ATKINS' PHYSICAL CHEMISTRY
ATKINS' PHYSICAL CHEMISTRY
11th Edition
ISBN: 9780190053956
Author: ATKINS
Publisher: Oxford University Press
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Chapter 13, Problem 13A.6BE
Interpretation Introduction

Interpretation:

The temperature at which 15% of the certain molecule be in upper state has to be stated.

Concept introduction:

Statistical thermodynamics is used to describe all the possible configurations in a system at given physical quantities such as pressure, temperature, and a number of particles in the system.  The important quantity in the thermodynamic is partition function that is represented as shown below.

  q≡∑igie−β∈i

It is also called canonical ensemble partition function.

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What I Have Learned Directions: Given the following reaction and the stress applied in each reaction, answer the question below. A. H2(g) + Cl2(g) 2 HCl(g) Stress applied: Decreasing the pressure 1. What is the Keq expression? 2. What will be the effect in the number of moles of HCl(g)? 3. What will be the Equilibrium Shift or the reaction? B. Fe3O4(s) + 4 H2(g) + heat 53 Fe(s) + 4 H₂O(g) Stress applied: Increasing the temperature 1. What is the Keq expression?. 2. What will be the effect in the volume of water vapor collected? 3. What will be the Equilibrium Shift or the reaction? C. 4 NH3(g) + 5 O2(g) 4 NO(g) + 6 H2O(g) + heat Stress applied: Increasing the volume of the container 1. What is the Keq expression?. 2. What will be the effect in the amount of H₂O? 3. What will be the Equilibrium Shift or the reaction?
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Chapter 13 Solutions

ATKINS' PHYSICAL CHEMISTRY

Ch. 13 - Prob. 13A.1STCh. 13 - Prob. 13B.1STCh. 13 - Prob. 13B.2STCh. 13 - Prob. 13C.1STCh. 13 - Prob. 13F.1STCh. 13 - Prob. 13F.3STCh. 13 - Prob. 13A.1DQCh. 13 - Prob. 13A.2DQCh. 13 - Prob. 13A.3DQCh. 13 - Prob. 13A.4DQ
Ch. 13 - Prob. 13A.1AECh. 13 - Prob. 13A.1BECh. 13 - Prob. 13A.2AECh. 13 - Prob. 13A.2BECh. 13 - Prob. 13A.3AECh. 13 - Prob. 13A.3BECh. 13 - Prob. 13A.4AECh. 13 - Prob. 13A.4BECh. 13 - Prob. 13A.5AECh. 13 - Prob. 13A.5BECh. 13 - Prob. 13A.6AECh. 13 - Prob. 13A.6BECh. 13 - Prob. 13A.1PCh. 13 - Prob. 13A.2PCh. 13 - Prob. 13A.4PCh. 13 - Prob. 13A.5PCh. 13 - Prob. 13A.6PCh. 13 - Prob. 13A.7PCh. 13 - Prob. 13B.1DQCh. 13 - Prob. 13B.2DQCh. 13 - Prob. 13B.3DQCh. 13 - Prob. 13B.1AECh. 13 - Prob. 13B.1BECh. 13 - Prob. 13B.2AECh. 13 - Prob. 13B.2BECh. 13 - Prob. 13B.3AECh. 13 - Prob. 13B.3BECh. 13 - Prob. 13B.4AECh. 13 - Prob. 13B.4BECh. 13 - Prob. 13B.7AECh. 13 - Prob. 13B.7BECh. 13 - Prob. 13B.8AECh. 13 - Prob. 13B.8BECh. 13 - Prob. 13B.9AECh. 13 - Prob. 13B.9BECh. 13 - Prob. 13B.10AECh. 13 - Prob. 13B.10BECh. 13 - Prob. 13B.11AECh. 13 - Prob. 13B.11BECh. 13 - Prob. 13B.12AECh. 13 - Prob. 13B.12BECh. 13 - Prob. 13B.4PCh. 13 - Prob. 13B.5PCh. 13 - Prob. 13B.6PCh. 13 - Prob. 13B.7PCh. 13 - Prob. 13B.8PCh. 13 - Prob. 13B.10PCh. 13 - Prob. 13C.1DQCh. 13 - Prob. 13C.2DQCh. 13 - Prob. 13C.1AECh. 13 - Prob. 13C.1BECh. 13 - Prob. 13C.6AECh. 13 - Prob. 13C.6BECh. 13 - Prob. 13C.7AECh. 13 - Prob. 13C.7BECh. 13 - Prob. 13C.3PCh. 13 - Prob. 13C.7PCh. 13 - Prob. 13C.8PCh. 13 - Prob. 13C.9PCh. 13 - Prob. 13D.1DQCh. 13 - Prob. 13D.2DQCh. 13 - Prob. 13D.3DQCh. 13 - Prob. 13D.4DQCh. 13 - Prob. 13D.1AECh. 13 - Prob. 13D.1BECh. 13 - Prob. 13D.1PCh. 13 - Prob. 13D.2PCh. 13 - Prob. 13E.1DQCh. 13 - Prob. 13E.2DQCh. 13 - Prob. 13E.3DQCh. 13 - Prob. 13E.4DQCh. 13 - Prob. 13E.5DQCh. 13 - Prob. 13E.6DQCh. 13 - Prob. 13E.1AECh. 13 - Prob. 13E.1BECh. 13 - Prob. 13E.2AECh. 13 - Prob. 13E.2BECh. 13 - Prob. 13E.3AECh. 13 - Prob. 13E.3BECh. 13 - Prob. 13E.4AECh. 13 - Prob. 13E.4BECh. 13 - Prob. 13E.5AECh. 13 - Prob. 13E.5BECh. 13 - Prob. 13E.6AECh. 13 - Prob. 13E.6BECh. 13 - Prob. 13E.7AECh. 13 - Prob. 13E.7BECh. 13 - Prob. 13E.8AECh. 13 - Prob. 13E.8BECh. 13 - Prob. 13E.9AECh. 13 - Prob. 13E.9BECh. 13 - Prob. 13E.1PCh. 13 - Prob. 13E.2PCh. 13 - Prob. 13E.3PCh. 13 - Prob. 13E.4PCh. 13 - Prob. 13E.7PCh. 13 - Prob. 13E.9PCh. 13 - Prob. 13E.10PCh. 13 - Prob. 13E.11PCh. 13 - Prob. 13E.14PCh. 13 - Prob. 13E.15PCh. 13 - Prob. 13E.16PCh. 13 - Prob. 13E.17PCh. 13 - Prob. 13F.1DQCh. 13 - Prob. 13F.2DQCh. 13 - Prob. 13F.3DQCh. 13 - Prob. 13F.1AECh. 13 - Prob. 13F.1BECh. 13 - Prob. 13F.2AECh. 13 - Prob. 13F.2BECh. 13 - Prob. 13F.3AECh. 13 - Prob. 13F.3BECh. 13 - Prob. 13F.3PCh. 13 - Prob. 13F.4PCh. 13 - Prob. 13F.5PCh. 13 - Prob. 13F.6PCh. 13 - Prob. 13.1IA
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