includes many drugs (morphine, quinine) and poisons (atropine). Although majority of alkaloids are basic in nature, there are some exceptions that show neutral and even slightly acidic properties.
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 13 Solutions
Chemistry In Focus
Ch. 13 - Which property is not generally associated with...Ch. 13 - Prob. 2SCCh. 13 - The ideal pH of a swimming pool is 7.2. You...Ch. 13 - Prob. 13.1YTCh. 13 - Identify the Brnsted-Lowry acid and base in the...Ch. 13 - Prob. 1ECh. 13 - What are the properties of acids?Ch. 13 - Prob. 3ECh. 13 - Prob. 4ECh. 13 - List five common laboratory acids and their uses.
Ch. 13 - Why are bases not commonly found in foods?Ch. 13 - List four common laboratory bases and their uses.Ch. 13 - What are the Arrhenius definitions of acids and...Ch. 13 - What are the Brnsted-Lowry definitions of acids...Ch. 13 - What is the difference between a strong acid and a...Ch. 13 - Prob. 11ECh. 13 - What pH range is considered acidic? Basic?...Ch. 13 - What acid is responsible for the sour taste of...Ch. 13 - What is pickling? What acid is responsible for the...Ch. 13 - Prob. 15ECh. 13 - Prob. 16ECh. 13 - List several common acids and where they might be...Ch. 13 - Prob. 18ECh. 13 - Prob. 19ECh. 13 - What causes acid indigestion? List some common...Ch. 13 - Prob. 21ECh. 13 - Explain how a leavening agent works.Ch. 13 - Prob. 23ECh. 13 - Prob. 24ECh. 13 - Prob. 25ECh. 13 - Prob. 26ECh. 13 - Prob. 27ECh. 13 - Prob. 28ECh. 13 - Write a chemical equation to show the...Ch. 13 - Write a chemical equation to show the...Ch. 13 - Identify the Brnsted-Lowry acid and base in each...Ch. 13 - Identify the Brnsted-Lowry acid and base in each...Ch. 13 - Write a chemical equation using Lewis structures...Ch. 13 - Write a chemical equation using Lewis structures...Ch. 13 - A chemist makes two solutions. One is a 0.01-MHCl...Ch. 13 - A chemist makes a 0.001-MNaOH solution and a...Ch. 13 - Give the pH that corresponds to each solution and...Ch. 13 - Give the pH that corresponds to each solution and...Ch. 13 - What is the [H3O+] in a solution with a pH of 4?Ch. 13 - What is the [H3O+] in a solution with a pH of 11?Ch. 13 - Write chemical reactions to show how each antacid...Ch. 13 - Write chemical reactions to show how each antacid...Ch. 13 - Suppose that the stomach contains...Ch. 13 - Suppose that 250.0 mL of a basic solution is 0.100...Ch. 13 - Prob. 45ECh. 13 - Write a chemical reaction to show how NO2 forms...Ch. 13 - Prob. 47ECh. 13 - Prob. 50ECh. 13 - Determine from the following molecular view of a...Ch. 13 - Determine from the following molecular view of a...
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