Concept explainers
Interpretation:
The values of
Concept introduction:
A

Answer to Problem 13F.6P
The values of
Explanation of Solution
The given moment of inertia for
The value of
The given vibrational wavenumbers for
The molar mass of
The given temperature is
The value of Planck’s constant is
The value of speed of light is
The expression that is used to calculate the standard molar Gibbs energy,
Where,
In the above expression,
The expression for translational partition function,
Where,
Substitute
Thus the value of translational partition function for
The expression for rotational partition function,
Where,
The value of
Substitute the values of
Substitute the values of
Thus, the value of rotational partition function of
The vibrational degrees of freedom of
Where,
Substitute the value of
Thus, the vibrational number for
The degeneracy of electronic ground sate is
Substitute the value of
Therefore, the value of
For
Thus the value of translational partition function for
The expression for rotational partition function,
Where,
The value of
Substitute the values of
Substitute the values of
Thus, the value of rotational partition function of
The vibrational degrees of freedom of
Where,
Substitute the value of
Thus, the vibrational number for
The degeneracy of electronic ground sate is
Substitute the value of
Therefore, the value of
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Chapter 13 Solutions
ATKINS' PHYSICAL CHEMISTRY
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