Organic Chemistry, 12e Study Guide/Student Solutions Manual
Organic Chemistry, 12e Study Guide/Student Solutions Manual
12th Edition
ISBN: 9781119077329
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 13, Problem 18P
Interpretation Introduction

Interpretation:

The reagents required for the given reactants to produce 1,3-butadiene are to be determined.

Concept introduction:

Alkyl halides undergo E2 elimination when reacted with a strong base and a strong nucleophile, like tertiary alkoxides.

Alcohols heated in the presence of mineral acids undergo elimination reaction and form alkanes.

Primary alcohols undergo E2 elimination with concentrated sulfuric acid H2SO4 to form alkenes.

H2SO4 is a dehydrating agent.

Nickel boride Ni2B (P-2) is an effective reducing catalyst sensitive to steric factors and also, a mild reducing agent which converts alkynes to alkenes.

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What is the mechanism by which the 1,4 product is created?  Please draw it by hand with arrows and stuff.
What is the relationship between A and B? H3C A Br Cl H3C B Br relationship (check all that apply) O same molecule O enantiomer O diastereomer structural isomer O stereoisomer isomer O need more information to decide O same molecule ☐ enantiomer Br Br Br CH3 Br CI CH3 O diastereomer ☐ structural isomer ☐ stereoisomer isomer O need more information to decide O same molecule O enantiomer Odiastereomer structural isomer O stereoisomer ☐ isomer O need more information to decide

Chapter 13 Solutions

Organic Chemistry, 12e Study Guide/Student Solutions Manual

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